Bis(benzonitrile)dichloroplatinum(II)
- CAS No.
- 14873-63-3
- Chemical Name:
- Bis(benzonitrile)dichloroplatinum(II)
- Synonyms
- bis(Benzonitrile)dichloroplatinum;Dichlorobis(benzonitrile)platinum;Dichlorobis-(benzonitrilo)-platinum;bis(benzonitrile)platinum(Ⅱ)chloride;Platinum, bis(benzonitrile)dichloro-;BIS(BENZONITRILE)DICHLOROPLATINUM(II);DICHLOROBIS(BENZONITRILE)PLATINUM(LL);BIS(BENZONITRILE)PLATINUM(II) CHLORIDE;DICHLOROBIS(BENZONITRILE)PLATINUM (II);BIS(BENZONITRILE)DICHLOROPLATINATE (II)
- CBNumber:
- CB8287724
- Molecular Formula:
- C14H10Cl2N2Pt
- Molecular Weight:
- 472.23
- MDL Number:
- MFCD00013125
- MOL File:
- 14873-63-3.mol
| Melting point | 224 °C (dec.)(lit.) |
|---|---|
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| solubility | Slightly soluble in acetone, chloroform |
| form | crystal |
| color | yellow to orange |
| Exposure limits |
ACGIH: TWA 0.002 mg/m3 NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3 |
| InChI | 1S/2C7H5N.2ClH.Pt/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2 |
| InChIKey | WAJRCRIROYMRKA-UHFFFAOYSA-L |
| SMILES | [Pt](Cl)(Cl)([NH]#Cc2ccccc2)[NH]#Cc1ccccc1 |
| UNSPSC Code | 12161600 |
| NACRES | NA.23 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS06,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301-H311-H317-H331-H334 | |||||||||
| Precautionary statements | P261-P280h-P284-P301+P310a-P405-P501a | |||||||||
| Risk Statements | 20/21/22 | |||||||||
| Safety Statements | 26-36/37/39 | |||||||||
| RIDADR | UN3439 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | TP2185000 | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| NFPA 704 |
|
Bis(benzonitrile)dichloroplatinum(II) price More Price(22)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 921041 | Dichlorobis(benzonitrile)platinum(II) ≥99.9% | 14873-63-3 | 500 mg | $133 | 2026-04-30 | Buy |
| Sigma-Aldrich | 921041 | Dichlorobis(benzonitrile)platinum(II) ≥99.9% | 14873-63-3 | 1 g | $204 | 2026-04-30 | Buy |
| Strem Chemicals | 78-0360 | Dichlorobis(benzonitrile)platinum(II), 99% 99% | 14873-63-3 | 250mg | $79 | 2026-04-30 | Buy |
| Strem Chemicals | 78-0360 | Dichlorobis(benzonitrile)platinum(II), 99% 99% | 14873-63-3 | 1g | $240 | 2026-04-30 | Buy |
| Strem Chemicals | 78-0360 | Dichlorobis(benzonitrile)platinum(II), 99% 99% | 14873-63-3 | 5g | $957 | 2026-04-30 | Buy |
Bis(benzonitrile)dichloroplatinum(II) Chemical Properties, Uses, Production
Uses
Bis(benzonitrile)dichloroplatinum(II) is used as a catalyst for asymmetric hydroformylation reactions, allylation reactions, cyclopropanation reactions, hydrosilylation reactions and carbene insertion into O-H bonds of alcohols.
Preparation
Bis(benzonitrile)dichloroplatinum(II) can be prepared as a mixture of cis and trans complexes. The reaction of Palladium(II) Chloride in benzonitrile at room temperature for 7 h yields a mixture that can be separated chromatographically to yield 26% trans- and 58% cis-PtCl2(PhCN)2. An alternate route requires stoichiometric amounts of potassium tetrachloroplatinate(II) and benzonitrile stirred at room temperature for one week. Trituration of the product with hot benzene yields pure cis-PtCl2(PhCN)2 in 60% yield; the cooled benzene solution yields pure trans-PtCl2(PhCN)2 in 20% yield.
Purification Methods
chromatography on silica gel with dichloromethane as eluant, or trituration with hot benzene.
Bis(benzonitrile)dichloroplatinum(II) Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| Beijing HwrkChemical Technology Co., Ltd | 89508211 18501085097 | sales.bj@hwrkchemical.com | China | 9407 | 55 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Sichuan Kulinan Technology Co., Ltd | 400-1166-196 18981987031 | cdhxsj@163.com | China | 11674 | 57 |
| Beijing HuaMeiHuLiBiological Chemical | 010-56205725 | waley188@sohu.com | China | 12323 | 58 |
| 9ding chemical ( Shanghai) Limited | 4009209199 | sales@9dingchem.com | China | 22497 | 55 |
| Shanghai Aladdin Bio-Chem Technology Co.,LTD | 400-6206333 13167063860 | anhua.mao@aladdin-e.com | China | 29985 | 65 |
| HBCChem, Inc. | +1-510-219-6317 | sales@hbcchem.com | United States | 10628 | 60 |
| Bide Pharmatech Ltd. | 400-164-7117 18317119277 | product02@bidepharm.com | China | 40000 | 60 |
View Latest Price from Bis(benzonitrile)dichloroplatinum(II) manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-08-25 | Bis(benzonitrile)dichloroplatinum(II)
14873-63-3
|
$2.00-5.00 | 1kg | 99% | 100kg | ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | |
 |
2022-09-27 | HAFNIUM
14873-63-3
|
1kg | 99% | 1000kg | henan kanbei chemical co.,ltd | ||
 |
2022-09-24 | Bis(benzonitrile)dichloroplatinum(II)
14873-63-3
|
1kg | 99% | 1000kg | henan kanbei chemical co.,ltd |
-
- Bis(benzonitrile)dichloroplatinum(II)
14873-63-3
- $2.00-5.00
- 99%
- ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
-
- HAFNIUM
14873-63-3
- $0.00
- 99%
- henan kanbei chemical co.,ltd
-
- Bis(benzonitrile)dichloroplatinum(II)
14873-63-3
- $0.00
- 99%
- henan kanbei chemical co.,ltd
