Allylidenetriphenylphosphorane
- CAS No.
- 15935-94-1
- Chemical Name:
- Allylidenetriphenylphosphorane
- Synonyms
- Allylenetriphenylphosphorane;allylidenetriphenylphosphorane;Triphenylpropenylidenephosphorane;Vinylmethylenetriphenylphosphorane;Triphenyl-2-propenylidenephosphorane;Phosphorane, triphenyl-2-propen-1-ylidene-
- CBNumber:
- CB4946957
- Molecular Formula:
- C21H19P
- Molecular Weight:
- 302.35
- MDL Number:
- MOL File:
- 15935-94-1.mol
Allylidenetriphenylphosphorane Chemical Properties, Uses, Production
Uses
Allylidenetriphenylphosphorane is used as a wittig reagent for 1,3-diene synthesis and Michael addition reaction.
Preparation
Allylidenetriphenylphosphorane is generally prepared from Allyltriphenylphosphonium Bromide or chloride by treatment with n-Butyllithium or Phenyllithium. Structurally related analogs have been prepared by the similar methods: 2-butenylidenetriphenylphosphorane; 3-methyl-2- butenylidenetriphenylphosphorane; (E)-2-octenylidenetriphenylphosphorane; (E)- pentadienylidenetriphenylphosphorane; (E)-2,4-hexadienylidenetriphenylphosphorane; 2- alkynylidenetriphenylphosphorane; allylidenetributylphosphorane. γ-Alkyl-substituted allylidenetriphenylphosphorane can be also obtained by the reaction of diisobutylaluminum alkylideneamide with methylidenetriphenylphosphorane.
storage
Allylidenetriphenylphosphorane must be prepared and transferred under inert gas (Ar or N2) to exclude oxygen and moisture.
Allylidenetriphenylphosphorane Preparation Products And Raw materials
Allylidenetriphenylphosphorane Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| DAYANG CHEM (HANGZHOU) CO.,LTD | +86-88938639 +86-17705817739 | info@dycnchem.com | China | 53636 | 58 |
| Supplier | Advantage |
|---|---|
| DAYANG CHEM (HANGZHOU) CO.,LTD | 58 |




