ChemicalBook >> CAS DataBase List >>9,9-Dihexyl-2,7-dibromofluorene

9,9-Dihexyl-2,7-dibromofluorene

9,9-Dihexyl-2,7-dibromofluorene structure

CAS No.: 189367-54-2

Chemical Name:: 9,9-Dihexyl-2,7-dibromofluorene

Synonyms: M8034;9,9-DihexyL;-2,7-dibromofL;9,9-Dihexyl-2,7-dibr;9,9-Dihexyl-2,7-dibromofluorene;2,7-DibroMo-9,9-dihexyl fluorine;2,7-Dibromo-9,9-dihexylfluorene>2,7-dibromo-9,9-di-n-hexylfluorene;9 9-DIHEXYL-2 7-DIBROMOFLUORENE 97;9,9-dihexyl-2,7-dibromine generation

CBNumber:: CB6504858

Molecular Formula:: C25H32Br2

Molecular Weight:: 492.33

MDL Number:: MFCD03427215

MOL File:: 189367-54-2.mol

MSDS File:: SDS

Last updated:2026-05-28 05:32:42

Request For Quotation

9,9-Dihexyl-2,7-dibromofluorene Properties

Melting point	67-71 °C(lit.)
Boiling point	0°C
Density	1.274±0.06 g/cm3(Predicted)
Flash point	0°C
storage temp.	Sealed in dry,Room Temperature
form	powder to crystal
color	White to Almost white
Water Solubility	Slightly soluble in water.
InChI	InChI=1S/C25H32Br2/c1-3-5-7-9-15-25(16-10-8-6-4-2)23-17-19(26)11-13-21(23)22-14-12-20(27)18-24(22)25/h11-14,17-18H,3-10,15-16H2,1-2H3
InChIKey	OXFFIMLCSVJMHA-UHFFFAOYSA-N
SMILES	C1(CCCCCC)(CCCCCC)C2=C(C=CC(Br)=C2)C2=C1C=C(Br)C=C2
UNSPSC Code	12352103
NACRES	NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319

Precautionary statements

P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P

PPE

Eyeshields, Gloves, type N95 (US)

Safety Statements

22-24/25

WGK Germany

HS Code

29039990

Storage Class

11 - Combustible Solids

NFPA 704

	1
0		0

9,9-Dihexyl-2,7-dibromofluorene price More Price(51)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	560065	9,9-Dihexyl-2,7-dibromofluorene 97%	189367-54-2	25g	$328	2023-06-20	Buy
TCI Chemical	D3933	2,7-Dibromo-9,9-dihexylfluorene >98.0%(HPLC)	189367-54-2	5g	$39	2026-04-30	Buy
TCI Chemical	D3933	2,7-Dibromo-9,9-dihexylfluorene >98.0%(HPLC)	189367-54-2	25g	$153	2026-04-30	Buy
Biosynth	FD62377	2,7-Dibromo-9,9-dihexylfluorene	189367-54-2	50g	$900	2026-06-04	Buy
Biosynth	FD62377	2,7-Dibromo-9,9-dihexylfluorene	189367-54-2	500g	$900	2026-06-04	Buy

Product number	Packaging	Price	Buy
560065	25g	$328	Buy
D3933	5g	$39	Buy
D3933	25g	$153	Buy
FD62377	50g	$900	Buy
FD62377	500g	$900	Buy

9,9-Dihexyl-2,7-dibromofluorene Chemical Properties,Uses,Production

Chemical Properties

White to brown crystal or powder

Uses

It finds its application as an intermediate for polymeric light-emitting diodes and as an OLED material because of their pure blue emission and efficient electroluminescence coupled with a high charge-carrier mobility and good process ability.

General Description

Intermediate for polymeric light-emitting diodes.

Synthesis

111-25-1

16433-88-8

189367-54-2

General procedure for the synthesis of 9,9-dihexyl-2,7-dibromofluorene from 2,7-dibromofluorene and 1-bromohexane: 2,7-dibromofluorene (1.5 g), and triethylbenzylammonium chloride (0.009 g) were suspended in 30 mL of dimethylsulfoxide in a triple-necked flask. 1.5 mL of 50 wt% aqueous sodium hydroxide solution was slowly added dropwise and the reaction was carried out for 30 min followed by the addition of 1.59 g of 1-bromohexane dropwise. The reaction mixture was stirred at room temperature for 3 h. After completion of the reaction, it was extracted with ether. The organic phase was sequentially washed with saturated brine and dried over anhydrous magnesium sulfate. The solvent was removed by distillation under reduced pressure and the resulting crude product was recrystallized from aqueous ethanol to give orange needle-like crystals of 2,7-dibromo-9,9-dihexylfluorene (1.96 g) in 86% yield.

