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4'-Bromovalerophenone

4'-Bromovalerophenone Structure
4'-Bromovalerophenone structure
CAS No.
7295-44-5
Chemical Name:
4'-Bromovalerophenone
Synonyms
4-BROMOVALEROPHENONE;P-BROMOVALEROPHENONE;4'-Bromovalerophenone;The broMobenzene ketone;4' -bromophenopentanone;Valerophenone, 4'-bromo-;p-Bromovalerophenone,98%;4'-Bromovalerophenone>1-Bromo-4-pentanoylbenzene;p-Bromophenyl butyl ketone
CBNumber:
CB5454776
Molecular Formula:
C11H13BrO
Molecular Weight:
241.12
MDL Number:
MFCD00000107
MOL File:
7295-44-5.mol
MSDS File:
SDS
Last updated:2026-09-12 18:53:33
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4'-Bromovalerophenone Properties

Melting point 34-36 °C(lit.)
Boiling point 168-169 °C20 mm Hg(lit.)
Density 1.3366 (rough estimate)
refractive index 1.5290 (estimate)
Flash point >230 °F
storage temp. Sealed in dry,Room Temperature
solubility Chloroform, Ethyl Acetate (Sparingly)
form Solid
color Tan
λmax 325nm(Heptane)(lit.)
InChI InChI=1S/C11H13BrO/c1-2-3-4-11(13)9-5-7-10(12)8-6-9/h5-8H,2-4H2,1H3
InChIKey STYJKBMRWQQJIS-UHFFFAOYSA-N
SMILES C(C1=CC=C(Br)C=C1)(=O)CCCC
CAS DataBase Reference 7295-44-5(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P301+P312-P302+P352-P304+P340-P305+P351+P338
PPE Eyeshields, Gloves, type N95 (US)
Hazard Codes  Xi
Safety Statements  24/25
WGK Germany  3
TSCA  T
HazardClass  IRRITANT
HS Code  29147000
Storage Class 11 - Combustible Solids
NFPA 704
1
0 0

4'-Bromovalerophenone price More Price(43)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 221414 4′-Bromovalerophenone ≥98% 7295-44-5 10g $97.5 2023-01-07 Buy
TCI Chemical B4733 4'-Bromovalerophenone >98.0%(GC) 7295-44-5 5g $21 2026-04-30 Buy
TCI Chemical B4733 4'-Bromovalerophenone >98.0%(GC) 7295-44-5 25g $65 2026-04-30 Buy
TRC TRC-B689025-5G 4'-Bromovalerophenone 7295-44-5 5g $84 2026-06-03 Buy
TRC TRC-B689025-1G 4'-Bromovalerophenone 7295-44-5 1g $65 2026-06-03 Buy
Product number Packaging Price Buy
221414 10g $97.5 Buy
B4733 5g $21 Buy
B4733 25g $65 Buy
TRC-B689025-5G 5g $84 Buy
TRC-B689025-1G 1g $65 Buy

4'-Bromovalerophenone Chemical Properties, Uses, Production

Chemical Properties

yellow crystalline powder

Uses

4′-Bromovalerophenone may be used in chemical synthesis studies.

Uses

4'-Bromovalerophenone is a derivative of Valerophenone, which is an aromatic ketone that is often used as a tool in the study of various photochemical processes. Valerophenone is also an inhibitor of the enzyme carbonyl reductase.

Synthesis

N-BUTYLMAGNESIUM BROMIDE

693-03-8

4-Bromo-N,N-dimethylbenzamide

18469-37-9

4'-BROMOVALEROPHENONE

7295-44-5

GENERAL PROCEDURE: Trifluoromethanesulfonic anhydride (Tf2O, 1.2 eq.) was slowly added dropwise to a solution of 4-bromo-N,N-dimethylbenzamide (1.0 eq.) and 2,6-di-tert-butyl-4-methylpyridine (DTBMP, 1.2 eq.) in dichloromethane (CH2Cl2, 5 mL) cooled to -78 °C. The reaction mixture was gradually warmed up to 0 °C over 2 hours. Subsequently, a solution of butylmagnesium bromide (1.0 eq.) in ether (Et2O) was slowly added dropwise to the reaction mixture at -78 °C and stirring was continued at the same temperature for 2 hours. After completion of the reaction, the reaction was quenched with 15% aqueous hydrochloric acid (5 mL). The organic layer was separated and the aqueous phase was extracted with ether (3 x 5 mL). The organic layers were combined, washed with saturated saline, dried over anhydrous sodium sulfate (Na2SO4), filtered and concentrated under reduced pressure. The residue was purified by silica gel fast column chromatography to obtain the target product 4-bromovalerophenone. For the separation of the by-product N,N-dimethyl-4-bromobenzamide, the aqueous phase was alkalized with 15% aqueous sodium hydroxide (6 mL) and extracted with dichloromethane (3 x 10 mL). The organic layers were combined, dried over anhydrous sodium sulfate (Na2SO4), filtered and concentrated under reduced pressure. The residue was purified by silica gel fast column chromatography to give N,N-dimethyl-4-bromobenzamide.

