4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID
- CAS No.
- 870774-25-7
- Chemical Name:
- 4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID
- Synonyms
- 4-(Naphthalen-1-yl);Boronic acid, [4-(1-napht;1-(4-Boronophenyl)naphthalene;4-(1-phthyl)phenylboronic acid;4-(1-Naphtyl)phenylboronic acid;-(1-Naphthyl)benzeneboronic Acid;4-(1-Naphthyl)phenylboronic acid;4-(1-Naphthyl)benzeneboronic Acid;4-(Naphth-1-yl)benzeneboronic acid;4-(1-naphthalenyl)phenylboronic acid
- CBNumber:
- CB91119184
- Molecular Formula:
- C16H13BO2
- Molecular Weight:
- 248.08
- MDL Number:
- MFCD08669639
- MOL File:
- 870774-25-7.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 4-(1-Naphthyl)phenylboronic Acid (contains varying amounts of Anhydride) | N0798 | 1g | $27 |
| 4-(1-Naphthyl)phenylboronic Acid (contains varying amounts of Anhydride) | N0798 | 5g | $75 |
| 4-(Naphthalen-1-yl)phenylboronicAcid | N378423 | 500mg | $75 |
| 4-(1-Naphthyl)benzeneboronic acid 98.65% | CS-W000991 | 5g | $25 |
| 4-(1-Naphthyl)benzeneboronic acid 98.65% | CS-W000991 | 25g | $96 |
| More product size | |||
| Boiling point | 449.4±48.0 °C(Predicted) |
|---|---|
| Density | 1.23±0.1 g/cm3(Predicted) |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| solubility | soluble in Tetrahydrofuran |
| form | powder to crystal |
| pka | 8.58±0.16(Predicted) |
| color | White to Light yellow |
| InChI | InChI=1S/C16H13BO2/c18-17(19)14-10-8-13(9-11-14)16-7-3-5-12-4-1-2-6-15(12)16/h1-11,18-19H |
| InChIKey | BQHVXFQXTOIMQM-UHFFFAOYSA-N |
| SMILES | B(C1=CC=C(C2=C3C(C=CC=C3)=CC=C2)C=C1)(O)O |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| HS Code | 2931900090 | |||||||||
| NFPA 704 |
|
4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID price More Price(28)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | N0798 | 4-(1-Naphthyl)phenylboronic Acid (contains varying amounts of Anhydride) | 870774-25-7 | 1g | $27 | 2025-07-31 | Buy |
| TCI Chemical | N0798 | 4-(1-Naphthyl)phenylboronic Acid (contains varying amounts of Anhydride) | 870774-25-7 | 5g | $75 | 2025-07-31 | Buy |
| TRC | N378423 | 4-(Naphthalen-1-yl)phenylboronicAcid | 870774-25-7 | 500mg | $75 | 2021-12-16 | Buy |
| ChemScene | CS-W000991 | 4-(1-Naphthyl)benzeneboronic acid 98.65% | 870774-25-7 | 5g | $25 | 2021-12-16 | Buy |
| ChemScene | CS-W000991 | 4-(1-Naphthyl)benzeneboronic acid 98.65% | 870774-25-7 | 25g | $96 | 2021-12-16 | Buy |
4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID Chemical Properties,Uses,Production
Application
4-(1-Naphthyl)phenylboronic acid is an acid derivative that can be used as an intermediate in organic synthesis.
Chemical Properties
off-white powder
Synthesis
204530-94-9
870774-25-7
A mixed solution of 208.8 g (737.4 mmol) of 1-(4-bromophenyl)naphthalene with 2.1 L of anhydrous tetrahydrofuran (THF) was cooled to -60 °C under argon protection. Subsequently, 567 mL (884.9 mmol) of 1.56 M n-butyllithium hexane solution was added slowly dropwise under stirring conditions. After the dropwise addition was completed, the reaction mixture was continued to be stirred at -60 °C for 2 hours. Maintaining the temperature at -60 °C, 416 g (2.21 mol) of triisopropyl borate was added dropwise to the reaction system. After completion of the dropwise addition, the reaction mixture was gradually warmed to room temperature and stirred for 17 hours. At the end of the reaction, an aqueous hydrochloric acid solution was added to the mixture and stirred for 1 hour at room temperature. The reaction mixture was extracted with toluene, and the aqueous phase was separated and discarded. The organic phase was dried with magnesium sulfate and the solvent was removed by distillation under reduced pressure. The resulting solid was purified by recrystallization from toluene to give 126 g of 4-(1-naphthyl)phenylboronic acid in 67% yield.
References
[1] Patent: US2010/331585, 2010, A1. Location in patent: Page/Page column 96-97
4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 | info@spring-chem.com | China | 2068 | 57 |
| Hebei Maison Chemical Co.,Ltd. | +8615511852758 | sales@maisonchem.com.cn | China | 484 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20134 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718; +8613336195806 | sales@capot.com | China | 29735 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 13595 | 58 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| Beijing Green Guardee Technology Co., Ltd | 86-010-69706062 | sales2@greenguardee.com | CHINA | 650 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29843 | 58 |
| SHAANXI WEISHINUO THE NEW MATERIALCO,.LTD | 18792503214 | Beryl@weishino.com | CHINA | 256 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28172 | 58 |
View Lastest Price from 4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2025-11-18 | 4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID
870774-25-7
|
US $1.10 / g | 1g | 99.00% | 100 Tons | Dideu Industries Group Limited | |
 |
2025-09-25 | 4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID
870774-25-7
|
US $188.00-1.00 / KG | 1KG | 99%, 99.5% Sublimated | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
 |
2025-04-04 | 4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID
870774-25-7
|
US $0.00-0.00 / KG | 1KG | 98% | 1ton | Henan Aochuang Chemical Co.,Ltd. |
-
- 4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID
870774-25-7
- US $1.10 / g
- 99.00%
- Dideu Industries Group Limited
-
- 4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID
870774-25-7
- US $188.00-1.00 / KG
- 99%, 99.5% Sublimated
- Henan Fengda Chemical Co., Ltd
-
- 4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID
870774-25-7
- US $0.00-0.00 / KG
- 98%
- Henan Aochuang Chemical Co.,Ltd.