References

[1] Journal of Organic Chemistry, 2010, vol. 75, # 8, p. 2714 - 2717
[2] Macromolecules, 2003, vol. 36, # 19, p. 6995 - 7003
[3] Chemical Communications, 2008, # 32, p. 3765 - 3767
[4] Macromolecules, 2003, vol. 36, # 19, p. 6970 - 6975
[5] Tetrahedron Letters, 2007, vol. 48, # 1, p. 89 - 93

9,9-Dihexyl-2,7-dibromofluorene Preparation Products And Raw materials

Raw materials

1-Bromohexane 9,9-Dihexylfluorene 1-Chlorohexane 2,7-Dibromofluorene Sodium hydroxide

Benzyltriethylammonium chloride Dimethyl sulfoxide

1of2

Preparation Products

9,9-Dihexyl-2,7-dibromofluorene Suppliers

Global( 211)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
J & K SCIENTIFIC LTD.	18210857532 18210857532	jkinfo@jkchemical.com	China	96815	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	4006356688 18621169109	market03@meryer.com	China	40202	62
future industrial shanghai co., ltd	400-0066400 13621662912	sales@jonln.com	China	1989	65
Alfa Aesar	400-6106006	saleschina@alfa-asia.com	China	30103	84
TCI (Shanghai) Development Co., Ltd.	021-67121386	Sales-CN@TCIchemicals.com	China	24512	81
Energy Chemical	400-0056266	sales8178@energy-chemical.com	China	44850	61
JinYan Chemicals(ShangHai) Co.,Ltd.	13817811078	sales@jingyan-chemical.com	China	9963	60
Puyang Huicheng Electronic Material Co. Ltd.	0393-0393-8910800 15036113989	info@huichengchem.com	China	588	64
Adamas Reagent, Ltd.	400-6009262 15618770481	yhx@titansci.com	China	14098	59
Accela ChemBio Co.,Ltd.	021-50795510 4000665055	marketing@accelachem.com	China	10972	64

Supplier	Advantage
J & K SCIENTIFIC LTD.	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	62
future industrial shanghai co., ltd	65
Alfa Aesar	84
TCI (Shanghai) Development Co., Ltd.	81
Energy Chemical	61
JinYan Chemicals(ShangHai) Co.,Ltd.	60
Puyang Huicheng Electronic Material Co. Ltd.	64
Adamas Reagent, Ltd.	59
Accela ChemBio Co.,Ltd.	64

View Lastest Price from 9,9-Dihexyl-2,7-dibromofluorene manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-09-11	2,7-Dibromo-9,9-dihexyl-9H-fluorene 189367-54-2	$15.00-209.00	5g	0.99	10kg	Shanghai UCHEM Inc.
2026-09-02	2,7-Dibromo-9,9-dihexylfluorene 189367-54-2	$1.00-200.00	1KG	99%, 99.5% Sublimated		Henan Fengda Chemical Co., Ltd
2026-08-18	9,9-Dihexyl-2,7-dibromofluorene 189367-54-2		1KG	98%	150KG /month	Shanghai Daken Advanced Materials Co.,Ltd

2,7-Dibromo-9,9-dihexyl-9H-fluorene
189367-54-2
$15.00-209.00
0.99
Shanghai UCHEM Inc.

2,7-Dibromo-9,9-dihexylfluorene
189367-54-2
$1.00-200.00
99%, 99.5% Sublimated
Henan Fengda Chemical Co., Ltd

9,9-Dihexyl-2,7-dibromofluorene
189367-54-2
$0.00
98%
Shanghai Daken Advanced Materials Co.,Ltd

9,9-Dihexyl-2,7-dibromofluorene Spectrum

9,9-Dihexyl-2,7-dibromofluorene(189367-54-2)¹HNMR

189367-54-2(9,9-Dihexyl-2,7-dibromofluorene)Related Search:

2,2-Bis(bromomethyl)propane-1,3-diol 1,3-Dibromo-5,5-dimethylhydantoin 1,2-Dibromopropane DBDCB 2,4-DIBROMOBIPHENYL

1,2-Dibromoethylene 9,9-Bis(4-aminophenyl)fluorene 9-Bromo-7,7-dimethyl-7H-benzo[c]fluorene 2-Bromo-9,9-dimethylfluorene 2-Bromo-9,9-diphenylfluorene

Dibenzo[b,d]furan-2-ylboronic acid 9,9-Dichlorofluorene 2,7-Dibromofluorene 9,9-dihexyl-2,7-dibromofluorene homopolymer dibromoethyl alcohol

9,9-DIDODECYL-2 7-DIBROMOFLUORENE 9,9-Dioctyl-2,7-dibromofluorene 9,9-Dihexyl-2,7-dibromofluorene

1of4

9 9-DIHEXYL-2 7-DIBROMOFLUORENE 97 9,9-Dihexyl-2,7-dibromofluorene 9,9-Dihexyl-2,7-dibr 2,7-DibroMo-9,9-dihexyl fluorine 2,7-Dibromo-9,9-di(1-hexyl)-9H-fluorene 9,9-Di-n-hexyl-2,7-dibroMofluorene, 98% 2,7-DibroMo-9,9-dihexylfluorene,9,9-dihexyl-2,7-dibroMofluorene 9H-Fluorene, 2,7-dibroMo-9,9-dihexyl- 2,7-Dibromo-9,9-dihexylfluorene> 9,9-Dihexyl-2,7-dibromofluorene, 98%, reagent grade 9,9-DihexyL -2,7-dibromofL M8034 2,7-dibromo-9,9-di-n-hexylfluorene 9,9-dihexyl-2,7-dibromine generation 189367-54-2 C25H32Br2 Fluorene Series OLED materials,pharm chemical,electronic Fluorene Derivatives Polyfluorene (PFO, PFE) Monomers Synthetic Tools and Reagents Organic Electronics and Photonics