5-Hydroxy-2-nitrobenzyl alcohol
- CAS No.
- 60463-12-9
- Chemical Name:
- 5-Hydroxy-2-nitrobenzyl alcohol
- Synonyms
- 3-(Hydroxymethyl)-4-nitrophenol;RARECHEM AL BD 0679;5-Hydroxy-2-nitrobenzyl alcohol;2-Nitro-5-hydroxybenzyl alcohol;5-Hydroxy-2-nitrobenzenemethanol;2-Nitro-5-hydroxybenzenemethanol;(5-Hydroxy-2-nitrophenyl)methanol;Benzenemethanol,5-hydroxy-2-nitro-;5-Hydroxy-2-nitrobenzyl alcohol 97%;5-HYDROXY-2-NITROBENZYL ALCOHOL ISO 9001：2015 REACH
- CBNumber:
- CB5682168
- Molecular Formula:
- C7H7NO4
- Molecular Weight:
- 169.13
- MDL Number:
- MFCD00134308
- MOL File:
- 60463-12-9.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 111-115 °C (lit.) |
|---|---|
| Boiling point | 398.6±32.0 °C(Predicted) |
| Density | 1.489±0.06 g/cm3(Predicted) |
| storage temp. | Sealed in dry,Room Temperature |
| pka | 6.99±0.10(Predicted) |
| Appearance | Light brown to gray Solid |
| InChI | 1S/C7H7NO4/c9-4-5-3-6(10)1-2-7(5)8(11)12/h1-3,9-10H,4H2 |
| InChIKey | ODWVFIWBWJXDMT-UHFFFAOYSA-N |
| SMILES | OCc1cc(O)ccc1[N+]([O-])=O |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 |
| target organs | Respiratory system |
| PPE | dust mask type N95 (US), Eyeshields, Gloves |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-37/39 |
| WGK Germany | 3 |
| Storage Class | 11 - Combustible Solids |
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
5-Hydroxy-2-nitrobenzyl alcohol price More Price(39)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 366005 | 5-Hydroxy-2-nitrobenzyl alcohol 97% | 60463-12-9 | 5g | $439 | 2026-04-30 | Buy |
| TRC | TRC-H973090-50MG | 3-(Hydroxymethyl)-4-nitrophenol | 60463-12-9 | 50mg | $84 | 2026-06-03 | Buy |
| TRC | TRC-H973090-25MG | 3-(Hydroxymethyl)-4-nitrophenol | 60463-12-9 | 25mg | $65 | 2026-06-03 | Buy |
| TRC | TRC-H973090-250MG | 3-(Hydroxymethyl)-4-nitrophenol | 60463-12-9 | 250mg | $129 | 2026-06-03 | Buy |
| Biosynth | KCA46312 | 5-Hydroxy-2-nitrobenzyl alcohol | 60463-12-9 | 5g | $295 | 2026-06-04 | Buy |
5-Hydroxy-2-nitrobenzyl alcohol Chemical Properties, Uses, Production
Uses
5-Hydroxy-2-nitrobenzyl alcohol may be used in the synthesis of 5-(2′-(dimethylamino)ethoxy)-2-nitrobenzyl alcohol. It may be used as difunctional photo-responsive initiator in the synthesis of thermo-responsive and photo-cleavable amphiphilic block copolymers containing photodegradable linkers as junction points between hydrophilic and hydrophobic chains.
Synthesis
42454-06-8
60463-12-9
General procedure for the synthesis of 5-hydroxy-2-nitrobenzaldehyde from 5-hydroxy-2-nitrobenzenemethanol: Sodium borohydride (1.4 g, 37.84 mmol) was slowly added to a solution of 5-hydroxy-2-nitrobenzaldehyde (4.07 g, 24.35 mmol) in methanol (30 mL) while the reaction mixture was cooled in an ice water bath. After the addition was completed, the reaction mixture was stirred at room temperature for 1 hour. Upon completion of the reaction, the solvent was removed by distillation under reduced pressure and the residue was recrystallized in methanol to give 4.0 g (23.62 mmol, 97% yield) of 5-hydroxy-2-nitrobenzyl alcohol.
References
[1] Angewandte Chemie - International Edition, 2006, vol. 45, # 17, p. 2753 - 2757
[2] Patent: US2007/213278, 2007, A1. Location in patent: Page/Page column 29; Sheet 9
[3] Journal of Polymer Science, Part A: Polymer Chemistry, 2013, vol. 51, # 20, p. 4309 - 4316
[4] Journal of Organic Chemistry, 1998, vol. 63, # 8, p. 2434 - 2441
[5] Chemistry - A European Journal, 2015, vol. 21, # 5, p. 1873 - 1877
5-Hydroxy-2-nitrobenzyl alcohol Preparation Products And Raw materials
5-Hydroxy-2-nitrobenzyl alcohol Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Syntechem Co.,Ltd | info@syntechem.com | China | 12973 | 57 | |
| Nanjing ShengSai Chemical Co., Ltd. | 025-85205967 13951876367 | shengsaichem@163.com | China | 818 | 58 |
| Bide Pharmatech Ltd. | 400-164-7117 18317119277 | product02@bidepharm.com | China | 40000 | 60 |
| Quzhou synpartner PharmaTech co.,ltd | 0570-3856196 13615701454 | Bella@synpartner.com | China | 67 | 65 |
| Finetech Industry Limited | 027-87465837 19945049750 | sales@finetechnology-ind.com | China | 9331 | 58 |
| Mashilabs (Shanghai) Co.,Ltd. | 19916721580 | mafarm@126.com | China | 4538 | 58 |
| Shanghai Xingui Biotechnology Co., Ltd. | 15121041756 | xingui2022@126.com | China | 9985 | 58 |
View Latest Price from 5-Hydroxy-2-nitrobenzyl alcohol manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-08-20 | 5-HYDROXY-2-NITROBENZYL ALCOHOL
60463-12-9
|
$1.10 | 1g | 99.00% | 100 Tons Min | Dideu Industries Group Limited |
-
- 5-HYDROXY-2-NITROBENZYL ALCOHOL
60463-12-9
- $1.10
- 99.00%
- Dideu Industries Group Limited
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