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2-Bromo-6-methylpyridine

2-Bromo-6-methylpyridine Structure
2-Bromo-6-methylpyridine structure
CAS No.
5315-25-3
Chemical Name:
2-Bromo-6-methylpyridine
Synonyms
2-BROMO-6-PICOLINE;2-Bromo-6-methyL;6-BROMO-2-PICOLINE;6-Bromo-2-picoline,97%;2-Brom-6-methylpyridin;2-Bromo-6-methylpyrdine;2-BROMO-6-METHYLPYRIDINE;2-bormo-6-methylpyridine;2-BROMO-6-MEFHYL PYRIDINE;Bromomethylpyridine,ca.97%
CBNumber:
CB5770908
Molecular Formula:
C6H6BrN
Molecular Weight:
172.02
MDL Number:
MFCD00040743
MOL File:
5315-25-3.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-06-15 22:31:22
Product description Number Pack Size Price
2-Bromo-6-methylpyridine 98% 429112 1g $28.5
2-Bromo-6-methylpyridine 98% 429112 10g $167
2-Bromo-6-methylpyridine >98.0%(GC)(T) B2114 5g $51
2-Bromo-6-methylpyridine >98.0%(GC)(T) B2114 25g $149
2-Bromo-6-methylpyridine Asreported 263669 50g $359
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2-Bromo-6-methylpyridine Properties

Boiling point 102-103 °C/20 mmHg (lit.)
Density 1.512 g/mL at 25 °C (lit.)
refractive index n20/D 1.562(lit.)
Flash point 207 °F
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform, Ethyl Aceate
form Liquid
pka 1.51±0.10(Predicted)
Specific Gravity 1.512
color Clear colorless to yellow
Water Solubility Soluble in chloroform, ethyl aceate. Not miscible or difficult to mix with water.
BRN 107322
InChI InChI=1S/C6H6BrN/c1-5-3-2-4-6(7)8-5/h2-4H,1H3
InChIKey SOHDPICLICFSOP-UHFFFAOYSA-N
SMILES C1(Br)=NC(C)=CC=C1
CAS DataBase Reference 5315-25-3(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
HazardClass  IRRITANT
HS Code  29333990
Storage Class 10 - Combustible liquids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
NFPA 704
1
2 0

2-Bromo-6-methylpyridine price More Price(88)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 429112 2-Bromo-6-methylpyridine 98% 5315-25-3 1g $28.5 2026-04-30 Buy
Sigma-Aldrich 429112 2-Bromo-6-methylpyridine 98% 5315-25-3 10g $167 2026-04-30 Buy
TCI Chemical B2114 2-Bromo-6-methylpyridine >98.0%(GC)(T) 5315-25-3 5g $51 2026-04-30 Buy
TCI Chemical B2114 2-Bromo-6-methylpyridine >98.0%(GC)(T) 5315-25-3 25g $149 2026-04-30 Buy
Usbiological 263669 2-Bromo-6-methylpyridine Asreported 5315-25-3 50g $359 2026-06-03 Buy
Product number Packaging Price Buy
429112 1g $28.5 Buy
429112 10g $167 Buy
B2114 5g $51 Buy
B2114 25g $149 Buy
263669 50g $359 Buy

2-Bromo-6-methylpyridine Chemical Properties,Uses,Production

Chemical Properties

Light yellow liquid

Uses

2-Bromo-6-methylpyridine is a halogenated pyridine derivative used is a building block in the preparation of nitrogen containing heterocyclic compounds.

Uses

2-Bromo-6-methylpyridine may be used in the synthesis of the following:

  • 6,6′-dimethyl-2,2′-bipyridine
  • 6-methyl-2-pyridyl-2-pyridylmethanone
  • 2-methyl-6-(trimethylsilyl)-pyridine
  • N,N′-bis-(6-methylpyrid-2-yl)-(1R,2R)-1,2- diaminocyclohexane (cydiampy)
  • 2-methyl-6-(trimethylstannanyl)pyridine
  • 2-(6-methylpyridin-2-yl)propan-2-ol
  • bis[(2-bromo-6-methylpyridinium)hexafluorosilicate] monohydrate

Synthesis Reference(s)

Journal of the American Chemical Society, 76, p. 3168, 1954 DOI: 10.1021/ja01641a017

General Description

2-Bromo-6-methylpyridine is a bromopyridine derivative. It is formed when 2-chloro-6-methylpyridine is heated with bromotrimethylsilane. Its synthesis from various methods have been reported.

Synthesis

The following are the steps for preparing 2-Bromo-6-methylpyridine:
Step 1: 2-Amino-6-methylpyridine With hydrogen bromide; bromine at -10~5℃ for 1.5h;
Step 2: With NaNO2 In water monomer at -10~5℃ for 1.5h;
Step 3: With sodium hydroxide In water monomer at -10℃.

