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D-2-Bromophenylalanine

D-2-Bromophenylalanine Structure
D-2-Bromophenylalanine structure
CAS No.
267225-27-4
Chemical Name:
D-2-Bromophenylalanine
Synonyms
2-BROMO-D-PHENYLALANINE;H-D-PHE(2-BR)-OH;D-2-Br-Phe;D-2-BROMOPHE;D-2-Br-Phe-OH;D-Phe(2-Br)-OH;D-2-Bromo-phe-OH;H-O-BROMO-D-PHE-OH;RARECHEM BK PT 0040;D-2-BROMOPHENYLALANINE
CBNumber:
CB5477793
Molecular Formula:
C9H10BrNO2
Molecular Weight:
244.09
MDL Number:
MFCD03092959
MOL File:
267225-27-4.mol
MSDS File:
SDS
Last updated:2026-07-27 08:50:42
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D-2-Bromophenylalanine Properties

Melting point 216-218 °C
Boiling point 363.2±32.0 °C(Predicted)
Density 1.588±0.06 g/cm3(Predicted)
storage temp. Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
form Powder
pka 2.16±0.10(Predicted)
color White to off-white
InChI InChI=1S/C9H10BrNO2/c10-7-4-2-1-3-6(7)5-8(11)9(12)13/h1-4,8H,5,11H2,(H,12,13)/t8-/m1/s1
InChIKey JFVLNTLXEZDFHW-MRVPVSSYSA-N
SMILES C(O)(=O)[C@@H](CC1=CC=CC=C1Br)N
CAS DataBase Reference 267225-27-4(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Hazard Codes  Xi
HS Code  2922498590
NFPA 704
1
0 0

D-2-Bromophenylalanine price More Price(70)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Usbiological 265215 2-Bromo-D-phenylalanine Asreported 267225-27-4 500mg $368 2026-06-03 Buy
Usbiological 265215 2-Bromo-D-phenylalanine Asreported 267225-27-4 1g $605 2026-06-03 Buy
Usbiological 265215 2-Bromo-D-phenylalanine Asreported 267225-27-4 2g $848 2026-06-03 Buy
Usbiological 265215 2-Bromo-D-phenylalanine Asreported 267225-27-4 5g $1700 2026-06-03 Buy
Usbiological 265215 2-Bromo-D-phenylalanine Asreported 267225-27-4 10g $2515 2026-06-03 Buy
Product number Packaging Price Buy
265215 500mg $368 Buy
265215 1g $605 Buy
265215 2g $848 Buy
265215 5g $1700 Buy
265215 10g $2515 Buy

D-2-Bromophenylalanine Chemical Properties, Uses, Production

Chemical Properties

White to off-white powder

Synthesis

Benzenepropanoic acid, 2-broMo-.alpha.-oxo-

120240-65-5

2,2-Diphenylglycine

3060-50-2

Benzophenone

119-61-9

D-2-Bromophenylalanine

267225-27-4

L-2-Bromophenylalanine

42538-40-9

The general procedure for the synthesis of benzophenone, (R)-2-amino-3-(2-bromophenyl)propionic acid and (S)-2-amino-3-(2-bromophenyl)propionic acid from 3-(2-bromophenyl)-2-oxopropionic acid and 2,2-diphenylglycine is as follows: to a 5 mL reaction vial equipped with a magnetic stirrer, 3-(2-bromophenyl)-2-oxopropionic acid (0.0510 g , 0.30 mmol), 2,2-diphenylglycine (0.0681 g, 0.30 mmol), chiral pyridoxamine 6 g (0.0195 g, 0.030 mmol), and MeOH-H2O (8:2, 3.0 mL). The reaction mixture was stirred at 20 °C for 3 days. Subsequently, the reaction mixture was transferred to a 25 mL round-bottomed flask and MeOH was added until all solids were completely dissolved. Next, silica gel (0.50 g) was added. After the solvent was removed by concentration under reduced pressure at 20 °C, the resulting residue was separated by silica gel column chromatography (eluent ratio EtOH/Ethyl acetate/25-28% ammonia = 100:58:16) to afford compound 3j (0.0401 g, 78% yield, 52% ee) as a white solid. To determine the enantiomeric excess of 3b-k, it was treated by thionyl chloride in methanol and subsequently converted to N-benzoylmethyl ester by reaction with benzoyl chloride and finally analyzed by HPLC. For the determination of the enantiomeric excess of 3a, it was converted to methyl ester by treatment with CH2N2 in methanol and then analyzed by HPLC.

