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Thiophene-3,4-dicarboxylic acid

CAS No.
4282-29-5
Chemical Name:
Thiophene-3,4-dicarboxylic acid
Synonyms
100G,500G,1KG,10KG;3,4-THIOPHENEDICARBOXYLIC ACID;EA129;DK7284;3,4-Dicarboxythiophene;THIOPHENE-3,4-DICARBOXY;THIOPHENE-3,4-DICARBOXYLATE;Thiophene-3,4-DicarboxylicAci;Thiophen-3,4-dicarboxylic acid;THIOPHENE-3,4-DICARBOXYLIC ACID
CBNumber:
CB7769265
Molecular Formula:
C6H4O4S
Molecular Weight:
172.16
MDL Number:
MFCD00067079
MOL File:
4282-29-5.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 03:36:32

Thiophene-3,4-dicarboxylic acid Properties

Melting point 227-231 °C
Boiling point 272.46°C (rough estimate)
Density 1.473 (estimate)
refractive index 1.5500 (estimate)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility soluble in Methanol
pka 3.36±0.20(Predicted)
form Crystalline Powder
color Yellow to beige-pinkish or light brown
λmax 240nm(H2O)(lit.)
InChI InChI=1S/C6H4O4S/c7-5(8)3-1-11-2-4(3)6(9)10/h1-2H,(H,7,8)(H,9,10)
InChIKey ZWWLLYJRPKYTDF-UHFFFAOYSA-N
SMILES C1SC=C(C(O)=O)C=1C(O)=O
FDA UNII J7P9TPY3Y5
UNSPSC Code 12352103
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P271-P280
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  24/25
WGK Germany  3
HazardClass  IRRITANT
HS Code  29349990
Storage Class 11 - Combustible Solids

Thiophene-3,4-dicarboxylic acid price More Price(61)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 795577 3,4-Thiophenedicarboxylic acid 4282-29-5 5g $124 2026-04-30 Buy
TCI Chemical T2280 3,4-Thiophenedicarboxylic Acid >98.0%(GC)(T) 4282-29-5 1g $64 2026-04-30 Buy
AstaTech 67066 THIOPHENE-3,4-DICARBOXYLIC ACID 97% 4282-29-5 5G $27 2026-04-30 Buy
Apolloscientific OR2907 Thiophene-3,4-dicarboxylic acid >97% 4282-29-5 1g $21 2026-06-04 Buy
Apolloscientific OR2907 Thiophene-3,4-dicarboxylic acid >97% 4282-29-5 5g $33 2026-06-04 Buy
Product number Packaging Price Buy
795577 5g $124 Buy
T2280 1g $64 Buy
67066 5G $27 Buy
OR2907 1g $21 Buy
OR2907 5g $33 Buy

Thiophene-3,4-dicarboxylic acid Chemical Properties,Uses,Production

Chemical Properties

yellow to beige-pinkish or light brown crystalline

Uses

Thiophene-3,4-dicarboxylic Acid is used in preparation of dibromo thienofuran dione.

Uses

Synthetic precursor for organic electronics materials.

Synthesis

Thiophene-3,4-dicarbonitrile (13.4 g, 100 mmol) and KOH (56.1 g, 1 mol) were dissolved in ethylene glycol (167 ml), and heated under stirring overnight. The solution was cooled, put into distilled water, and washed with diethyl ether. The aqueous layer was oxidized with saturated hydrochloric acid, and organic materials were extracted with ethyl acetate. The organic layer was dried over MgSO and the4, solvent was evaporated Then, recrystallization was performed in distilled water to obtain thiophene-3,4-dicarboxylic acid (15.2 g, 88percent).

References

[1] Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1993, # 9, p. 1589 - 1596
[2] Patent: WO2008/127029, 2008, A1. Location in patent: Page/Page column 18
[3] Patent: US2010/99840, 2010, A1
[4] Journal of Heterocyclic Chemistry, 1986, vol. 23, p. 1103 - 1108
[5] Journal of the American Chemical Society, 2012, vol. 134, # 46, p. 19035 - 19042

18853-32-2
4282-29-5
Synthesis of Thiophene-3,4-dicarboxylic acid from 3,4-DICYANOTHIOPHENE,
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View Lastest Price from Thiophene-3,4-dicarboxylic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
THIOPHENE-3,4-DICARBOXYLIC ACID pictures 2026-09-02 THIOPHENE-3,4-DICARBOXYLIC ACID
4282-29-5
$1.00-50.00 1KG 99% Henan Fengda Chemical Co., Ltd
THIOPHENE-3,4-DICARBOXYLIC ACID  pictures 2026-08-20 THIOPHENE-3,4-DICARBOXYLIC ACID
4282-29-5
$1.10 1g 99.00% 100 Tons Dideu Industries Group Limited
Thiophene-3,4-dicarboxylic acid pictures 2026-06-30 Thiophene-3,4-dicarboxylic acid
4282-29-5
1kg 99% 10000KGS Shaanxi Dideu New Materials Co. Ltd

Thiophene-3,4-dicarboxylic acid Spectrum

3,4-THIOPHENEDICARBOXYLIC ACID THIOPHENE-3,4-DICARBOXYLIC ACID 3,4-Thiophenedicarboxylic acid,97% 3,4-Dicarboxythiophene 3,4-Thiophenedicarboxylic acid ,98% THIOPHENE-3,4-DICARBOXYLATE 100G,500G,1KG,10KG THIOPHENE-3,4-DICARBOXY Thiophene-3,4-DicarboxylicAci THIOPHENE-3,4-DICARBOXYLIC ACID ISO 9001:2015 REACH EA129 THIOPHENE-3,4-DICARBOXYLIC ACID 4282-29-5 DK7284 3,4-Thiophenedicarboxylic acid (6CI, 7CI, 8CI, 9CI, ACI) Thiophen-3,4-dicarboxylic acid 4282-29-5 Building Blocks Carboxy Thiophene API intermediates Acids and Derivatives Heterocycles