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(1R,2R)-(+)-1,2-Diphenylethylenediamine

(1R,2R)-(+)-1,2-Diphenylethylenediamine structure

CAS No.: 35132-20-8

Chemical Name:: (1R,2R)-(+)-1,2-Diphenylethylenediamine

Synonyms: (1R,2R)-1,2-diphenylethane-1,2-diamine;(1R,2R)-1,2-DIPHENYLETHYLENEDIAMINE;R-DPEN;(1R,2R)-1,2-DIPHENYL-1,2-ETHANEDIAMINE;(1R,2R)-(+)-1,2-Diph;(1R,2R)-(+)-1,2-DiphenyL;(1R,2R)-1,2-Diphenyldiamine;(αS,βS)-Bibenzyl-α,β-diamine;(1S,2S)-(+)-1,2-Diphenylethane;(+)-1,2-Diphenylethylenediamine

CBNumber:: CB4727536

Molecular Formula:: C14H16N2

Molecular Weight:: 212.29

MDL Number:: MFCD00082769

MOL File:: 35132-20-8.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-05-28 02:01:44

Product description	Number	Pack Size	Price
(1R,2R)-(+)-1,2-Diphenylethylenediamine 97%	364010	500mg	$70.8
(1R,2R)-(+)-1,2-Diphenylethylenediamine 97%	364010	1g	$119
(1R,2R)-(+)-1,2-Diphenylethylenediamine >98.0%(GC)(T)	D2176	1g	$32
(1R,2R)-(+)-1,2-Diphenylethylenediamine >98.0%(GC)(T)	D2176	5g	$122
(1R,2R)-(+)-1,2-Diphenylethylenediamine, min. 97% (R,R)-DPEN min.97%	07-0474	500mg	$55
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(1R,2R)-(+)-1,2-Diphenylethylenediamine Properties

Melting point	79-83 °C(lit.)
alpha	104 º (c=1.1, MeOH 25 ºC)
Boiling point	342.14°C (rough estimate)
Density	1.0799 (rough estimate)
refractive index	103 ° (C=1, EtOH)
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
solubility	Chloroform (Slightly), Methanol (Slightly)
form	Crystalline Powder
pka	9.78±0.10(Predicted)
color	White to light yellow
optical activity	[α]20/D +102°, c = 1 in ethanol
Water Solubility	Insoluble in water.
Sensitive	Air Sensitive
BRN	2369988
Stability	Hygroscopic
InChI	1S/C14H16N2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-14H,15-16H2/t13-,14-/m1/s1
InChIKey	PONXTPCRRASWKW-ZIAGYGMSSA-N
SMILES	N[C@@H]([C@H](N)c1ccccc1)c2ccccc2
CAS DataBase Reference	35132-20-8(CAS DataBase Reference)
FDA UNII	JZ5DV7MKY6
UNSPSC Code	12352116
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P264-P271-P280-P302+P352-P305+P351+P338

target organs

Respiratory system

PPE

dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes

Risk Statements

Safety Statements

WGK Germany

HazardClass

HS Code

29212900

Storage Class

11 - Combustible Solids

Hazard Classifications

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

NFPA 704

	1
2		0

(1R,2R)-(+)-1,2-Diphenylethylenediamine price More Price(84)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	364010	(1R,2R)-(+)-1,2-Diphenylethylenediamine 97%	35132-20-8	500mg	$70.8	2026-04-30	Buy
Sigma-Aldrich	364010	(1R,2R)-(+)-1,2-Diphenylethylenediamine 97%	35132-20-8	1g	$119	2026-04-30	Buy
TCI Chemical	D2176	(1R,2R)-(+)-1,2-Diphenylethylenediamine >98.0%(GC)(T)	35132-20-8	1g	$32	2026-04-30	Buy
TCI Chemical	D2176	(1R,2R)-(+)-1,2-Diphenylethylenediamine >98.0%(GC)(T)	35132-20-8	5g	$122	2026-04-30	Buy
Strem Chemicals	07-0474	(1R,2R)-(+)-1,2-Diphenylethylenediamine, min. 97% (R,R)-DPEN min.97%	35132-20-8	500mg	$55	2026-04-30	Buy

Product number	Packaging	Price	Buy
364010	500mg	$70.8	Buy
364010	1g	$119	Buy
D2176	1g	$32	Buy
D2176	5g	$122	Buy
07-0474	500mg	$55	Buy

(1R,2R)-(+)-1,2-Diphenylethylenediamine Chemical Properties,Uses,Production

Description

(1R,2R)-(+)-1,2-Diphenylethylenediamine is a chiral reagent widely used in the chemical industry at present, used for asymmetric synthesis and optical resolution.

Chemical Properties

white to light yellow crystal powder

Uses

(1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine is used as chiral solvation agent for determination of enantiomeric excess of chiral acids by NMR. It is used in various catalyst systems for asymmetric reactions.

