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ETHYL 3-PHENYLGLYCIDATE

CAS No.
121-39-1
Chemical Name:
ETHYL 3-PHENYLGLYCIDATE
Synonyms
FEMA 2454;ETHYL PHENYLGLYCIDATE;ethyl3-phenyloxirane;β-epoxyhydrocinnamate;strawberry glycidate 2;ethyl3-phenyloxirane-2-;ETHYL 3-PHENYLGLYCIDATE;ETHYL PHENYLGLYCIDATE FCC;Ethyl 3-Phenylglycidate ETHYL A B-EPOXYHYDROCINNAMATE
CBNumber:
CB5292099
Molecular Formula:
C11H12O3
Molecular Weight:
192.21
MDL Number:
MFCD00005123
MOL File:
121-39-1.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 02:26:41
Product description Number Pack Size Price
Ethyl 3-phenylglycidate mixture of cis and trans, 92% W245402 1 each $55.9
Ethyl 3-phenylglycidate mixture of cis and trans, 92% W245402 1 unit $51.87
Ethyl 3-phenylglycidate mixture of cis and trans, 92% W245402 1 unit $51.87
Ethyl 3-phenylglycidate mixture of W245402 sample $54.6
Ethyl 3-phenylglycidate technical grade, 92%, mixture of 291404 100ml $49
More product size

ETHYL 3-PHENYLGLYCIDATE Properties

Melting point 17-18 °C
Boiling point 96 °C/0.5 mmHg (lit.)
Density 1.102 g/mL at 25 °C (lit.)
vapor pressure 0.12Pa at 24℃
FEMA 2454 | ETHYL 3-PHENYLGLYCIDATE
refractive index n20/D 1.518(lit.)
FLAVIS Number 16.018 | Ethyl 3-phenyl-2,3-epoxypropionate
Flash point >230 °F
storage temp. 2-8°C
solubility Insoluble in water
form Liquid
color Clear colorless to yellow
Odor at 100.00 %. sweet strawberry berry floral tropical
Odor Type fruity
biological source synthetic
Water Solubility 748.4mg/L at 24℃
Sensitive Moisture Sensitive
JECFA Number 1576
Stability Stable. Combustible. Incompatible with strong oxidizing agents.
Major Application flavors and fragrances
Cosmetics Ingredients Functions PERFUMING
InChI 1S/C11H12O3/c1-2-13-11(12)10-9(14-10)8-6-4-3-5-7-8/h3-7,9-10H,2H2,1H3
InChIKey GOMAKLPNAAZVCJ-UHFFFAOYSA-N
SMILES CCOC(=O)C1OC1c2ccccc2
LogP 2.4 at 20℃
CAS DataBase Reference 121-39-1(CAS DataBase Reference)
Substances Added to Food (formerly EAFUS) ETHYL 3-PHENYLGLYCIDATE
EWG's Food Scores 1
FDA UNII 2VVS520ZWM
EPA Substance Registry System Ethyl 3-phenylglycidate (121-39-1)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H303-H335-H315-H319
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a
PPE Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  23-24/25
WGK Germany  2
RTECS  MB4970000
TSCA  TSCA listed
HS Code  29189990
Storage Class 10 - Combustible liquids
Hazardous Substances Data 121-39-1(Hazardous Substances Data)
Toxicity The acute oral LD50 value in rats was reported as 2.3 ml/kg (2.0-2.6 ml/ kg) (Shelanski, 1973b). The acute dermal LD50 value in rabbits was reported as > 5 g/kg (Shelanski, 1973a).
REACH Registrations Active
NFPA 704
1
2 0

