Bis(triphenylphosphine)dicarbonylnickel
- CAS No.
- 13007-90-4
- Chemical Name:
- Bis(triphenylphosphine)dicarbonylnickel
- Synonyms
- phosphine)dicarbonyL;Bis(triphenylphosphine)dicarbonylnickel;BIS(TRIPHENYLPHOSPHINE)NICKEL &;DICARBONYL-BIS(TRIPHENYLPHOSPHINE)NICKEL;BIS(TRIPHENYLPHOSPHINE)NICKEL DICARBONYL;NICKEL-BIS(TRIPHENYLPHOSPHINE) DICARBONYL;Bis-(triphenylphosphino)-nickel dicarbonyl;dicarbonylbis(triphenylphosphine)nickel(0);Bis(triphenylphosphine)nickel(0)dicarbonyl;Bis(triphenylphosphine)nickeldicarbonyl,98%
- CBNumber:
- CB0687047
- Molecular Formula:
- C38H30NiO2P2
- Molecular Weight:
- 639.28
- MDL Number:
- MFCD00009591
- MOL File:
- 13007-90-4.mol
- MSDS File:
- SDS
| Melting point | 206-209 °C (lit.) |
|---|---|
| storage temp. | 2-8°C |
| solubility | Soluble in HMPA, THF, diglyme, triglyme, benzene, acetonitrile, ethanol, and cyclohexane. |
| form | crystal |
| color | light yellow |
| Sensitive | air sensitive |
| Merck | 14,1304 |
| Exposure limits | NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 |
| InChI | 1S/2C18H15P.2CO.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2*1-2;/h2*1-15H;;; |
| InChIKey | SLFKPACCQUVAPG-UHFFFAOYSA-N |
| SMILES | [Ni].[C-]#[O+].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6 |
| CAS DataBase Reference | 13007-90-4 |
| REACH Annex XVII Substances List | Dicarbonylbis(triphenylphosphine)nickel (13007-90-4) |
| FDA UNII | 1QB0TWF7LY |
| UNSPSC Code | 12161600 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H317-H350 | |||||||||
| Precautionary statements | P201-P280-P302+P352-P308+P313 | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges | |||||||||
| Hazard Codes | T | |||||||||
| Risk Statements | 45-42/43 | |||||||||
| Safety Statements | 53-22-36/37-45 | |||||||||
| RIDADR | 3281 | |||||||||
| WGK Germany | 3 | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | II | |||||||||
| Storage Class | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
|||||||||
| Hazard Classifications | Carc. 1B Skin Sens. 1 |
|||||||||
| NFPA 704 |
|
Bis(triphenylphosphine)dicarbonylnickel price More Price(24)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 213934 | Bis(triphenylphosphine)dicarbonylnickel | 13007-90-4 | 10g | $143 | 2026-04-30 | Buy |
| Strem Chemicals | 28-0100 | Bis(triphenylphosphine)nickel dicarbonyl, 98% 98% | 13007-90-4 | 5g | $46 | 2026-04-30 | Buy |
| Strem Chemicals | 28-0100 | Bis(triphenylphosphine)nickel dicarbonyl, 98% 98% | 13007-90-4 | 25g | $173 | 2026-04-30 | Buy |
| Strem Chemicals | 28-0100 | Bis(triphenylphosphine)nickel dicarbonyl, 98% 98% | 13007-90-4 | 100g | $513 | 2026-04-30 | Buy |
| Activate Scientific | AS225310 | Bis(triphenylphosphine)dicarbonylnickel 95% | 13007-90-4 | 1g | $34 | 2026-06-04 | Buy |
Bis(triphenylphosphine)dicarbonylnickel Chemical Properties, Uses, Production
Chemical Properties
light yellow crystals or crystalline powder
Uses
Catalyst in polymerization of acetylene to benzene and styrene, trimerization of ethynyl Compounds, cyclization of butadiene.
Uses
Catalyst for:
- Cyclotrimerization reactions
- Cyclooligomerization reactions
reaction suitability
core: nickel
reagent type: catalyst
Synthesis
The preparative method of Bis(triphenylphosphine)dicarbonylnickel: by treating Tetracarbonylnickel with 2 equiv of Triphenylphosphine or by dissolving Dichlorobis(triphenylphosphine)nickel(II) in ethanol and treating it with CO in the presence of MeSNa. Purification: recrystallize from benzene.
Precautions
Catalytic activity decreases with storage. It is likely to be toxic, similar to nickel carbonyl, but its low volatility makes it easy to avoid ingestion. Use in a fume hood.
Bis(triphenylphosphine)dicarbonylnickel Preparation Products And Raw materials
Raw materials
Preparation Products
Bis(triphenylphosphine)dicarbonylnickel Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Beijing Taiya Jie Technology Development Co., Ltd. | 021-33690831-8001 13552411790;18616022633 | postmaster@tyjchem.cn | China | 1541 | 55 |
| Shijiazhuang Lickon PharmaTech Co., Ltd. | 031185291771 13832391721 | yaofeng2005@163.com | China | 947 | 58 |
| Chongqing Xingcan Pharmaceutical Technology Co., Ltd. | 13594048950 19923294409 | xingcanyaoye@sina.com | China | 1591 | 58 |
| Sigma-Aldrich | 021-61415566 800-8193336 | orderCN@merckgroup.com | China | 51389 | 80 |
| Shanghai YuanYe Biotechnology Co., Ltd. | 15026964105 | 2881489226@qq.com | China | 89667 | 60 |
13007-90-4 (Bis(triphenylphosphine)dicarbonylnickel) Related Search:
1of3
