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4'-CHLOROPIVALOANILIDE

4'-CHLOROPIVALOANILIDE structure

CAS No.: 65854-91-3

Chemical Name:: 4'-CHLOROPIVALOANILIDE

Synonyms: 4-Chloropivalamide;4-Chloropivalanilide;4'-CHLOROPIVALOANILIDE;N-Pivaloyl-p-chlorophenyl;4'-Chloropivaloanilide>4-CHLORO-N-PIVALOYLANILINE;N-PIVALOYL-P-CHLOROANILINE;N-(4-chlorophenyl)pivalaMide;N-(4-CHLOROPHENYL)PIVALOYLAMIDE;4''-CHLOROPIVALOANILIDE,98.0%+(GC)

CBNumber:: CB5365717

Molecular Formula:: C11H14ClNO

Molecular Weight:: 211.69

MDL Number:: MFCD00095895

MOL File:: 65854-91-3.mol

MSDS File:: SDS

Last updated:2026-05-28 01:30:21

Product description	Number	Pack Size	Price
4'-CHLORO-2,2-DIMETHYLPROPIONANILIDE Aldrich^CPR	S902640	1 unit	$32.7
4'-CHLORO-2,2-DIMETHYLPROPIONANILIDE Aldrich	S902640	50mg	$29.8
4'-Chloropivaloanilide >98.0%(GC)	C2099	25g	$30
4'-Chloropivaloanilide >98.0%(GC)	C2099	250g	$250
N-(4-Chlorophenyl)pivalamide 98%	AA003L5I	1g	$18
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4'-CHLOROPIVALOANILIDE Properties

Melting point	152 °C
Boiling point	352.1±25.0 °C(Predicted)
Density	1.150±0.06 g/cm3(Predicted)
storage temp.	2-8°C
pka	14.25±0.70(Predicted)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H302+H312+H332

Precautionary statements

P261-P264-P270-P271-P280-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P501

HS Code

2921420090

NFPA 704

	0
1		0

4'-CHLOROPIVALOANILIDE price More Price(23)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	S902640	4'-CHLORO-2,2-DIMETHYLPROPIONANILIDE Aldrich^CPR	65854-91-3	1 unit	$32.7	2026-04-30	Buy
Sigma-Aldrich	S902640	4'-CHLORO-2,2-DIMETHYLPROPIONANILIDE Aldrich	65854-91-3	50mg	$29.8	2024-03-01	Buy
TCI Chemical	C2099	4'-Chloropivaloanilide >98.0%(GC)	65854-91-3	25g	$30	2026-04-30	Buy
TCI Chemical	C2099	4'-Chloropivaloanilide >98.0%(GC)	65854-91-3	250g	$250	2026-04-30	Buy
aablocks	AA003L5I	N-(4-Chlorophenyl)pivalamide 98%	65854-91-3	1g	$18	2026-05-28	Buy

Product number	Packaging	Price	Buy
S902640	1 unit	$32.7	Buy
S902640	50mg	$29.8	Buy
C2099	25g	$30	Buy
C2099	250g	$250	Buy
AA003L5I	1g	$18	Buy

4'-CHLOROPIVALOANILIDE Chemical Properties,Uses,Production

Synthesis

3282-30-2

106-47-8

65854-91-3

The general procedure for synthesizing N-pivaloyl-p-chloroaniline from pivaloyl chloride and 4-chloroaniline was as follows: referring to Example 2, 4-chloroaniline (113 kg, 886 mol), deionized water (565 L), and sodium bicarbonate (89.3 kg, 1.2 eq.) were added to ethyl acetate (1695 L). Pivaloyl chloride (112 kg, 1.05 eq.) was slowly added dropwise at 15°C or lower. After the dropwise addition was completed, the reaction solution was stirred at about 25°C for 2 hours. Upon completion of the reaction, the organic and aqueous layers were separated. The organic layer was washed twice with deionized water (848 L x 2) and then concentrated under reduced pressure to about 600 L. To the concentrate was added ethylcyclohexane (848 L) and again concentrated under reduced pressure to about 600 L. The residue was cooled to about 5 °C and stirred for 1 h to promote crystallization. The precipitated crystals were collected by filtration and dried under reduced pressure to afford N-pivaloyl-p-chloroaniline (187 kg, 99.7% yield).