Synthesis

Add 1,2-diphenylethanedione dioxime (48g, 0.20mol) and 260ml methanol in a 500ml four-necked flask equipped with a condenser, stir to dissolve all of them, and then add 2g of activated charcoal (120 mesh), 0.5g of Raney's nickel, raise the temperature to 60 , and then add 80% hydrazine hydrate (28.75g, 0.46mol) slowly dropwise, and keep the temperature of the reaction between 58 -62 , there is nitrogen emission during the reaction, and the rate of dropwise acceleration is controlled to keep the nitrogen emission rate not too fast, and liquid chromatography tracks the reaction process. -62 , the reaction process has nitrogen release, drop acceleration control in the nitrogen release rate is not too fast as well, liquid chromatography to track the reaction process, when the raw material 1,2-diphenylethanedione dioxime disappeared after the end of the reaction, cooling the mixture, filtration of Ranieri nickel and activated carbon, to a small amount of water covered with a preserved in order to prepare for sets of use, the filtrate distillation to recover the methanol, and the residue added to 200 ml of petroleum ether heated to make all dissolved, cooled for 24 hours and filtered to get the product The residue was heated by adding 200 ml of petroleum ether to dissolve all of it, then cooled and filtered for 24 hours to obtain the product (1R,2R)-1,2-diphenylethylenediamine 41.55g, yield 98%, chemical purity 99.57%.

(1R,2R)-(+)-1,2-Diphenylethylenediamine synthesis

Synthesis of (1R,2R)-(+)-1,2-Diphenylethylenediamine from N-Benzylideneamine

(1R,2R)-(+)-1,2-Diphenylethylenediamine Preparation Products And Raw materials

Raw materials

Sodium acetate Ethanol Acetic anhydride N,N-Dimethylformamide D-(-)-Tartaric Acid

Sodium Sodium ethoxide Hydrogen bromide Benzaldehyde Hydrochloric acid

Acetic acid Cyclohexanone Benzil Lithium Ammonia

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Preparation Products

(1R,2R)-N,N'-DI-P-TOLUENESULFONYL-1,2-DIPHENYL-1,2-ETHYLENEDIAMINE (1R,2R)-(+)-N,N'-DIMETHYL-1,2-DIPHENYL-1,2-ETHANE DIAMINE Benzenesulfonamide, N-[(1R,2R)-2-amino-1,2-diphenylethyl]-4-nitro-

(1R,2R)-(+)-1,2-Diphenylethylenediamine Suppliers

Global( 430)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai UCHEM Inc.	+86-18930848214 +86-021-56762820	sales@myuchem.com	China	8898	58
Shaanxi Dideu Medichem Co. Ltd	+86-029-81138252 +86-173 9270 1263	1057@dideu.com	China	3961	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29626	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-2158073036	info@dakenam.com	China	14036	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21533	55
Fluoropharm Co., Ltd.	+86-0571-85586753 +86-13336034509	sales@fluoropharm.com	China	1444	60
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29766	58
Changzhou Ditong Chemical Co.,Ltd	+86-0519-88298848	info@edengenechem.com	China	2163	58
CONIER CHEM AND PHARMA LIMITED		sales@conier.com	China	49906	58
SIMAGCHEM CORP	+86-5922680277 +86-13806087780	sale@simagchem.com	China	17339	58

Supplier	Advantage
Shanghai UCHEM Inc.	58
Shaanxi Dideu Medichem Co. Ltd	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
Fluoropharm Co., Ltd.	60
career henan chemical co	58
Changzhou Ditong Chemical Co.,Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
SIMAGCHEM CORP	58

View Lastest Price from (1R,2R)-(+)-1,2-Diphenylethylenediamine manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-08-19	(1R,2R)-(+)-1,2-Diphenylethylenediamine 35132-20-8	$11.00-193.00	1g	0.98	25kg	Shanghai UCHEM Inc.
2025-06-27	(1R,2R)-(+)-1,2-Diphenylethylenediamine 35132-20-8		1KG	99%	500000kg	Hebei Chuanghai Biotechnology Co., Ltd
2025-04-04	(1R,2R)-(+)-1,2-Diphenylethylenediamine 35132-20-8		1kg	98%	1Ton	Henan Aochuang Chemical Co.,Ltd.

(1R,2R)-(+)-1,2-Diphenylethylenediamine
35132-20-8
$11.00-193.00
0.98
Shanghai UCHEM Inc.

(1R,2R)-(+)-1,2-Diphenylethylenediamine
35132-20-8
99%
Hebei Chuanghai Biotechnology Co., Ltd

(1R,2R)-(+)-1,2-Diphenylethylenediamine
35132-20-8
98%
Henan Aochuang Chemical Co.,Ltd.