References

[1] Tetrahedron, 2015, vol. 71, # 24, p. 4248 - 4254

4'-Bromovalerophenone Preparation Products And Raw materials

Raw materials

n-Butylmagnesium bromide 4-Bromo-N,N-dimethylbenzamide Dichloromethane Trifluoromethanesulfonic anhydride 2,6-Di-tert-butyl-4-methylpyridine

Preparation Products

1,1,1-Trifluoro-2-hexanone 4-n-Pentylphenylmagnesium bromide

4'-Bromovalerophenone Suppliers

Global Suppliers ( 141)
Supplier Tel Email Country ProdList Advantage
Shandong INOV New Materials Co., Ltd. 18369999171 sales2@promisechemical.com China 85 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Shijiazhuang Sdyano Fine Chemical Co., Ltd. 0311-89250318 13582355795 master@sjzsdyn.com China 2776 65
Adamas Reagent, Ltd. 400-6009262 15618770481 yhx@titansci.com China 14098 59
Nanjing Chemlin Chemical Co., Ltd 025-83697070 13770331960 info@chemlin.com.cn China 16305 64
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Supplier Advantage
Shandong INOV New Materials Co., Ltd. 58
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
Alfa Aesar 84
TCI (Shanghai) Development Co., Ltd. 81
Energy Chemical 61
Shijiazhuang Sdyano Fine Chemical Co., Ltd. 65
Adamas Reagent, Ltd. 59
Nanjing Chemlin Chemical Co., Ltd 64
Shanghai Hanhong Scientific Co.,Ltd. 64

View Latest Price from 4'-Bromovalerophenone manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4' -bromophenopentanone pictures 2024-08-20 4' -bromophenopentanone
7295-44-5
 $9.00-15.00 1kg 99.9% 50ton Hebei Ganmiao New material Technology Co., LTD
4'-BROMOVALEROPHENONE pictures 2023-08-31 4'-BROMOVALEROPHENONE
7295-44-5
 $100.00 1drum 99 5000 Hebei Fengqiang Trading Co., LTD
4'-BROMOVALEROPHENONE pictures 2020-03-08 4'-BROMOVALEROPHENONE
7295-44-5
 $1.00 1g 99%min 100kg Career Henan Chemical Co

4'-Bromovalerophenone Spectrum

4'-BROMOVALEROPHENONE(7295-44-5)1HNMR4'-BROMOVALEROPHENONE(7295-44-5)FT-IR4'-BROMOVALEROPHENONE(7295-44-5)IR4'-BROMOVALEROPHENONE(7295-44-5)Raman

7295-44-5 (4'-Bromovalerophenone) Related Search:

1-BROMO-4-n-HEPTANOYLBENZENE 4'-Bromovalerophenone Valerophenone 4-Bromopentanophenone cis-2-[2-(4-Bromophenyl)-2-oxoethyl]cyclohexane-1-carboxylic acid
5-(4-Bromophenyl)-5-oxovaleric acid 1-(4-Bromophenyl)-7-chloro-1-oxoheptane 1-(4-Bromophenyl)-6-chloro-1-oxohexane 5-(4-Bromophenyl)-5-oxovaleronitrile Ethyl 5-(4-bromophenyl)-5-oxovalerate
p-Bromophenyl n-heptyl ketone trans-2-[2-(4-Bromophenyl)-2-oxoethyl]cyclopentane-1-carboxylic acid trans-2-(4-Bromobenzoyl)cyclopentane-1-carboxylic acid 2-(2-(4-Bromophenyl)-2-oxoethyl)-5,5-dimethylcyclohexane-1,3-dione cis-2-(4-Bromobenzoyl)-1-cyclohexane-carboxylic acid
trans-2-[2-(4-Bromophenyl)-2-oxoethyl]cyclohexane-1-carboxylic acid Ethyl 6-(4-bromophenyl)-6-oxohexanoate Ethyl 4-(4-bromophenyl)-4-oxo-2-(phenylcarbonyl)butanoate

1of4

P-BROMOVALEROPHENONE 1-(4-Bromophenyl)-1-pentanone p-Bromophenyl butyl ketone Valerophenone, 4'-bromo- 4-BROMOVALEROPHENONE 4'-BROMOVALEROPHENONE, 98+% 1-(4-BROMO-PHENYL)-PENTAN-1-ONE 4-Bromophenyl n-butyl ketone The broMobenzene ketone 1-Bromo-4-pentanoylbenzene p-Bromovalerophenone,98% 4'-Bromovalerophenone> 1-Pentanone, 1-(4-bromophenyl)- 4-Bromophenyl Butyl Ketone 4' -bromophenopentanone 4'-Bromovalerophenone 4′-Bromovalerophenone, CAS 7295-44-5 7295-44-5 BrC6H4COCH23CH3 ARYL HALIDE Building Blocks Carbonyl Compounds C11 to C12 Organic Building Blocks Ketones C11 to C12 Carbonyl Compounds Ketones 7295-44-5