ETHYL 3-PHENYLGLYCIDATE price More Price(51)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich W245402 Ethyl 3-phenylglycidate mixture of cis and trans, 92% 121-39-1 1 each $55.9 2026-04-30 Buy
Sigma-Aldrich W245402 Ethyl 3-phenylglycidate mixture of cis and trans, 92% 121-39-1 1 unit $51.87 2025-07-31 Buy
Sigma-Aldrich W245402 Ethyl 3-phenylglycidate mixture of cis and trans, 92% 121-39-1 1 unit $51.87 2025-07-31 Buy
Sigma-Aldrich W245402 Ethyl 3-phenylglycidate mixture of 121-39-1 sample $54.6 2024-03-01 Buy
Sigma-Aldrich 291404 Ethyl 3-phenylglycidate technical grade, 92%, mixture of 121-39-1 100ml $49 2023-06-20 Buy
Product number Packaging Price Buy
W245402 1 each $55.9 Buy
W245402 1 unit $51.87 Buy
W245402 1 unit $51.87 Buy
W245402 sample $54.6 Buy
291404 100ml $49 Buy

ETHYL 3-PHENYLGLYCIDATE Chemical Properties,Uses,Production

Chemical Properties

pale yellow liquid

Chemical Properties

Ethyl 3-Phenylglycidate is a colorless liquid with a strawberry-like odor.
It is prepared by treating ethyl cinnamatewith peracetic acid or by condensation of benzaldehyde with ethyl chloroacetate (in the aforementioned Darzens reaction, R == H).Theglycidate is used as a long-lasting fragrancematerial for creating harmonic, fruity notes in household and fine fragrances.

Chemical Properties

Ethyl 3-phenylglycidate has a strong, fruity odor suggestive of strawberry with a corresponding sweet flavor.

Occurrence

Apparently has not been reported to occur in nature.

Uses

Ethyl 3-Phenyloxirane-2-carboxylate is used in preparation method of early-strength viscosity-breaking Polycarboxylate water reducer containing three viscosity-breaking group and used as concrete additive.

Preparation

Usually prepared by the reaction of benzaldehyde and the ethyl ester of monochloracetic acid in the presence of an alkaline condensing agent; by reacting the silver salt of phenyl glycidic acid with ethyl iodide.

Definition

ChEBI: Ethyl phenylglycidate is an epoxide and a carboxylic acid.

Aroma threshold values

Detection: 8.5 ppm

Taste threshold values

Taste characteristics at 30 ppm: sweet, fruity and berry with dried fruit and floral nuance.

Synthesis Reference(s)

Synthetic Communications, 12, p. 355, 1982 DOI: 10.1080/00397918209408010

General Description

Clear pale yellow or yellow liquid.

Air & Water Reactions

Slightly water soluble.

Reactivity Profile

Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.

Fire Hazard

ETHYL 3-PHENYLGLYCIDATE is probably combustible.

Flammability and Explosibility

Non flammable

Safety Profile

Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.

ETHYL 3-PHENYLGLYCIDATE Preparation Products And Raw materials

Global( 180)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Chuanghai Biotechnology Co., Ltd
+8615350571055 Sibel@chuanghaibio.com China 8738 58
Hebei Zhuanglai Chemical Trading Co Ltd
+86-16264648883 niki@zlchemi.com China 7245 58
career henan chemical co
+86-0371-86658258 +8613203830695 factory@coreychem.com China 29792 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
HANGZHOU CLAP TECHNOLOGY CO.,LTD
86-571-88216897,88216896 13588875226 sales@hzclap.com CHINA 6312 58
ANHUI WITOP BIOTECH CO., LTD
+8615255079626 eric@witopchemical.com China 23541 58
Dideu Industries Group Limited
+86-29-89586680 +86-15129568250 1026@dideu.com China 20582 58
Henan Alfa Chemical Co., Ltd
+8615838112936 sale03@alfachem.cn China 9796 58
Guangzhou TongYi biochemistry technology Co.,LTD
+8613073028829 tongyibiochem@163.com China 2995 58
Hebei Fengjia New Material Co., Ltd
+86-0311-87836622 +86-18712993135 sales01@tairunfaz.com China 8051 58