References

[1] Patent: CN105384684, 2016, A. Location in patent: Paragraph 0028; 0029
[2] Organic Letters, 2000, vol. 2, # 21, p. 3373 - 3376
[3] Phosphorus, Sulfur and Silicon and the Related Elements, 2002, vol. 177, # 11, p. 2579 - 2587
[4] Chemical and Pharmaceutical Bulletin, 1990, vol. 38, # 9, p. 2446 - 2458
[5] Journal of the Chemical Society - Perkin Transactions 1, 1998, # 19, p. 3151 - 3155

2-Bromo-6-methylpyridine synthesis

1824-81-3
5315-25-3
Synthesis of 2-Bromo-6-methylpyridine from 2-Amino-6-methylpyridine

2-Bromo-6-methylpyridine Preparation Products And Raw materials

Raw materials

2-Amino-6-methylpyridine Sodium nitrite

Preparation Products

6-Methoxypyridine-2-carbaldehyde 6,6'-Dimethyl-2,2'-dipyridyl 6-IODO-PYRIDINE-2-CARBOXYLIC ACID METHYL ESTER 6-Bromopyridine-2-carbaldehyde 6-Bromo-4-nitropyridine-2-carboxylic acid ,98%
5,5'-DIMETHYL-2,2'-DIPYRIDYL 6-Methyl-2-pyridinecarboxylic acid Pyridine, 2-Methyl-6-(1H-pyrazol-3-yl)- 2-METHYL-6-VINYLPYRIDINE 2-bromo-6-methylpyridin-4-amine
6-Trifluoromethyl-pyridine-2-carbaldehyde 2-Propyn-1-ol, 3-(6-methyl-2-pyridinyl)- (9CI) 2-(CHLOROMETHYL)-6-PHENYLPYRIDINE 6-Methyl-2,3'-bipyridine

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2-Bromo-6-methylpyridine Suppliers

Global( 597)Suppliers
Supplier Tel Email Country ProdList Advantage
Shenyang TYSChem Co., Ltd.
+86-24-83607930 +8618640359690 sales@honghuchem.com China 403 58
Terma Medicare India Pvt.,Ltd
+86-53530655; +8613916485955 shivshanghai@yahoo.com India 286 58
Shanghai UCHEM Inc. 		+862156762820 +86-13564624040 sales@myuchem.com China 8834 58
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 20120 58
Frapp's ChemicalNFTZ Co., Ltd. 		+86 (576) 8169-6106 sales@frappschem.com China 880 50
Capot Chemical Co.,Ltd. 		+86-（0）57185586718 +86-13336195806 sales@capot.com China 29640 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-2158073036 info@dakenam.com China 14026 58
Hi-Tech Chemistry Corp 		0519-86626038 yuhh@hitechem.com CHINA 810 58
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 33024 60
career henan chemical co 		+86-0371-86658258 +8613203830695 sales@coreychem.com China 29812 58
Supplier Advantage
Shenyang TYSChem Co., Ltd.
58
Terma Medicare India Pvt.,Ltd
58
Shanghai UCHEM Inc. 		58
Henan Fengda Chemical Co., Ltd 		58
Frapp's ChemicalNFTZ Co., Ltd. 		50
Capot Chemical Co.,Ltd. 		60
Shanghai Daken Advanced Materials Co.,Ltd 		58
Hi-Tech Chemistry Corp 		58
ATK CHEMICAL COMPANY LIMITED 		60
career henan chemical co 		58

View Lastest Price from 2-Bromo-6-methylpyridine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Bromo-6-methylpyridine pictures 2026-07-24 2-Bromo-6-methylpyridine
5315-25-3
 $238.00 1kg 0.98 25kg Shanghai UCHEM Inc.
2-Bromo-6-methylpyridine pictures 2026-07-24 2-Bromo-6-methylpyridine
5315-25-3
 1KG 98%min GC 1000kg WUHAN FORTUNA CHEMICAL CO., LTD
2-Bromo-6-methylpyridine pictures 2026-07-09 2-Bromo-6-methylpyridine
5315-25-3
 $5.00 1KG 98% Henan Fengda Chemical Co., Ltd

2-Bromo-6-methylpyridine Spectrum

2-Bromo-6-methylpyridine(5315-25-3)MS2-Bromo-6-methylpyridine(5315-25-3)1HNMR2-Bromo-6-methylpyridine(5315-25-3)IR1

5315-25-3(2-Bromo-6-methylpyridine)Related Search:

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2-BROMO-6-PICOLINE 6-BROMO-2-PICOLINE 2-BroMo-6-Methylpyridine, 97+% 2 - broMine - 6 - Methyl pyridine Pyridine, 2-bromo-6-methyl- 2-BROMO-6-METHYLPYRIDINE Bromomethylpyridine,ca.97% 2-Bromo-6-methylpyrdine 2-BROMO-6-METHYLPYRIDINE 98% 2-BROMO-6-METHYLPYRIDINE (2-BROMO-6-PICOLINE) 6-Bromo-2-Picoline (2-bromo-5-methylpyridine) 2-BROMO-6-MEFHYL PYRIDINE 2-Bromo-6-methyl pyridine ,98% 2-bormo-6-methylpyridine 6-Bromo-2-picoline,97% 6-Bromo-2-picoline 2-Bromo-6-picoline 6-Bromo-2-Picoline (2-bromo-6-methylpyridine) 2-Bromo-6-methylpyridine > 2-Bromo-6-methyL 2-Brom-6-methylpyridin 2-Bromo-6-methylpyridine ISO 9001：2015 REACH 2-Bromo-6-methylpyridine, 95% 2-Bromo-6-methylpyridine / 6-Bromo-2-picoline 5315-25-3 5351-25-3 3510-66-6 Bromopyridines Halopyridines Building Blocks Pyridines Heterocyclic Building Blocks Halogenated Heterocycles Bromopyridines Halopyridines Boronic Acid C6Heterocyclic Building Blocks Halogenated Heterocycles Heterocyclic Building Blocks blocks Bromides Pyridines Pyridine pyridine derivative Pyridines, Pyrimidines, Purines and Pteredines Halides Heterocycles compounds of pyridine bc0001