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Allylidenetriphenylphosphorane

CAS No.
15935-94-1
Chemical Name:
Allylidenetriphenylphosphorane
Synonyms
Allylenetriphenylphosphorane;allylidenetriphenylphosphorane;Triphenylpropenylidenephosphorane;Vinylmethylenetriphenylphosphorane;Triphenyl-2-propenylidenephosphorane;Phosphorane, triphenyl-2-propen-1-ylidene-
CBNumber:
CB4946957
Molecular Formula:
C21H19P
Molecular Weight:
302.35
MDL Number:
MOL File:
15935-94-1.mol
Last updated:2024-12-18 16:19:15

Allylidenetriphenylphosphorane Properties

Boiling point 452.3±28.0 °C(Predicted)
Density 1.09
solubility sol THF and toluene.

Allylidenetriphenylphosphorane price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
aablocks AA00AC7A Allylidenetriphenylphosphorane 95+% 15935-94-1 1g $1050 2026-05-28 Buy
Product number Packaging Price Buy
AA00AC7A 1g $1050 Buy

Allylidenetriphenylphosphorane Chemical Properties, Uses, Production

Uses

Allylidenetriphenylphosphorane is used as a wittig reagent for 1,3-diene synthesis and Michael addition reaction.

Preparation

Allylidenetriphenylphosphorane is generally prepared from Allyltriphenylphosphonium Bromide or chloride by treatment with n-Butyllithium or Phenyllithium. Structurally related analogs have been prepared by the similar methods: 2-butenylidenetriphenylphosphorane; 3-methyl-2- butenylidenetriphenylphosphorane; (E)-2-octenylidenetriphenylphosphorane; (E)- pentadienylidenetriphenylphosphorane; (E)-2,4-hexadienylidenetriphenylphosphorane; 2- alkynylidenetriphenylphosphorane; allylidenetributylphosphorane. γ-Alkyl-substituted allylidenetriphenylphosphorane can be also obtained by the reaction of diisobutylaluminum alkylideneamide with methylidenetriphenylphosphorane.

storage

Allylidenetriphenylphosphorane must be prepared and transferred under inert gas (Ar or N2) to exclude oxygen and moisture.

Allylidenetriphenylphosphorane Preparation Products And Raw materials

Raw materials

Preparation Products

Allylidenetriphenylphosphorane Suppliers

Global Suppliers ( 5)
Supplier Tel Email Country ProdList Advantage
DAYANG CHEM (HANGZHOU) CO.,LTD +86-88938639 +86-17705817739 info@dycnchem.com China 53636 58
Supplier Advantage
DAYANG CHEM (HANGZHOU) CO.,LTD 58
allylidenetriphenylphosphorane Allylenetriphenylphosphorane Triphenyl-2-propenylidenephosphorane Triphenylpropenylidenephosphorane Vinylmethylenetriphenylphosphorane Phosphorane, triphenyl-2-propen-1-ylidene- 15935-94-1 C21H19P