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TIGLOYL CHLORIDE

CAS No.
35660-94-7
Chemical Name:
TIGLOYL CHLORIDE
Synonyms
Tiglyl chloride;TIGLOYL CHLORIDE;Tiglic acid chloride;2-Methylcrotonic acid chloride;(E)-2-methylcrotonoyl chloride;(E)-2-Methyl-2-butenoyl chloride;(E)-2-METHYL-BUT-2-ENOYL CHLORIDE;(2E)-2-Methylbut-2-enoyl chloride;TRANS-2-METHYL-2-BUTENOYL CHLORIDE;(E)-2,3-Dimethylacryloyl chloride
CBNumber:
CB7769801
Molecular Formula:
C5H7ClO
Molecular Weight:
118.56
MDL Number:
MFCD00800725
MOL File:
35660-94-7.mol
MSDS File:
SDS
Last updated:2026-05-28 03:36:33

TIGLOYL CHLORIDE Properties

Boiling point 145 °C
Density 1,08 g/cm3
refractive index n20/D 1.471
Flash point 22 °C
storage temp. -20°C
solubility soluble in Chloroform, Methanol
form clear liquid
color Colorless to Almost colorless
InChI 1S/C5H7ClO/c1-3-4(2)5(6)7/h3H,1-2H3/b4-3+
InChIKey TUNLYEHIVPWOHK-ONEGZZNKSA-N
SMILES C\C=C(/C)C(Cl)=O
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Corrosion (GHS05)Skull and Crossbones (GHS06)
GHS02,GHS05,GHS06
Signal word  Danger
Hazard statements  H225-H301+H311+H331-H314
Precautionary statements  P210-P233-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
PPE Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Codes  T
Risk Statements  10-23/24/25-34
Safety Statements  16-26-36/37/39-45
RIDADR  3265
WGK Germany  3
HazardClass  8/3
PackingGroup  II
HS Code  2916199590
Storage Class 3 - Flammable liquids
Hazard Classifications Acute Tox. 3 Inhalation
Acute Tox. 4 Oral
Eye Dam. 1
Flam. Liq. 3
Skin Corr. 1B
NFPA 704
1
3 0

TIGLOYL CHLORIDE price More Price(21)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 688606 trans-2-Methyl-2-butenoyl chloride ≥97.0% 35660-94-7 5g $551 2026-04-30 Buy
Sigma-Aldrich 688606 trans-2-Methyl-2-butenoyl chloride ≥97.0% 35660-94-7 1g $166 2023-06-20 Buy
TCI Chemical T1811 Tigloyl Chloride >98.0%(GC)(T) 35660-94-7 5g $242 2026-04-30 Buy
TRC TRC-T440130-5G Tigloyl Chloride 35660-94-7 5g $256 2026-06-03 Buy
TRC TRC-T440130-1G Tigloyl Chloride 35660-94-7 1g $179 2026-06-03 Buy
Product number Packaging Price Buy
688606 5g $551 Buy
688606 1g $166 Buy
T1811 5g $242 Buy
TRC-T440130-5G 5g $256 Buy
TRC-T440130-1G 1g $179 Buy

TIGLOYL CHLORIDE Chemical Properties,Uses,Production

Chemical Properties

Clear Colourless Oil

Uses

Tigloyl Chloride is used in the polymerization of propylene as well as through a Freidel-Crafts reaction for the preparation of permethylindenyl complexes of transition metals. As well, it is primari ly used as a reagent in the enantioselective synthesis of dihydropyrans.

Synthesis Reference(s)

Tetrahedron Letters, 18, p. 3379, 1977 DOI: 10.1016/S0040-4039(01)83244-5

TIGLOYL CHLORIDE Preparation Products And Raw materials

Global( 60)Suppliers
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J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Chemsky(shanghai)International Co.,Ltd. 021-50135380 shchemsky@sina.com China 32273 50
Hangzhou Sage Chemical Co., Ltd. +86057186818502 13588463833 info@sagechem.com China 10265 58
TOKYO CHEMICAL INDUSTRY CO., LTD. 03-36680489 Sales-JP@TCIchemicals.com Japan 28364 80
9ding chemical ( Shanghai) Limited 4009209199 sales@9dingchem.com China 22497 55
Letopharm Limited +86-21-5821 5861 sales@letopharm.com China 70 55
Shanghai Leto Pharmatech Co.,Ltd. 86-021-5821 5861; 18016401466 sales@letopharm.com China 235 58
TRANS-2-METHYL-2-BUTENOYL CHLORIDE TIGLOYL CHLORIDE (E)-2-methylcrotonoyl chloride Tiglyl chloride (E)-2-METHYL-BUT-2-ENOYL CHLORIDE (E)-2,3-Dimethylacryloyl chloride, (E)-2-Methylcrotonoyl chloride, 3-cis-Methyl-methacryloyl chloride, Tigloyl chloride (E)-2-Methyl-2-butenoic acid chloride 2-Methylcrotonic acid chloride Tiglic acid chloride (E)-2,3-Dimethylacryloyl chloride 3-cis-Methyl-methacryloyl chloride 2-Butenoyl chloride, 2-Methyl-, (2E)- (E)-2-Methyl-2-butenoyl chloride (2E)-2-Methylbut-2-enoyl chloride trans-2-Methyl-2-butenoyl chloride >=97.0% (E)-2,3-Dimethylacryloyl chloride, (E)-2-Methylcrotonoyl chloride, 3-cis-Methyl-methacryloyl chloride, Tigloyl chlo trans-2-Methyl-2-butenoyl chloride 35660-94-7