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2-Bromo-6-methylpyridine

2-Bromo-6-methylpyridine Structure
2-Bromo-6-methylpyridine structure
CAS No.
5315-25-3
Chemical Name:
2-Bromo-6-methylpyridine
Synonyms
2-BROMO-6-PICOLINE;2-Bromo-6-methyL;6-BROMO-2-PICOLINE;6-Bromo-2-picoline,97%;2-Brom-6-methylpyridin;2-Bromo-6-methylpyrdine;2-BROMO-6-METHYLPYRIDINE;2-bormo-6-methylpyridine;2-BROMO-6-MEFHYL PYRIDINE;Bromomethylpyridine,ca.97%
CBNumber:
CB5770908
Molecular Formula:
C6H6BrN
Molecular Weight:
172.02
MDL Number:
MFCD00040743
MOL File:
5315-25-3.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-06-15 22:31:22
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2-Bromo-6-methylpyridine Properties

Boiling point 102-103 °C/20 mmHg (lit.)
Density 1.512 g/mL at 25 °C (lit.)
refractive index n20/D 1.562(lit.)
Flash point 207 °F
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform, Ethyl Aceate
form Liquid
pka 1.51±0.10(Predicted)
Specific Gravity 1.512
color Clear colorless to yellow
Water Solubility Soluble in chloroform, ethyl aceate. Not miscible or difficult to mix with water.
BRN 107322
InChI InChI=1S/C6H6BrN/c1-5-3-2-4-6(7)8-5/h2-4H,1H3
InChIKey SOHDPICLICFSOP-UHFFFAOYSA-N
SMILES C1(Br)=NC(C)=CC=C1
CAS DataBase Reference 5315-25-3(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
HazardClass  IRRITANT
HS Code  29333990
Storage Class 10 - Combustible liquids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
NFPA 704
1
2 0

2-Bromo-6-methylpyridine price More Price(81)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 429112 2-Bromo-6-methylpyridine 98% 5315-25-3 1g $28.5 2026-04-30 Buy
Sigma-Aldrich 429112 2-Bromo-6-methylpyridine 98% 5315-25-3 10g $167 2026-04-30 Buy
TCI Chemical B2114 2-Bromo-6-methylpyridine >98.0%(GC)(T) 5315-25-3 5g $51 2026-04-30 Buy
TCI Chemical B2114 2-Bromo-6-methylpyridine >98.0%(GC)(T) 5315-25-3 25g $149 2026-04-30 Buy
Usbiological 263669 2-Bromo-6-methylpyridine Asreported 5315-25-3 50g $359 2026-06-03 Buy
Product number Packaging Price Buy
429112 1g $28.5 Buy
429112 10g $167 Buy
B2114 5g $51 Buy
B2114 25g $149 Buy
263669 50g $359 Buy

2-Bromo-6-methylpyridine Chemical Properties,Uses,Production

Chemical Properties

Light yellow liquid

Uses

2-Bromo-6-methylpyridine is a halogenated pyridine derivative used is a building block in the preparation of nitrogen containing heterocyclic compounds.

Uses

2-Bromo-6-methylpyridine may be used in the synthesis of the following:

  • 6,6′-dimethyl-2,2′-bipyridine
  • 6-methyl-2-pyridyl-2-pyridylmethanone
  • 2-methyl-6-(trimethylsilyl)-pyridine
  • N,N′-bis-(6-methylpyrid-2-yl)-(1R,2R)-1,2- diaminocyclohexane (cydiampy)
  • 2-methyl-6-(trimethylstannanyl)pyridine
  • 2-(6-methylpyridin-2-yl)propan-2-ol
  • bis[(2-bromo-6-methylpyridinium)hexafluorosilicate] monohydrate

Synthesis Reference(s)

Journal of the American Chemical Society, 76, p. 3168, 1954 DOI: 10.1021/ja01641a017

General Description

2-Bromo-6-methylpyridine is a bromopyridine derivative. It is formed when 2-chloro-6-methylpyridine is heated with bromotrimethylsilane. Its synthesis from various methods have been reported.

Synthesis

The following are the steps for preparing 2-Bromo-6-methylpyridine:
Step 1: 2-Amino-6-methylpyridine With hydrogen bromide; bromine at -10~5℃ for 1.5h;
Step 2: With NaNO2 In water monomer at -10~5℃ for 1.5h;
Step 3: With sodium hydroxide In water monomer at -10℃.

