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6-METHYL-2,2'-BIPYRIDINE

6-METHYL-2,2'-BIPYRIDINE structure

CAS No.: 56100-22-2

Chemical Name:: 6-METHYL-2,2'-BIPYRIDINE

Synonyms: 6-METHYL-2,2'-DIPYRIDYL;6-Methyl-2,2'-Bipyridine;6-Methyl-2,2 '- Dipyridine;2,2'-Bipyridine, 6-Methyl-;6-Methyl-2,2'-dipyridyl 97%;6-methyl-2-(2-pyridyl)pyridine;2-methyl-6-(pyridin-2-yl)pyridine

CBNumber:: CB7241622

Molecular Formula:: C11H10N2

Molecular Weight:: 170.21

MDL Number:: MFCD02093688

MOL File:: 56100-22-2.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-05-28 02:22:57

Product description	Number	Pack Size	Price
6-Methyl-2,2'-bipyridine 98%	AS140563	1g	$132
6-Methyl-2,2'-bipyridine 98%	AS140563	5g	$502
6-Methyl-2,2'-bipyridine 98%	M54263	100mg	$30
6-Methyl-2,2'-bipyridine 98%	M54263	250mg	$36
6-Methyl-2,2'-bipyridine 98%	M54263	1g	$80

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6-METHYL-2,2'-BIPYRIDINE Properties

Boiling point	117-119 °C0.1 mm Hg(lit.)
Density	1.09 g/mL at 25 °C(lit.)
refractive index	n20/D 1.607(lit.)
Flash point	>230 °F
storage temp.	Inert atmosphere,Room Temperature
pka	4.82±0.10(Predicted)
Appearance	Yellow to brown Solid-Liquid Mixture
InChI	1S/C11H10N2/c1-9-5-4-7-11(13-9)10-6-2-3-8-12-10/h2-8H,1H3
InChIKey	LLCYXFYLGPOKQO-UHFFFAOYSA-N
SMILES	Cc1cccc(n1)-c2ccccn2
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H315-H319-H335
Precautionary statements	P261-P305+P351+P338
target organs	Respiratory system
PPE	Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
WGK Germany	3
Storage Class	10 - Combustible liquids
Hazard Classifications	Eye Irrit. 2 Skin Irrit. 2 STOT SE 3

6-METHYL-2,2'-BIPYRIDINE price More Price(27)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Activate Scientific	AS140563	6-Methyl-2,2'-bipyridine 98%	56100-22-2	1g	$132	2026-06-04	Buy
Activate Scientific	AS140563	6-Methyl-2,2'-bipyridine 98%	56100-22-2	5g	$502	2026-06-04	Buy
Synthonix	M54263	6-Methyl-2,2'-bipyridine 98%	56100-22-2	100mg	$30	2026-05-06	Buy
Synthonix	M54263	6-Methyl-2,2'-bipyridine 98%	56100-22-2	250mg	$36	2026-05-06	Buy
Synthonix	M54263	6-Methyl-2,2'-bipyridine 98%	56100-22-2	1g	$80	2026-05-06	Buy

Product number	Packaging	Price	Buy
AS140563	1g	$132	Buy
AS140563	5g	$502	Buy
M54263	100mg	$30	Buy
M54263	250mg	$36	Buy
M54263	1g	$80	Buy