References

[1] Tetrahedron Letters, 2016, vol. 57, # 41, p. 4612 - 4615

D-2-Bromophenylalanine Preparation Products And Raw materials

Raw materials

Benzenepropanoic acid, 2-broMo-.alpha.-oxo- 2,2-Diphenylglycine

Preparation Products

D-2-Bromophenylalanine Suppliers

Global Suppliers ( 178)
Supplier Tel Email Country ProdList Advantage
SICHUAN TONGSHENG BIOPHARMACEUTICAL CO., LTD 0838-2809458 13350585791 pharm@biots.cn China 778 58
Suzhou haiyu Biochem Industrial Co., LTD 512-68097639 18013585858 744942877@qq.com China 915 62
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Shanghai HC Biotech Co., Ltd 021-20227858 sale@hcbiotech.com.cn China 1173 55
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
Capot Chemical Co., Ltd +86 (0) 571 85 58 67 18 China 18187 66
Pure Chemistry Scientific Inc. 001-857-928-2050 or 1-888-588-9418 sales@chemreagents.com United States 10174 62
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
China DongFan Chemical Co.,LTD 86-0571-85151182 China 5681 66
Supplier Advantage
SICHUAN TONGSHENG BIOPHARMACEUTICAL CO., LTD 58
Suzhou haiyu Biochem Industrial Co., LTD 62
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
Shanghai HC Biotech Co., Ltd 55
Alfa Aesar 84
Capot Chemical Co., Ltd 66
Pure Chemistry Scientific Inc. 62
Shanghai Hanhong Scientific Co.,Ltd. 64
China DongFan Chemical Co.,LTD 66

View Latest Price from D-2-Bromophenylalanine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
D-2-Bromophenylalanine pictures 2019-07-06 D-2-Bromophenylalanine
267225-27-4
 $3.00 1KG 99% 100kg Career Henan Chemical Co

D-2-Bromophenylalanine Spectrum

D-2-Bromophenylalanine(267225-27-4)1HNMR

267225-27-4 (D-2-Bromophenylalanine) Related Search:

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2-Methylphenyl-D-alanine H-D-Phe(3-NO2)-OH.HCl D-2,4-Dimethylphe

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H-O-BROMO-D-PHE-OH D-2-BROMOPHE D-2-BROMOPHENYLALANINE (R)-2-AMINO-3-(2-BROMO-PHENYL)-PROPIONIC ACID RARECHEM BK PT 0040 (2R)-2-amino-3-(2-bromophenyl)propanoic acid D-2-Br-Phe-OH (R)-2-Amino-3-(2'-bromophenyl)propanoic acid D-2-Bromo-phe-OH D-2-Br-Phe-OH 2-BroMo-D-Phenylalanine D-2-Br-Phe 2-Bromo-D-phenylalanine≥ 99.5% (HPLC, Chiral purity) D-Phe(2-Br)-OH 2-Bromo-D-phenylalanine 98% 2-Bromophenyl-D-alanine o-Bromo-D-phenylalanine D-Phenylalanine, 2-bromo- 2-Bromo-D-phenylalanine,95% (2R)-2-amino-3-(2-bromophenyl)propanoicaci D-2-Bromophenylalanine USP/EP/BP (R)-2-Amino-3-(2-bromophenyl)propanoic acid - [A71998] 2-BROMO-D-PHENYLALANINE H-D-PHE(2-BR)-OH 267225-27-4 Phenylalanine analogs and other aromatic alpha amino acids Amino Acids Chiral Reagent a-amino Amino Acid Derivatives