Tetramethoxymethane
- CAS No.
- 1850-14-2
- Chemical Name:
- Tetramethoxymethane
- Synonyms
- TETRAMETHYL ORTHOCARBONATE;NSC 359558;Dimethoxymethylal;TETRAMETHOXYMETHANE;Methane, tetramethoxy-;Tetramethyl orthocarbonate 98%;Orthocarbonic acid, tetramethyl ester
- CBNumber:
- CB6746771
- Molecular Formula:
- C5H12O4
- Molecular Weight:
- 136.15
- MDL Number:
- MFCD00008473
- MOL File:
- 1850-14-2.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | -5 °C (lit.) |
|---|---|
| Boiling point | 114 °C (lit.) |
| Density | 1.023 g/mL at 25 °C (lit.) |
| refractive index |
n |
| Flash point | 44 °F |
| storage temp. | Refrigerator |
| solubility | Chloroform, Ethyl Acetate, Methanol |
| form | Liquid |
| color | Colorless |
| Sensitive | Moisture Sensitive |
| BRN | 1737682 |
| InChI | InChI=1S/C5H12O4/c1-6-5(7-2,8-3)9-4/h1-4H3 |
| InChIKey | AHJWSRRHTXRLAQ-UHFFFAOYSA-N |
| SMILES | C(OC)(OC)(OC)OC |
| CAS DataBase Reference | 1850-14-2(CAS DataBase Reference) |
| FDA UNII | FHC4GZ2SYJ |
| NIST Chemistry Reference | Tetramethoxymethane(1850-14-2) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H225-H315-H319-H335 | |||||||||
| Precautionary statements | P210-P233-P240-P241-P303+P361+P353-P305+P351+P338 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 10-36/37/38 | |||||||||
| Safety Statements | 26-37 | |||||||||
| RIDADR | UN 3272 3/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 21 | |||||||||
| HS Code | 2909.19.6000 | |||||||||
| HazardClass | 3.1 | |||||||||
| PackingGroup | II | |||||||||
| Storage Class | 3 - Flammable liquids | |||||||||
| Hazard Classifications | Eye Irrit. 2 Flam. Liq. 2 Skin Irrit. 2 STOT SE 3 |
|||||||||
| NFPA 704 |
|
Tetramethoxymethane price More Price(30)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 132624 | Tetramethyl orthocarbonate 98% | 1850-14-2 | 5g | $190 | 2026-04-30 | Buy |
| Sigma-Aldrich | 132624 | Tetramethyl orthocarbonate 98% | 1850-14-2 | 25g | $673 | 2026-04-30 | Buy |
| TCI Chemical | T1045 | Tetramethoxymethane >97.0%(GC) | 1850-14-2 | 5g | $319 | 2026-04-30 | Buy |
| TCI Chemical | T1045 | Tetramethoxymethane >97.0%(GC) | 1850-14-2 | 25g | $1275 | 2026-04-30 | Buy |
| TRC | TRC-T298860-5G | Tetramethoxymethane | 1850-14-2 | 5g | $179 | 2026-06-03 | Buy |
Tetramethoxymethane Chemical Properties,Uses,Production
Description
Tetramethoxymethane can be usede in CO2 fixation, formation of orthocarbonates from diols and electrophilic introduction of an ester functionality.
Uses
Tetramethoxymethane has application within an electrolyte solution for the use of rechargeable lithium batteries. It has also been used as a reactant in the synthesis of novel anti-HIV-1 compounds.
Synthesis
Tetramethoxymethane has been prepared by heating a solution of Sodium Methoxide in methanol with chloropicrin, Trichloroacetonitrile, or thiocarbonyl perchlorate; the best yields have been obtained with the perchlorate. Alternatively, disodium hexamethoxystannate (prepared in situ from sodium methoxide and tetrachlorostannane) can be refluxed with Carbon Disulfide in methanol to form the orthocarbonate.
Purification Methods
Tetramethyl orthocarbonate (methyl orthocarbonate, tetramethoxy methane) [1850-14-2] M 136.2, m -5.6o, -5o, -2o, b 113.5o/760mm, 113.5 -114o/755mm, 112-114o/atm, d 4 1.0202, n D 1.3860. Purify it in the same way as for tetraethyl orthocarbonate. [Smith Acta Chem Scand 10 1006 1956, Tiekelmann & Post J Org Chem 13 266 1948, Kantlehner et al. Synthesis 73 1977, Beilstein 3 IV 4.]
Tetramethoxymethane Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Nanjing Datang Pharmaceutical Technology Co., Ltd. | 025-84341491 13951930983 | 821832400@qq.com | China | 300 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| SpringPharma Tech Co.,Ltd | +86-25-68710855, +86-25-68710897 | sales@springpharma.net | China | 1260 | 62 |
| TOKYO CHEMICAL INDUSTRY CO., LTD. | 03-36680489 | Sales-JP@TCIchemicals.com | Japan | 28364 | 80 |
| 9ding chemical ( Shanghai) Limited | 4009209199 | sales@9dingchem.com | China | 18201 | 56 |
| Chengdu AstaTech Trading Co., Ltd./AstaTech (Chengdu) Pharma. Co., Ltd. | +86-28-85122536 85324413 | market@astatech.cn | China | 8016 | 55 |
| Wuxi Zhangkun Biochemical Technology Co., Ltd. | +86 0510-85629785 | China | 2321 | 58 |
View Lastest Price from Tetramethoxymethane manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-12-20 | Tetramethoxymethane
1850-14-2
|
$7.00 | 1KG | 99% | Career Henan Chemical Co |
-
- Tetramethoxymethane
1850-14-2
- $7.00
- 99%
- Career Henan Chemical Co