6-METHYL-2,2'-BIPYRIDINE Chemical Properties,Uses,Production

Synthesis

366-18-7

917-54-4

56100-22-2

A tetrahydrofuran (26 mL) solution of methyl lithium (1.3 M, 33.80 mmol) was slowly added dropwise to an ethyl ether (100 mL) solution of 2,2'-bipyridine (5.30 g, 34.00 mmol) at 0°C and under nitrogen protection. The reaction mixture was stirred at this temperature for 2 hours and then refluxed at elevated temperature for 3 hours. When the reaction solution was cooled to room temperature, the reaction was quenched by the addition of water (10 mL). The organic phase was separated and the aqueous phase was extracted with ether three times. The organic phases were combined and dried over anhydrous sodium sulfate. The solvent was removed by concentration under reduced pressure to give an orange colored oil. This oily material was dissolved in acetone solution saturated with potassium permanganate (300 mL) and stirred at room temperature for 1 hour for oxidation reaction. The filtrate was filtered and concentrated to remove the acetone. The residue was purified by vacuum distillation to afford the colorless oily target product 6-methyl-2,2'-bipyridine (3.73 g, 63.8% yield). The structure of the product was confirmed by nuclear magnetic resonance hydrogen spectroscopy (1H NMR, 400MHz, CDCl3), carbon spectroscopy (13C NMR, 100MHz, CDCl3) and electrospray ionization mass spectrometry (ESI-MS): 1H NMR δ 8.65 (s, 1H), 8.38 (d, J = 8.0 Hz, 1H), 8.15 (d, J = 7.9 Hz, 1H), 7.72-7.82 (d, J = 7.9 Hz, 1H), 8.15 (d, J = 7.9 Hz, 1H) 7.72-7.82 (m, 1H), 7.66 (d, J = 7.7 Hz, 1H), 7.21-7.30 (m, 1H), 7.13 (d, J = 7.7 Hz, 1H), 2.61 (s, 3H); 13C NMR δ 157.7, 156.3, 155.4, 149.0, 136.9, 136.7, 123.6, 123.2, 121.02, 117.9, 24.5; ESI-MS m/z: [M+H]+ measured value 171.61 (calculated value 171.22).

References

[1] Angewandte Chemie - International Edition, 2014, vol. 53, # 23, p. 5872 - 5876
[2] Dyes and Pigments, 2016, vol. 128, p. 33 - 40
[3] Patent: CN105669689, 2016, A. Location in patent: Paragraph 0032
[4] Angewandte Chemie - International Edition, 2016, vol. 55, # 37, p. 11207 - 11211
[5] Angew. Chem., 2016, vol. 128, # 37, p. 11373 - 11377,5

6-METHYL-2,2'-BIPYRIDINE Preparation Products And Raw materials

Raw materials

2-Bromo-6-methylpyridine 2,2'-Bipyridine 2-Bromopyridine Methyllithium 2,6-Dichloropyridine

Preparation Products

6-((di-tert-butylphosphino)methyl)-2,2'-bipyridine

6-METHYL-2,2'-BIPYRIDINE Suppliers

Global( 106)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29812	58
Zhengzhou HQ Material CO.,LTD.	+86-371-55919009 +8615225108189	sale1@hqmat.com	China	1100	58
Fuxin Pharmaceutical	+86-021-021-50872116 +8613122107989	contact@fuxinpharm.com	China	9976	58
QINGDAO KAIENSI INTERNATIONAL TRADE CO.,LTD.	+86-0532-8699-9256 +8615254267723	kaley@cnfdevelop.com	China	1410	58
Shanghai UCHEM Inc.	+1-7027589231 +1-7027589231	sales@myuchem.com	China	8834	58
ANHUI WITOP BIOTECH CO., LTD	+8615255079626	eric@witopchemical.com	China	23541	58
Chemsigma International Co., Ltd.	+86-2558742998 +86-19951791336	info@chemsigma.com	China	1818	58
Dayang Chem (Hangzhou) Co.,Ltd.	+86-0571-88938639 +8617705817739	info@dycnchem.com	China	52704	58
CD Chemical Group Limited	+8615986615575	info@codchem.com	China	17259	58
changzhou huayang technology co., ltd	+8615250961469	2571773637@qq.com	China	9653	58

Supplier	Advantage
career henan chemical co	58
Zhengzhou HQ Material CO.,LTD.	58
Fuxin Pharmaceutical	58
QINGDAO KAIENSI INTERNATIONAL TRADE CO.,LTD.	58
Shanghai UCHEM Inc.	58
ANHUI WITOP BIOTECH CO., LTD	58
Chemsigma International Co., Ltd.	58
Dayang Chem (Hangzhou) Co.,Ltd.	58
CD Chemical Group Limited	58
changzhou huayang technology co., ltd	58

View Lastest Price from 6-METHYL-2,2'-BIPYRIDINE manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2019-08-08	6-METHYL-2,2'-BIPYRIDINE 56100-22-2	$1.00	1KG	98%	100KG	Career Henan Chemical Co

6-METHYL-2,2'-BIPYRIDINE
56100-22-2
$1.00
98%
Career Henan Chemical Co

6-METHYL-2,2'-BIPYRIDINE Spectrum

6-METHYL-2,2'-BIPYRIDINE(56100-22-2)¹HNMR

56100-22-2(6-METHYL-2,2'-BIPYRIDINE)Related Search:

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