2-Formylbenzeneboronic acid
- CAS No.
- 40138-16-7
- Chemical Name:
- 2-Formylbenzeneboronic acid
- Synonyms
- 2-FORMYLPHENYLBORONIC ACID;2-FPBA;NSC 157839;AKOS BRN-0109;RARECHEM AH PB 0192;2-Formylbenzeneboron;2-BORONOBENZALDEHYDE;2-formylphenylboronic;ForMylphenylboronic aci;Formylbenzeneboronic acid
- CBNumber:
- CB6352866
- Molecular Formula:
- C7H7BO3
- Molecular Weight:
- 149.94
- MDL Number:
- MFCD00151822
- MOL File:
- 40138-16-7.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 2-Formylphenylboronic acid ≥95.0% | 431958 | 1g | $52.4 |
| 2-Formylphenylboronic acid ≥95.0% | 431958 | 5g | $131 |
| 2-Formylphenylboronic Acid (contains varying amounts of Anhydride) | B1873 | 1g | $30 |
| 2-Formylphenylboronic Acid (contains varying amounts of Anhydride) | B1873 | 5g | $85 |
| 2-Formylphenylboronic acid | F701493 | 100mg | $70 |
| More product size | |||
| Melting point | 115-120 °C (lit.) |
|---|---|
| Boiling point | 355.7±44.0 °C(Predicted) |
| Density | 1.24±0.1 g/cm3(Predicted) |
| storage temp. | 2-8°C |
| solubility | Soluble in methanol. |
| pka | 8.18±0.53(Predicted) |
| form | Crystalline Powder or Needles and Chunks |
| color | Light yellow to light orange-pink |
| Sensitive | Air Sensitive |
| BRN | 3030776 |
| InChI | 1S/C7H7BO3/c9-5-6-3-1-2-4-7(6)8(10)11/h1-5,10-11H |
| InChIKey | DGUWACLYDSWXRZ-UHFFFAOYSA-N |
| SMILES | OB(O)c1ccccc1C=O |
| CAS DataBase Reference | 40138-16-7(CAS DataBase Reference) |
| FDA UNII | MT69HY4FNF |
| UNSPSC Code | 12352103 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36 | |||||||||
| WGK Germany | 3 | |||||||||
| HazardClass | IRRITANT | |||||||||
| HS Code | 29319090 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
|||||||||
| NFPA 704 |
|
2-Formylbenzeneboronic acid price More Price(45)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 431958 | 2-Formylphenylboronic acid ≥95.0% | 40138-16-7 | 1g | $52.4 | 2026-03-19 | Buy |
| Sigma-Aldrich | 431958 | 2-Formylphenylboronic acid ≥95.0% | 40138-16-7 | 5g | $131 | 2026-03-19 | Buy |
| TCI Chemical | B1873 | 2-Formylphenylboronic Acid (contains varying amounts of Anhydride) | 40138-16-7 | 1g | $30 | 2026-03-19 | Buy |
| TCI Chemical | B1873 | 2-Formylphenylboronic Acid (contains varying amounts of Anhydride) | 40138-16-7 | 5g | $85 | 2026-03-19 | Buy |
| TRC | F701493 | 2-Formylphenylboronic acid | 40138-16-7 | 100mg | $70 | 2021-12-16 | Buy |
2-Formylbenzeneboronic acid Chemical Properties,Uses,Production
Chemical Properties
light yellow to light orange-pink crystalline
Uses
suzuki reaction
Uses
2-Formylbenzeneboronic acid is used as an organic chemical synthesis intermediate.
Synthesis
1229227-01-3
68-12-2
40138-16-7
Under nitrogen protection, o-bromophenylboronic acid trimer (cas:1229227-01-3) was added to anhydrous tetrahydrofuran (600 mL). The mixture was transferred to a 2 L three-neck flask and N,N-dimethylformamide (87.7 g, 1.2 mol) was added. Subsequently, the reaction system was cooled to -70 °C to -80 °C and 2.5 M n-butyllithium hexane solution (520 mL, 1.3 mol) was slowly added dropwise with controlled titration rate to keep the reaction temperature from exceeding -70 °C. Stirring was continued at this temperature for 1-3 h. The reaction mixture was then allowed to warm up to room temperature naturally, and stirring was continued for another 3-5 h. The reaction was monitored by TLC. The progress of the reaction was monitored by TLC and after confirming the completion of the reaction, the system was cooled to 0°C, 15% aqueous hydrochloric acid was added to quench the reaction, and the pH was adjusted to 1-2. Stirring was continued at room temperature for 3-5 h to ensure complete hydrolysis of the trimer. Subsequently, the reaction solution was distilled to remove the organic solvent and filtered to obtain the solid product. Finally, purification by recrystallization from toluene gave 93.0 g of light gray solid 2-formylphenylboronic acid with 99.0% HPLC purity and 62% yield.
References
[1] Patent: CN105037408, 2017, B. Location in patent: Paragraph 0028; 0031; 0032
2-Formylbenzeneboronic acid Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
1of2
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shaanxi Dideu Medichem Co. Ltd | +86-29-81139210 +86-18192627656 | 1059@dideu.com | China | 3590 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20124 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718; +8613336195806 | sales@capot.com | China | 29640 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 13815 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21592 | 55 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3009 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29821 | 58 |
| Shanghai Arbor Chemical Co., Ltd. | 021-60451682 | act@arborchemical.com | CHINA | 904 | 58 |
| Jinan Carbotang Biotech Co.,Ltd. | +8615866703830 | figo.gao@foxmail.com | China | 8497 | 58 |
View Lastest Price from 2-Formylbenzeneboronic acid manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-04-21 | 2-FPBA
40138-16-7
|
US $2500.00-1980.00 / mg | 10g | TargetMol Chemicals Inc. | |||
 |
2025-12-12 | 2-Formylbenzeneboronic acid
40138-16-7
|
US $1.00-100.00 / KG | 1KG | 95% | 300KG | Shaanxi Dideu Medichem Co. Ltd | |
 |
2025-09-25 | 2-Formylbenzeneboronic acid
40138-16-7
|
US $34.00-1.20 / kg | 1kg | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd |
-
- 2-FPBA
40138-16-7
- US $2500.00-1980.00 / mg
- TargetMol Chemicals Inc.
-
- 2-Formylbenzeneboronic acid
40138-16-7
- US $1.00-100.00 / KG
- 95%
- Shaanxi Dideu Medichem Co. Ltd
-
- 2-Formylbenzeneboronic acid
40138-16-7
- US $34.00-1.20 / kg
- 99%
- Henan Fengda Chemical Co., Ltd
