6-Methoxy-pyridine-2-carboxylicacidmethylester
- CAS No.
- 26256-72-4
- Chemical Name:
- 6-Methoxy-pyridine-2-carboxylicacidmethylester
- Synonyms
- Methyl 6-methoxy;Methyl 6-methoxypicolinate;methyl 6-methoxy-2-pyridinecarboxylate;6-Methoxypyridinecarboxylic acid methyl ester;6-Methoxy-2-Pyridinecarboxylic Acid Methyl Ester;2-Pyridinecarboxylic acid, 6-Methoxy-, Methyl ester;Methyl 6-
methoxypyridine- 2- carboxylate
- CBNumber:
- CB51229335
- Molecular Formula:
- C8H9NO3
- Molecular Weight:
- 167.16
- MDL Number:
- MFCD07779517
- MOL File:
- 26256-72-4.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 33-38℃ |
|---|---|
| Boiling point | 256.6±20.0 °C(Predicted) |
| Density | 1.156±0.06 g/cm3(Predicted) |
| storage temp. | Sealed in dry,Room Temperature |
| form | solid |
| pka | 0.41±0.10(Predicted) |
| color | White |
| InChI | InChI=1S/C8H9NO3/c1-11-7-5-3-4-6(9-7)8(10)12-2/h3-5H,1-2H3 |
| InChIKey | QCCJUEURAZMEGY-UHFFFAOYSA-N |
| SMILES | C1(C(OC)=O)=NC(OC)=CC=C1 |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS05,GHS07 |
|---|---|
| Signal word | Danger |
| Hazard statements | H315-H318-H335 |
| Precautionary statements | P261-P280-P305+P351+P338 |
| target organs | Respiratory system |
| PPE | dust mask type N95 (US), Eyeshields, Gloves |
| Hazard Codes | Xi |
| Risk Statements | 37/38-41 |
| Safety Statements | 26-39 |
| WGK Germany | 3 |
| HS Code | 2933399990 |
| Storage Class | 11 - Combustible Solids |
| Hazard Classifications | Eye Dam. 1 Skin Irrit. 2 STOT SE 3 |
6-Methoxy-pyridine-2-carboxylicacidmethylester price More Price(42)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Biosynth | BBA25672 | Methyl 6-methoxypyridine-2-carboxylate | 26256-72-4 | 100g | $688 | 2026-06-04 | Buy |
| Biosynth | BBA25672 | Methyl 6-methoxypyridine-2-carboxylate | 26256-72-4 | 250g | $1032.5 | 2026-06-04 | Buy |
| Apolloscientific | OR901996 | Methyl 6-methoxypicolinate 98% | 26256-72-4 | 250mg | $21 | 2026-06-04 | Buy |
| Apolloscientific | OR901996 | Methyl 6-methoxypicolinate 98% | 26256-72-4 | 1g | $24 | 2026-06-04 | Buy |
| Apolloscientific | OR901996 | Methyl 6-methoxypicolinate 98% | 26256-72-4 | 5g | $30 | 2026-06-04 | Buy |
6-Methoxy-pyridine-2-carboxylicacidmethylester Chemical Properties, Uses, Production
Uses
Methyl 6-methoxy-2-pyridinecarboxylate is a useful research chemical.
Synthesis Reference(s)
Tetrahedron Letters, 15, p. 4339, 1974 DOI: 10.1016/S0040-4039(01)92158-6
Synthesis
19621-92-2
74-88-4
26256-72-4
General procedure for the synthesis of methyl 6-methoxypyridine-2-carboxylate from 6-hydroxypyridine-2-carboxylic acid and iodomethane: 6-hydroxypyridine-2-carboxylic acid (1 g, 7.19 mmol) and silver carbonate (2.2 g, 7.90 mmol) were placed in a round-bottomed flask, and chloroform (20 mL) was added to dissolve. Subsequently, iodomethane (1 mL, 15.81 mmol) was added slowly and dropwise. The reaction mixture was stirred at 60°C for 26 hours. After completion of the reaction, the mixture was filtered and extracted with chloroform. Next, the extract was vacuum filtered and vacuum distilled to remove the solvent. Finally, the residue was purified by column chromatography (eluent ratio of ethyl acetate: hexane = 1:5) to afford the target product methyl 6-methoxypyridine-2-carboxylate (1.25 g, 100% yield).
References
[1] Patent: WO2014/3483, 2014, A1. Location in patent: Page/Page column 34
[2] Organic and Biomolecular Chemistry, 2006, vol. 4, # 6, p. 1071 - 1084
[3] Organic Letters, 2009, vol. 11, # 23, p. 5562 - 5565
[4] Patent: WO2011/79076, 2011, A1. Location in patent: Page/Page column 93
6-Methoxy-pyridine-2-carboxylicacidmethylester Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hunan Caiya Biological Technology Co., Ltd | 15580017485 | 2036676503@qq.com | China | 91 | 58 |
| Suzhou Xinrui Biotechnology Co., Ltd. | 13401437572 | xinruibiotech01@163.com | China | 2738 | 58 |
| Suzhou Qiushuo Biotechnology Co., Ltd | 0512-67862615 13382151840 | 2943249291@QQ.COM | China | 352 | 58 |
| PharmaBlock Sciences (Nanjing),Inc. | 025-86918202 4000255188 | sales@pharmablock.com | China | 5000 | 55 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Wuhan Chemwish Technology Co., Ltd | 86-027-67849912 | sales@chemwish.com | China | 35884 | 56 |
| Capot Chemical Co., Ltd | +86 (0) 571 85 58 67 18 | China | 18187 | 66 | |
| Record Tech (Shanghai) Co., LTD | 13761627472 | 183009664@qq.com | China | 660 | 62 |
| Hunan Hui Bai Shi Biotechnology Co., Ltd. | 0731-85526065 13308475853 | ivy@hnhbsj.com | China | 7236 | 62 |
| Chengdu Forest Science and Technology Development Co., Ltd. | 18030648795 18030648795 | sales@cdforestchem.com | China | 1997 | 58 |
View Latest Price from 6-Methoxy-pyridine-2-carboxylicacidmethylester manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-08-25 | 6-METHOXY-PYRIDINE-2-CARBOXYLICACIDMETHYLESTER
26256-72-4
|
$100.00-600.00 | 5g | 99% | 50 | Zibo Hangyu Biotechnology Development Co., Ltd | |
 |
2020-01-13 | 6-METHOXY-PYRIDINE-2-CARBOXYLICACIDMETHYLESTER
26256-72-4
|
$5.50 | 1KG | 98%min | 1kg-100kg | Career Henan Chemical Co |
-
- 6-METHOXY-PYRIDINE-2-CARBOXYLICACIDMETHYLESTER
26256-72-4
- $100.00-600.00
- 99%
- Zibo Hangyu Biotechnology Development Co., Ltd
-
- 6-METHOXY-PYRIDINE-2-CARBOXYLICACIDMETHYLESTER
26256-72-4
- $5.50
- 98%min
- Career Henan Chemical Co
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