View Lastest Price from ETHYL 3-PHENYLGLYCIDATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
ETHYL 3-PHENYLGLYCIDATE pictures 2026-03-20 ETHYL 3-PHENYLGLYCIDATE
121-39-1
$10.00 1KG 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
ETHYL 3-PHENYLGLYCIDATE pictures 2025-05-23 ETHYL 3-PHENYLGLYCIDATE
121-39-1
$45.00 1kg 99% 20 tons Hebei Zhuanglai Chemical Trading Co Ltd
ETHYL 3-PHENYLGLYCIDATE pictures 2020-01-13 ETHYL 3-PHENYLGLYCIDATE
121-39-1
$1.00 1g 99.0% 100kg Career Henan Chemical Co
(2R,3R)-3-Phenyloxirane-2-carboxylic acid ethyl ester 3-Phenyloxirane-2-carboxylic acid ethyl ester Ethyl 3-Phenylglycidate (cis- and trans- mixture) (2S,3S)-3-Phenyloxirane-2-carboxylic acid ethyl ester Ethyl 3-phenylglycidate,98%,mixture of cis and trans Ethyl 3-phenylglycidate,90%,mixture of cis and trans ethyl2,3-epoxy-3-phenylpropion Ethyl 2,3-epoxy-3-phenylpropionate Ethyl 3-phenyl-2-oxiranecarboxylate Ethyl alpha,beta-epoxy-alpha-phenylpropionate Ethyl alpha,beta-epoxyhydrocinnamate ethyl2,3-epoxy-3-phenylpropionate ethyl3-phenylglycidate,mixtureofcisandtrans ethyl3-phenyloxirane ethyl3-phenyloxirane-2- ethyl3-phenyloxirane-2-carboxylate ethyl3-phenyloxiranecarboxylate ethylalpha,beta-epoxy-alpha-phenylpropionate ethylalpha,beta-epoxyhydrocinnamate Oxiranecarboxylicacid,3-phenyl-,ethylester 3-Phenylglycidic Acid Ethyl Ester Ethyl 3-Phenyloxiranecarboxylate Ethyl 3-Phenylglycidate  Ethyl 3-Phenylglycidate (cis- and trans- mixture) 3-phenyl-glycidicaciethylester 3-phenyl-oxiranecarboxylicaciethylester GLYCIDIC ACID, 3-PHENYL:ETHYL ESTER ETHYL 3-PHENYLGLYCIDATE ETHYL A B-EPOXYHYDROCINNAMATE ETHYL3-PHENYLGLYCIDATE,TECHNICAL 23EPOXY3PHENYLPROPIONICACIDETHYLESTERCISTRANS Ethyl-3-phenyloxiran-2-carboxylat Ethyl 3-phenylglycidate, cis + trans, 90+% ETHYL PHENYLGLYCIDATE FCC 3-PHENYLGLYCIDIC ACID ETHYL ESTER 3-PHENYLOXIRANECARBOXYLIC ACID ETHYL ESTER ETHYL 3-PHENYLGLYCIDATE 92+% & ETHYL 3-PHENYLGLYCIDATE, TECH., 92%, MIX TURE OF CIS AND TRANS Ethyl 3-phenylglycidate, cis + trans, 95% Ethyl3-Phenylglycidate(cis-andtrans-mixture)> 2-Oxiranecarboxylic acid, 3-phenyl-, ethyl ester ETHYL 3-PHENYLGLYCIDATE USP/EP/BP strawberry glycidate 2 β-epoxyhydrocinnamate ETHYL PHENYLGLYCIDATE FEMA 2454 121-39-1 C11H12O3C11H12O3C11H12O3C11H12O3C11H12O3 Oxygen Compounds Organic Building Blocks Epoxides Building Blocks Alphabetical Listings E-F Flavors and Fragrances Epoxides Organic Building Blocks Oxygen Compounds Building Blocks