3-(1,1,1-TRIBUTYLSTANNYL)PYRIDINE
- CAS No.
- 59020-10-9
- Chemical Name:
- 3-(1,1,1-TRIBUTYLSTANNYL)PYRIDINE
- Synonyms
- 3-(TRIBUTYLSTANNYL)PYRIDINE;SKL989;3-PYRIDYLTRI-N-BUTYLTIN;3-(tributyltin) pyridine;3-Pyridyltributylstannane;tributyl(3-pyridyl)stannane;3-PYRIDYLTRI-n-BUTYLTIN 95%;Pyridine,3-(tributylstannyl)-;tributyl(pyridin-3-yl)stannane;3-(Tributylstannyl)pyridine 97%
- CBNumber:
- CB9701083
- Molecular Formula:
- C17H31NSn
- Molecular Weight:
- 368.14
- MDL Number:
- MFCD00052054
- MOL File:
- 59020-10-9.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| 3-(Tributylstannyl)pyridine | FT142773 | 25g | $519.25 |
| 3-(Tributylstannyl)pyridine | FT142773 | 50g | $779 |
| 3-(Tributylstannyl)pyridine | FT142773 | 100g | $1233 |
| 3-(Tributylstannyl)pyridine | FT142773 | 250g | $2337.5 |
| 3-(Tributylstannyl)pyridine | FT142773 | 500g | $4545 |
| More product size | |||
| Boiling point | 132°C 0,3mm |
|---|---|
| Density | 1,15 g/cm3 |
| Flash point | 110 °C |
| storage temp. | -20°C |
| form | liquid |
| pka | 5.21±0.12(Predicted) |
| Specific Gravity | 1.150 |
| color | Dark brown |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| Exposure limits |
ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin) NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS06,GHS08,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301-H312-H315-H319-H372-H410-H400 | |||||||||
| Precautionary statements | P309-P310-P501a-P273-P280-P301+P310-P305+P351+P338-P314-P501 | |||||||||
| Hazard Codes | T,Xi,N | |||||||||
| Risk Statements | 20/21/22-36/37/38-50/53-48/23/25-36/38-25-21 | |||||||||
| Safety Statements | 26-36/37/39-61-60-45-35 | |||||||||
| RIDADR | UN 2788 6.1/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | No | |||||||||
| HazardClass | 6.1 | |||||||||
| HazardClass | IRRITANT, KEEP COLD, TOXIC | |||||||||
| HS Code | 29333990 | |||||||||
| NFPA 704 |
|
3-(1,1,1-TRIBUTYLSTANNYL)PYRIDINE price More Price(28)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Biosynth | FT142773 | 3-(Tributylstannyl)pyridine | 59020-10-9 | 25g | $519.25 | 2026-06-04 | Buy |
| Biosynth | FT142773 | 3-(Tributylstannyl)pyridine | 59020-10-9 | 50g | $779 | 2026-06-04 | Buy |
| Biosynth | FT142773 | 3-(Tributylstannyl)pyridine | 59020-10-9 | 100g | $1233 | 2026-06-04 | Buy |
| Biosynth | FT142773 | 3-(Tributylstannyl)pyridine | 59020-10-9 | 250g | $2337.5 | 2026-06-04 | Buy |
| Biosynth | FT142773 | 3-(Tributylstannyl)pyridine | 59020-10-9 | 500g | $4545 | 2026-06-04 | Buy |
3-(1,1,1-TRIBUTYLSTANNYL)PYRIDINE Chemical Properties,Uses,Production
Uses
3-Tributylstannylpyridine (CAS# 59020-10-9) can be used to prepare polyimide material that is resistant to atomic oxygen.
Synthesis
626-55-1
1461-22-9
59020-10-9
In a two-necked round-bottomed flask 0.5 mL (5.19 mmol) of 3-bromopyridine was dissolved in 25 mL of anhydrous ether and the reaction system was cooled to -78 °C. 3.89 mL (6.23 mmol) of n-butyllithium (1.6 M hexane solution) was slowly added dropwise and the reaction was stirred for 3 hours keeping the temperature at -78 °C. Subsequently, 1.55 mL (5.71 mmol) of tributyltin chloride was added and stirring was continued at -78°C for 30 minutes, then gradually warmed to room temperature and stirred for 12 hours. Upon completion of the reaction, the reaction was quenched by the addition of saturated aqueous ammonium chloride and extracted with ether. The organic layer was separated, dried with anhydrous magnesium sulfate and concentrated under reduced pressure to remove the solvent. Purification by column chromatography (eluent: hexane/ethyl acetate=9:1, v/v) afforded 1.58 g of the target product 3-(1,1,1-tributylmethylstannyl)pyridine as a clear oil (yield: 83%).
References
[1] Patent: KR2015/142709, 2015, A. Location in patent: Paragraph 0441-0443
[2] Patent: US6498159, 2002, B1
[3] Patent: US6599917, 2003, B1
[4] Tetrahedron, 2013, vol. 69, # 2, p. 902 - 909
[5] Advanced Synthesis and Catalysis, 2017, vol. 359, # 5, p. 832 - 840
3-(1,1,1-TRIBUTYLSTANNYL)PYRIDINE Preparation Products And Raw materials
Raw materials
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Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Arbor Chemical Co., Ltd. | 021-60451682 | act@arborchemical.com | CHINA | 904 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49979 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29792 | 58 |
| Chengdu Aslee Biopharmaceuticals, Inc. | 28-85305008 | CHINA | 964 | 58 | |
| Shanghai Gubang New Materail Technology Co. LTD | 21-51317962 +8618721305404 | 16728589@qq.com | CHINA | 272 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-29-81139210 +86-17392587031 | 1059@dideu.com | China | 9996 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52704 | 58 |
| Alfa Chemistry | +1-5166625404; | Info@alfa-chemistry.com | United States | 20000 | 58 |
| Hebei Chuanghai Biotechnology Co., Ltd | +8615531151365 | mina@chuanghaibio.com | China | 18126 | 58 |
| GIHI CHEMICALS CO.,LIMITED | +86-571-86217390; +8618058761490 | info@gihichemicals.com | China | 49897 | 58 |
View Lastest Price from 3-(1,1,1-TRIBUTYLSTANNYL)PYRIDINE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2020-01-09 | 3-(1,1,1-TRIBUTYLSTANNYL)PYRIDINE
59020-10-9
|
$2.00 | 1g | 98%min | Career Henan Chemical Co |
-
- 3-(1,1,1-TRIBUTYLSTANNYL)PYRIDINE
59020-10-9
- $2.00
- 98%min
- Career Henan Chemical Co
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