(1R,2R)-(+)-1,2-Diphenylethylenediamine Spectrum

(1R,2R)-(+)-1,2-Diphenylethylenediamine(35132-20-8)¹HNMR (1R,2R)-(+)-1,2-Diphenylethylenediamine(35132-20-8)¹HNMR

35132-20-8((1R,2R)-(+)-1,2-Diphenylethylenediamine)Related Search:

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(1S,2S)-(-)-1,2-Diphenylethylenediamine-C14H16N2,(1S,2S)-(-)-1,2-Diphenylethylenediamine,min.97%(S,S)-DPEN,(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE (S,S)-DPEN 2,2-Diphenylethylamine (R,R)-N-(p-Toluenesulfonyl)-1,2-diphenylethylenediamine(Chloro)(p-cymene)ruthenium(II) Dichloro[(R)-(-)-4,12-bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) 1,2-Dianilinoethane

1,2-Diphenylethylenediamine (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II)

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(R,R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine ee (1S,2S)-1,2-Diphenyl-1,2-diaminoethane (αS,βS)-Bibenzyl-α,β-diamine (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine ,98% [99%,e.e.] (1R,2R)-(+)-1,2-Diphenylethylenediamine ,99% [ee:99%] (1R,2R)-Diphenyl-1,2-ethanediamine (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine, 98+%, ee 98% (1R,2R)-(+)-1,2-Diph (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine,99%,99% ee (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediaMine, 99% ee, 99% 250MG ((1R,2R)-2-AMino-1,2-diphenylethyl)aMine (R,R)-1,2-DiaMino-1,2-diphenylethane (R,R)-1,2-Diphenylethylene-1,2-diaMine (1R,2R)-(+)-1,2-DiphenylethylenediaMine,(R,R)-DPEN (1R,2R)-(+)-1,2-DiphenylethylenediaMine, ee: 99% (1R,2R)-(+)-1,2-diphenylethylendediamine (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine, 98+% (1R,2R)-1,2-Diphenylethane-1,2-diamine 98% (1R,2R)-DIPHENYL-ETHANE-1,2-DIAMINE (1R,2R)-(+)-1,2-DIAMINO-1,2-DIPHENYLETHANE (1R,2R)-(+)-1,2-DIPHENYL-1,2-ETHANEDIAMINE (1R,2R)-1,2-DIPHENYL-1,2-ETHANEDIAMINE (1R,2R)-(+)-1,2-DIPHENYL-1,2-ETHYLENEDIAMINE (1R,2R)-(-)-1,2-DIPHENYLETHYLENEDIAMINE (1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE 1,2-ETHANEDIAMINE, 1,2-DIPHENYL-, (1R,2R)- (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine, 99% ee, 99% (1S,2S)-(+)-1,2-Diphenylethane (1R,2R)-(+)-1,2-Diphenylethylenediamine,min.97%(R,R)-DPEN (1S,2S)-(-)-1,2-Diphenylenediamine (1R,2R)-(+)-1,2-DIPHENYLETHYLENDIAMIN (1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE, 97% (99% EE/GLC) (1R,2R)-(+)-1,2-DiphenylethylenediaMine, 97+% (1R,2R)-(+)-1,2-Diphenylethylenediamine,97% (R,R)-DPEN (1R,2R)-(+)-1,2-Diphenylethylenediamine (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine (1R,2R)-(+)-1,2-Diphenylethylenediamine (1R,2R)-(+)-1,2-Diphenylethylenediamine 97% (R,R)-DPEN , (1R,2R)-1,2-Diphenyl-1,2-ethanediamine, 98% (1R,2R)-(+)-1,2-Diphenylethylenediamine≥ 99.5% (HPLC, Chiral purity) (1R,2R)-Diphenylethane-1,2-diamine,99%e.e. (1R,2R)-(+)-1,2-Diphenylethylenediamine, min. 97% (1R,2R)-(+)-1,2-Diphenyl-1,2-diaminoethane (1R,2R)-(+)-1,2-Diphenylethylenediamine, 99%, ee: 99% (1R,2R)-(+)-1,2-DIPHENYL-1,2-ETHANEDIAMI (1R,2R)-(+)-1,2-Diphenylethylenediamine> (1R,2R)-(+)-1,2-DiphenyL (1R,2R)-(+)-1,2-Diphenylethylenediamine,min.97% (+)-1,2-Diphenylethylenediamine (1R,2R)-1,2-Diphenylethylenediamine / R-DPEN (1R,2R)-(+)-1,2-Diphenylethylenediamine (1R,2R)-1,2-Diphenyldiamine (1R,2R)-(+)-1,2-diphenylethyldiamine (1R,2R)-1,2-DIPHENYLETHYLENEDIAMINE (1R,2R)-1,2-diphenylethane-1,2-diamine R-DPEN 1R,2R)-1,2-Diphenyl-1,2-ethanediamine8 35132-20-8