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(R)-1-(3-Bromophenyl)ethylamine

CAS No.
176707-77-0
Chemical Name:
(R)-1-(3-Bromophenyl)ethylamine
Synonyms
(R)-1-(3-bromophenyl)ethan-1-amine;(R)-1-(3-BROMOPHENYL)ETHANAMINE;Albb-005066;?-1-(3-Bromophenyl)ethanamine;(R)-3-Bromo-α-methylbenzylamine;(R)-1-(3-BROMOPHENYL)ETHYLAMINE;[(1R)-1-(3-Bromophenyl)ethyl]amine;(R)-(+)-3-BROMO A-METHYLBENZYLAMINE;(R)-3-BROMO-ALPHA-METHYLBENZYLAMINE;(1R)-1-(3-bromophenyl)ethan-1-amine
CBNumber:
CB8302375
Molecular Formula:
C8H10BrN
Molecular Weight:
200.08
MDL Number:
MFCD00671637
MOL File:
176707-77-0.mol
MSDS File:
SDS
Last updated:2026-05-28 03:56:16

(R)-1-(3-Bromophenyl)ethylamine Properties

Boiling point 96°C/4mm
Density 1.33
Flash point 96°C/4mm
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
pka 8.73±0.10(Predicted)
Appearance Colorless to light yellow Liquid
optical activity Consistent with structure
Sensitive Air Sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)Exclamation Mark (GHS07)Environment (GHS09)
GHS05,GHS07,GHS09
Signal word  Danger
Hazard statements  H318-H302-H314-H317-H411
Precautionary statements  P273-P280-P305+P351+P338-P310-P303+P361+P353
Hazard Codes  C,N
Risk Statements  34-51/53-43-22
Safety Statements  26-36/37/39-61-45
RIDADR  2735
HazardClass  8
PackingGroup  III
NFPA 704
0
3 0

(R)-1-(3-Bromophenyl)ethylamine price More Price(46)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Activate Scientific AS5298 (R)-1-(3-Bromophenyl)ethanamine 97%EE 176707-77-0 1g $37 2026-06-04 Buy
Activate Scientific AS5298 (R)-1-(3-Bromophenyl)ethanamine 97%EE 176707-77-0 5g $113 2026-06-04 Buy
Activate Scientific AS5298 (R)-1-(3-Bromophenyl)ethanamine 97%EE 176707-77-0 25g $386 2026-06-04 Buy
Matrix Scientific 167633 (R)-1-(3-Bromophenyl)ethanamine 176707-77-0 1.00g $166 2026-05-18 Buy
Matrix Scientific 167633 (R)-1-(3-Bromophenyl)ethanamine 176707-77-0 5.00g $497 2026-05-18 Buy
Product number Packaging Price Buy
AS5298 1g $37 Buy
AS5298 5g $113 Buy
AS5298 25g $386 Buy
167633 1.00g $166 Buy
167633 5.00g $497 Buy

(R)-1-(3-Bromophenyl)ethylamine Chemical Properties,Uses,Production

Synthesis

Ethanone, 1-(3-bromophenyl)-, oxime

24280-05-5

(R)-1-(3-Bromophenyl)ethylamine

176707-77-0

The general procedure for the synthesis of (R)-1-(3-bromophenyl)ethylamine from 1-(3-bromophenyl)ethanone oxime is as follows: 1 equiv. of N-[1-(3-bromophenyl)ethylidene]hydroxylamine, 5 mol% of RuCl(Cymene)(S-tol-Binap)Cl catalyst, 5 equiv. of additives, and 70 vol. of methanol (relative to the amount of the oxime) are added to a glass vial. The glass vials were placed in a parallel autoclave, which was pressurized to 30 bar with hydrogen, then heated to 90 °C and kept for 24 hours. After completion of the reaction, the system was cooled to 20 °C. The reaction mixture was diluted with isopropyl alcohol. The reaction mixture was diluted with isopropanol and analyzed by chiral HPLC.

References

[1] Patent: WO2015/178847, 2015, A1. Location in patent: Page/Page column 7-8

2142-63-4
176707-77-0
Synthesis of (R)-1-(3-Bromophenyl)ethylamine from 3'-Bromoacetophenone
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(R)-1-(3-Bromophenyl)ethylamine Spectrum

(R)-3-BROMO-ALPHA-METHYLBENZYLAMINE (R)-(+)-3-BROMO A-METHYLBENZYLAMINE (R)-1-(3-BROMOPHENYL)ETHANAMINE (R)-1-(3-BROMOPHENYL)ETHYLAMINE [(1R)-1-(3-Bromophenyl)ethyl]amine (R)-1-(3-Bromophenyl)ethylamine, ChiPros 99%, ee 98+% Benzenemethanamine, 3-bromo-α-methyl-, (αR)- Albb-005066 Benzenemethanamine, 3-bromo-.alpha.-methyl-, (.alpha.R)- (1R)-1-(3-bromophenyl)ethanamine(SALTDATA: FREE) (R)-3-Bromo-α-methylbenzylamine (R)-1-(3-BroMophenyl)ethylaMine, ChiPros|r, 99%, ee 98+% (R)-3-BroMo-α-MethylbenzylaMine ?-1-(3-Bromophenyl)ethanamine (1R)-1-(3-bromophenyl)ethan-1-amine (R)-1-(3-Bromophenyl)Ethylamine, Chipros (R)-1-(3-bromophenyl)ethan-1-amine 176707-77-0 API intermediates