Methyl 3-amino-2-methylbenzoate
- CAS No.
- 18583-89-6
- Chemical Name:
- Methyl 3-amino-2-methylbenzoate
- Synonyms
- AKOS BB-3100;3-Amino-2-Methylbenzoate;METHYL 3-AMINO-O-TOLUATE;Lenalidomide Impurity 27;Lenalidomide Impurity 98;3-aminotoluene methyl ester;METHYL 3-AMINO-2-METHYLBENZOATE;METHYL 2-METHYL-3-AMINO BENZOATE;Methyl 3-Amino-2-melthyl benzoate;Methyl 3-amino-2-methylbenzoate 96%
- CBNumber:
- CB7702334
- Molecular Formula:
- C9H11NO2
- Molecular Weight:
- 165.19
- MDL Number:
- MFCD00211328
- MOL File:
- 18583-89-6.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Boiling point | 300 °C (lit.) |
|---|---|
| Density | 1.146 g/mL at 25 °C (lit.) |
| refractive index |
n |
| Flash point | 220 °F |
| storage temp. | under inert gas (nitrogen or Argon) at 2–8 °C |
| solubility | Chloroform (Sparingly), Methanol (Slightly) |
| form | Liquid |
| pka | 3.31±0.10(Predicted) |
| color | Colorless to brown |
| InChI | 1S/C9H11NO2/c1-6-7(9(11)12-2)4-3-5-8(6)10/h3-5H,10H2,1-2H3 |
| InChIKey | ZOOQFAUFPWXUMI-UHFFFAOYSA-N |
| SMILES | COC(=O)c1cccc(N)c1C |
| CAS DataBase Reference | 18583-89-6(CAS DataBase Reference) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36 | |||||||||
| WGK Germany | 3 | |||||||||
| HazardClass | IRRITANT | |||||||||
| HS Code | 2922498590 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
|||||||||
| NFPA 704 |
|
Methyl 3-amino-2-methylbenzoate price More Price(64)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 530271 | Methyl 3-amino-2-methylbenzoate 96% | 18583-89-6 | 25g | $162 | 2023-06-20 | Buy |
| TCI Chemical | A1563 | Methyl 3-Amino-2-methylbenzoate >98.0%(GC)(T) | 18583-89-6 | 5g | $82 | 2026-04-30 | Buy |
| TCI Chemical | A1563 | Methyl 3-Amino-2-methylbenzoate >98.0%(GC)(T) | 18583-89-6 | 25g | $236 | 2026-04-30 | Buy |
| TRC | TRC-M331018-500MG | Methyl 3-Amino-2-methylbenzoate | 18583-89-6 | 500mg | $75 | 2026-06-03 | Buy |
| TRC | TRC-M331018-250MG | Methyl 3-Amino-2-methylbenzoate | 18583-89-6 | 250mg | $58 | 2026-06-03 | Buy |
Methyl 3-amino-2-methylbenzoate Chemical Properties,Uses,Production
Chemical Properties
off-white powder
Uses
Methyl 3-Amino-2-methylbenzoate can be used in petroleum recovery process.
Synthesis
52130-17-3
18583-89-6
A. General procedure for the synthesis of methyl 3-amino-2-methylbenzoate: 10 g (66.2 mmol) of 3-amino-2-methylbenzoic acid and 20 g of p-toluenesulfonic acid monohydrate were dissolved in 400 mL of methanol and the reaction was carried out at reflux overnight. After completion of the reaction, the reaction solution was diluted with a mixture of ethyl acetate and 1 M potassium carbonate solution. After cooling, the organic and aqueous layers were separated. The organic layer was washed sequentially with 1M potassium carbonate solution and saturated brine, dried over anhydrous sodium sulfate, filtered, and concentrated to give 9.23 g of an orange oily product in 85% yield. The product was characterized as follows: 1H NMR (CDCl3): δ 2.34 (s, 3H), 3.73 (br.s, 2H), 3.88 (s, 3H), 6.81 (d, J = 7.96 Hz, 1H), 7.05 (t, J = 7.78 Hz, 1H), 7.19-7.30 (m, 1H). IR (CHCl3): 3406, 3027, 3012, 2.30 (m). 3027, 3012, 2978, 2953, 1718, 1621, 1467, 1435, 1315, 1301, 1265, 1196, 1159, 1108, 1066, 1045, 810 cm-1. MS (FD): m/e 165 (M+, 100).
References
[1] Patent: US5952343, 1999, A
[2] Patent: US5461154, 1995, A
[3] Patent: US5484926, 1996, A
[4] Patent: US6555541, 2003, B1
Methyl 3-amino-2-methylbenzoate Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Capot Chemical Co., Ltd | +86 (0) 571 85 58 67 18 | China | 18187 | 66 | |
| JinYan Chemicals(ShangHai) Co.,Ltd. | 13817811078 | sales@jingyan-chemical.com | China | 9963 | 60 |
| Pure Chemistry Scientific Inc. | 001-857-928-2050 or 1-888-588-9418 | sales@chemreagents.com | United States | 10174 | 62 |
| Adamas Reagent, Ltd. | 400-6009262 15618770481 | yhx@titansci.com | China | 14098 | 59 |
| Accela ChemBio Co.,Ltd. | 021-50795510 4000665055 | marketing@accelachem.com | China | 10972 | 64 |
View Lastest Price from Methyl 3-amino-2-methylbenzoate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-06-30 | Methyl 3-amino-2-methylbenzoate
18583-89-6
|
1KG | 99.0% | 10000KGS | Shaanxi Dideu New Materials Co. Ltd | ||
 |
2026-03-20 | Methyl 3-amino-2-methylbenzoate
18583-89-6
|
$10.00 | 1KG | 99% | 10 mt | Hebei Chuanghai Biotechnology Co., Ltd | |
 |
2024-04-24 | Methyl 3-amino-2-methylbenzoate
18583-89-6
|
$30.00-100.00 | 1kg | 99.93% | 1000kg per week | Ouhuang Engineering Materials (Hubei) Co., Ltd |
-
- Methyl 3-amino-2-methylbenzoate
18583-89-6
- 99.0%
- Shaanxi Dideu New Materials Co. Ltd
-
- Methyl 3-amino-2-methylbenzoate
18583-89-6
- $10.00
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-
- Methyl 3-amino-2-methylbenzoate
18583-89-6
- $30.00-100.00
- 99.93%
- Ouhuang Engineering Materials (Hubei) Co., Ltd
