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POTASSIUM 4-BROMOPHENYLTRIFLUOROBORATE

CAS No.
374564-35-9
Chemical Name:
POTASSIUM 4-BROMOPHENYLTRIFLUOROBORATE
Synonyms
Potassium (4-bromophenyl);POTASSIUM 4-BROMOPHENYLTRIFLUOROBORATE;Potassium(4-bromophenyl)trifluoroborate96%;POTASSIUM (4-BROMOROPHENYL)TRIFLUOROBORATE;potassium (4-bromophenyl)-trifluoroboranuide;Potassium (4-bromophenyl)trifluoroborate 96%;4-bromophenyltrifluoroboric acid potassium salt;4-bromobenzenetrifluoroboric acid potassium salt;POTASSIUM 4-BROMOPHENYLTRIFLUOROBORATE ISO 9001:2015 REACH;4-Bromobenzenetrifluoroboric acid potassium salt~4-Bromophenyltrifluoroboric acid potassium salt
CBNumber:
CB5687406
Molecular Formula:
C6H4BBrF3K
Molecular Weight:
262.9
MDL Number:
MFCD02093978
MOL File:
374564-35-9.mol
MSDS File:
SDS
Last updated:2026-05-28 01:29:22
Product description Number Pack Size Price
Potassium (4-Bromophenyl)trifluoroborate P2647 1G $34
Potassium (4-Bromophenyl)trifluoroborate P2647 5G $110
Potassium (4-bromophenyl)trifluoroborate ≥97% CS-0041331 5g $12
Potassium (4-bromophenyl)trifluoroborate >98% PC1749 5g $21
Potassium (4-bromophenyl)trifluoroborate ≥97% CS-0041331 10g $25
More product size

POTASSIUM 4-BROMOPHENYLTRIFLUOROBORATE Properties

Melting point >300 °C(lit.)
storage temp. Inert atmosphere,Room Temperature
form powder to crystal
color White to Almost white
Water Solubility Soluble in water.
BRN 9297533

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
Hazard Note  Irritant
HS Code  2931900090
NFPA 704
1
2 0

POTASSIUM 4-BROMOPHENYLTRIFLUOROBORATE price More Price(57)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical P2647 Potassium (4-Bromophenyl)trifluoroborate 374564-35-9 1G $34 2026-04-30 Buy
TCI Chemical P2647 Potassium (4-Bromophenyl)trifluoroborate 374564-35-9 5G $110 2026-04-30 Buy
ChemScene CS-0041331 Potassium (4-bromophenyl)trifluoroborate ≥97% 374564-35-9 5g $12 2026-06-04 Buy
Apolloscientific PC1749 Potassium (4-bromophenyl)trifluoroborate >98% 374564-35-9 5g $21 2026-06-04 Buy
ChemScene CS-0041331 Potassium (4-bromophenyl)trifluoroborate ≥97% 374564-35-9 10g $25 2026-06-04 Buy
Product number Packaging Price Buy
P2647 1G $34 Buy
P2647 5G $110 Buy
CS-0041331 5g $12 Buy
PC1749 5g $21 Buy
CS-0041331 10g $25 Buy

POTASSIUM 4-BROMOPHENYLTRIFLUOROBORATE Chemical Properties,Uses,Production

Uses

Potassium 4-bromophenyltrifluoroborate is used as potent boronic acid surrogates in Suzuki-Miyaura Cross-Coupling reactions.

Synthesis

4-Bromophenylboronic acid

5467-74-3

POTASSIUM 4-BROMOPHENYLTRIFLUOROBORATE

374564-35-9

GENERAL STEPS: In a reaction vessel equipped with a charging funnel, 4-bromophenylboronic acid (5 mmol) was dissolved in methanol (10 mL). A solution of potassium hydrogen fluoride (KHF2, 1.56 g, 20 mmol) in water (8 mL) was added slowly and dropwise. The reaction mixture was stirred at room temperature for 30 min. Subsequently, the mixture was concentrated under high vacuum to remove the solvent. The residual solid was extracted with an acetone solution of 20% methanol (4 x 10 mL). The extracts were combined, concentrated to near saturation, and then ether (Et2O) was added until no further precipitate was produced. The precipitate was collected by filtration, washed with ether (2 × 10 mL), and finally dried under high vacuum to give a potassium 4-bromophenyl trifluoroborate product of sufficient purity for subsequent characterization.

References

[1] Journal of the American Chemical Society, 2008, vol. 130, # 47, p. 15792 - 15793
[2] Tetrahedron Letters, 2012, vol. 53, # 32, p. 4240 - 4242

5467-74-3
374564-35-9
Synthesis of POTASSIUM 4-BROMOPHENYLTRIFLUOROBORATE from 4-Bromophenylboronic acid

POTASSIUM 4-BROMOPHENYLTRIFLUOROBORATE Preparation Products And Raw materials

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Capot Chemical Co.,Ltd.
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J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62

View Lastest Price from POTASSIUM 4-BROMOPHENYLTRIFLUOROBORATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
POTASSIUM 4-BROMOPHENYLTRIFLUOROBORATE pictures 2020-01-14 POTASSIUM 4-BROMOPHENYLTRIFLUOROBORATE
374564-35-9
$7.00 1KG 99% 1000kg Career Henan Chemical Co

POTASSIUM 4-BROMOPHENYLTRIFLUOROBORATE Spectrum

potassium (4-bromophenyl)-trifluoroboranuide POTASSIUM 4-BROMOPHENYLTRIFLUOROBORATE POTASSIUM (4-BROMOROPHENYL)TRIFLUOROBORATE 4-Bromobenzenetrifluoroboric acid potassium salt~4-Bromophenyltrifluoroboric acid potassium salt 4-bromobenzenetrifluoroboric acid potassium salt 4-bromophenyltrifluoroboric acid potassium salt Potassium (4-bromophenyl)trifluoroborate 96% Potassium(4-bromophenyl)trifluoroborate96% Potassium (4-bromophenyl) POTASSIUM 4-BROMOPHENYLTRIFLUOROBORATE ISO 9001:2015 REACH 374564-35-9 BrC6H4BF3K Boronic Acids and Derivatives Aryl Trifluoroborate Salts Organometallic Reagents blocks Trifluoroborates Aryl Boronic Acids and Derivatives Trifluoroborate Salts Aryl Trifluoroborate Salts Boronic Acids and Derivatives Chemical Synthesis Organometallic Reagents Trifluoroborate Salts alkyl bromide| Boric Acid| Boric Acid Ester| Potassium Trifluoroborate