References

[1] Patent: CN105384684, 2016, A. Location in patent: Paragraph 0028; 0029
[2] Organic Letters, 2000, vol. 2, # 21, p. 3373 - 3376
[3] Phosphorus, Sulfur and Silicon and the Related Elements, 2002, vol. 177, # 11, p. 2579 - 2587
[4] Chemical and Pharmaceutical Bulletin, 1990, vol. 38, # 9, p. 2446 - 2458
[5] Journal of the Chemical Society - Perkin Transactions 1, 1998, # 19, p. 3151 - 3155

2-Bromo-6-methylpyridine synthesis

1824-81-3
5315-25-3
Synthesis of 2-Bromo-6-methylpyridine from 2-Amino-6-methylpyridine

2-Bromo-6-methylpyridine Preparation Products And Raw materials

Raw materials

2-Amino-6-methylpyridine Sodium nitrite

Preparation Products

6-Methoxypyridine-2-carbaldehyde 6,6'-Dimethyl-2,2'-dipyridyl 6-Iodo-pyridine-2-carboxylic acid methyl ester 6-Bromopyridine-2-carbaldehyde 6-Bromo-4-nitropyridine-2-carboxylic acid ,98%
5,5'-Dimethyl-2,2'-dipyridyl 6-Methyl-2-pyridinecarboxylic acid Pyridine, 2-Methyl-6-(1H-pyrazol-3-yl)- 2-Methyl-6-vinylpyridine 2-bromo-6-methylpyridin-4-amine
6-Trifluoromethyl-pyridine-2-carbaldehyde 2-Propyn-1-ol, 3-(6-methyl-2-pyridinyl)- (9CI) 2-(Chloromethyl)-6-phenylpyridine 6-Methyl-2,3'-bipyridine

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2-Bromo-6-methylpyridine Suppliers

Global( 602)Suppliers
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
INTATRADE GmbH +49 3493/605464 sales@intatrade.de Germany 3563 66
New Energy Chemicals 0515-82159099 13770142076 info@njuchem.com China 251 65
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TAIYUAN RHF CO.,LTD. +86 351 7031519 sales@RHFChem.com China 2334 56
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
ShangHai DEMO Chemical Co.,Ltd 400-021-7337 2355568890 sales@demochem.com China 2569 57
Beijing dtftchem Technology Co., Ltd. 010-60275820 13031183356 elainezt@sina.com China 1386 62
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
INTATRADE GmbH 66
New Energy Chemicals 65
Alfa Aesar 84
TAIYUAN RHF CO.,LTD. 56
TCI (Shanghai) Development Co., Ltd. 81
ShangHai DEMO Chemical Co.,Ltd 57
Beijing dtftchem Technology Co., Ltd. 62
Energy Chemical 61

View Lastest Price from 2-Bromo-6-methylpyridine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Bromo-6-methylpyridine pictures 2026-09-11 2-Bromo-6-methylpyridine
5315-25-3
 $238.00 1kg 0.98 25kg Shanghai UCHEM Inc.
2-Bromo-6-methylpyridine pictures 2026-09-11 2-Bromo-6-methylpyridine
5315-25-3
 1KG 98%min GC 1000kg WUHAN FORTUNA CHEMICAL CO., LTD
2-Bromo-6-methylpyridine pictures 2026-09-02 2-Bromo-6-methylpyridine
5315-25-3
 $5.00 1KG 98% Henan Fengda Chemical Co., Ltd

2-Bromo-6-methylpyridine Spectrum

2-Bromo-6-methylpyridine(5315-25-3)MS2-Bromo-6-methylpyridine(5315-25-3)1HNMR2-Bromo-6-methylpyridine(5315-25-3)IR1

5315-25-3(2-Bromo-6-methylpyridine)Related Search:

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2-BROMO-6-PICOLINE 6-BROMO-2-PICOLINE 2-BroMo-6-Methylpyridine, 97+% 2 - broMine - 6 - Methyl pyridine Pyridine, 2-bromo-6-methyl- 2-BROMO-6-METHYLPYRIDINE Bromomethylpyridine,ca.97% 2-Bromo-6-methylpyrdine 2-BROMO-6-METHYLPYRIDINE 98% 2-BROMO-6-METHYLPYRIDINE (2-BROMO-6-PICOLINE) 6-Bromo-2-Picoline (2-bromo-5-methylpyridine) 2-BROMO-6-MEFHYL PYRIDINE 2-Bromo-6-methyl pyridine ,98% 2-bormo-6-methylpyridine 6-Bromo-2-picoline,97% 6-Bromo-2-picoline 2-Bromo-6-picoline 6-Bromo-2-Picoline (2-bromo-6-methylpyridine) 2-Bromo-6-methylpyridine > 2-Bromo-6-methyL 2-Brom-6-methylpyridin 2-Bromo-6-methylpyridine ISO 9001：2015 REACH 2-Bromo-6-methylpyridine, 95% 2-Bromo-6-methylpyridine / 6-Bromo-2-picoline 5315-25-3 5351-25-3 3510-66-6 Bromopyridines Halopyridines Building Blocks Pyridines Heterocyclic Building Blocks Halogenated Heterocycles Bromopyridines Halopyridines Boronic Acid C6Heterocyclic Building Blocks Halogenated Heterocycles Heterocyclic Building Blocks blocks Bromides Pyridines Pyridine pyridine derivative Pyridines, Pyrimidines, Purines and Pteredines Halides Heterocycles compounds of pyridine bc0001