References

[1] Patent: WO2005/121133, 2005, A1. Location in patent: Page/Page column 30-31
[2] Patent: US2009/247766, 2009, A1. Location in patent: Page/Page column 27
[3] Patent: WO2015/118515, 2015, A1. Location in patent: Page/Page column 9
[4] Journal of Organic Chemistry, 1998, vol. 63, # 23, p. 8536 - 8543
[5] Patent: CN105801442, 2016, A. Location in patent: Paragraph 0006; 0018; 0022; 0026; 0030

4'-CHLOROPIVALOANILIDE Preparation Products And Raw materials

Raw materials

2,2,2-TRIMETHYLACETANILIDE tert-Butyl methyl ether Pivaloyl chloride 4-Chloroaniline Ethyl acetate

Sodium bicarbonate

1of2

Preparation Products

1-(2-AMINO-5-CHLOROPHENYL)-2,2,2-TRIFLUOROETHANONE

4'-CHLOROPIVALOANILIDE Suppliers

Global( 98)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49979	58
career henan chemical co	+86-0371-86658258 +8613203830695	factory@coreychem.com	China	29792	58
Alfa Chemistry		info@alfa-chemistry.com	United States	2344	58
Dayang Chem (Hangzhou) Co.,Ltd.	+86-0571-88938639 +8617705817739	info@dycnchem.com	China	52705	58
GIHI CHEMICALS CO.,LIMITED	+86-571-86217390; +8618058761490	info@gihichemicals.com	China	49967	58
Aladdin Scientific		tp@aladdinsci.com	United States	57505	58
Hebei Chuanghai Biotechnology Co., Ltd	+86-15350571055	Sibel@chuanghaibio.com	China	6085	58
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD	+86-13017695106 +86-13676922317	jiuyitime@fdachem.com	China	16513	58
Amadis Chemical Company Limited	571-89925085	sales@amadischem.com	China	131957	58
J & K SCIENTIFIC LTD.	18210857532; 18210857532	jkinfo@jkchemical.com	China	96815	76

Supplier	Advantage
CONIER CHEM AND PHARMA LIMITED	58
career henan chemical co	58
Alfa Chemistry	58
Dayang Chem (Hangzhou) Co.,Ltd.	58
GIHI CHEMICALS CO.,LIMITED	58
Aladdin Scientific	58
Hebei Chuanghai Biotechnology Co., Ltd	58
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD	58
Amadis Chemical Company Limited	58
J & K SCIENTIFIC LTD.	76

View Lastest Price from 4'-CHLOROPIVALOANILIDE manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2020-01-13	4'-CHLOROPIVALOANILIDE 65854-91-3	$1.00	1KG	99%	100KG	Career Henan Chemical Co

4'-CHLOROPIVALOANILIDE
65854-91-3
$1.00
99%
Career Henan Chemical Co

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N-PIVALOYL-P-CHLOROANILINE N-(4-CHLOROPHENYL)-2,2-DIMETHYLPROPIONAMIDE N-(4-CHLOROPHENYL)PIVALOYLAMIDE 4-Chloropivalanilide 4''-CHLOROPIVALOANILIDE,98.0%+(GC) N-Pivaloyl-p-chlorophenyl 4-CHLORO-N-PIVALOYLANILINE 4'-CHLOROPIVALOANILIDE N-(4-Chlorophenyl)-2,2-dimethylpropanamide 4-Chloro-N-pivaloylaniline N-(4-Chlorophenyl)pivaloylamide N-(4-Chlorophenyl)-2,2-dimethylpropionamide N-(4-chlorophenyl)pivalaMide 4'-CHLORO-2,2-DIMETHYLPROPIONANILIDE 4-Chloropivalamide 4'-Chloropivaloanilide> Propanamide, N-(4-chlorophenyl)-2,2-dimethyl- 4'-CHLORO-2,2-DIMETHYLPROPIONANILIDE 4′-Chloropivaloanilide, CAS 65854-91-3 65854-91-3