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Ethoxyethyne

CAS No.
927-80-0
Chemical Name:
Ethoxyethyne
Synonyms
ETHOXYACETYLENE;ETHYL ETHYNYL ETHER;1-Ethoxyacetylene;Ethynyl ethyl ether;ethoxy-ethyn;ETHOXYETHYNE;EthoxyacetyL;ethynoxyethane;Ethyne, ethoxy-;Ethoxyacethlene
CBNumber:
CB9720017
Molecular Formula:
C4H6O
Molecular Weight:
70.09
MDL Number:
MFCD00009247
MOL File:
927-80-0.mol
MSDS File:
SDS
Last updated:2026-05-28 05:53:25

Ethoxyethyne Properties

Boiling point 53°C
Density 0.732 g/mL at 25 °C
refractive index n20/D 1.379
Flash point −20 °F
storage temp. 2-8°C
solubility sol alcohol, ether, benzene, hexane
form liquid
color Clear Yellow
Water Solubility Slightly miscible with water.
BRN 741882
Dielectric constant 8.0500000000000007
InChI InChI=1S/C4H6O/c1-3-5-4-2/h1H,4H2,2H3
InChIKey WMYNMYVRWWCRPS-UHFFFAOYSA-N
SMILES C#COCC
CAS DataBase Reference 927-80-0(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII B8RFM34GMK
NIST Chemistry Reference Ethoxyacetylene(927-80-0)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Exclamation Mark (GHS07)Health Hazard (GHS08)Environment (GHS09)
GHS02,GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H225-H304-H315-H336-H361-H373-H411
Precautionary statements  P202-P210-P273-P301+P310-P303+P361+P353-P331
target organs Central nervous system
Hazard Codes  F,Xn,N
Risk Statements  11-38-48/20-51/53-62-65-67-36/37/38-36/38
Safety Statements  16-36/37-61-62-45-36/37/39-26-33-29-9
RIDADR  UN 1993 3/PG 2
WGK Germany  3
RTECS  KN9900000
Hazard Note  Highly Flammable/Keep Cold
HazardClass  3
PackingGroup  II
HS Code  29091990
Storage Class 3 - Flammable liquids
Hazard Classifications Aquatic Chronic 2
Asp. Tox. 1
Flam. Liq. 2
Repr. 2
Skin Irrit. 2
STOT RE 2 Inhalation
STOT SE 3
NFPA 704
3
2 1

Ethoxyethyne price More Price(25)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 271365 Ethoxyacetylene solution ~40 wt. % in hexanes 927-80-0 1g $63.9 2026-04-30 Buy
Sigma-Aldrich 271365 Ethoxyacetylene solution ~40 wt. % in hexanes 927-80-0 5g $135 2026-04-30 Buy
Biosynth FE34781 Ethyl ethynyl ether - 40 wt. % in hexanes 927-80-0 25g $900 2026-06-04 Buy
Biosynth FE34781 Ethyl ethynyl ether - 40 wt. % in hexanes 927-80-0 1g $900 2026-06-04 Buy
Biosynth FE34781 Ethyl ethynyl ether - 40 wt. % in hexanes 927-80-0 10g $900 2026-06-04 Buy
Product number Packaging Price Buy
271365 1g $63.9 Buy
271365 5g $135 Buy
FE34781 25g $900 Buy
FE34781 1g $900 Buy
FE34781 10g $900 Buy

Ethoxyethyne Chemical Properties, Uses, Production

Chemical Properties

Clear orange to brown solution

Uses

Ethoxyacetylene is used in Arens-van Dorp synthesis to prepare propargyl alcohol via reaction with ketone. In organic synthesis, it undergoes [2+2] cycloaddition reactions with ketenes to give cyclobutenone derivatives. It is also used to prepare alpha, beta-unsaturated esters from ketones by following Meyer-Schuster rearrangement.Used with N-vinylamides and triflic anhydride in a direct, three-component synthesis of pyridines. Also used to prepare α, β-unsaturated esters from ketones via a Meyer-Schuster rearrangement.

Uses

Used with N-vinylamides and triflic anhydride in a direct, three-component synthesis of pyridines. Also used to prepare α,β-unsaturated esters from ketones via a Meyer-Schuster rearrangement.

Preparation

Ethoxyethyne can be prepared from chloroacetaldehyde diethyl acetal (70%).

Hazard

Ethoxyethyne is moisture sensitive; potential fire hazard with certain metal salts. Use in a fume hood.

Global Suppliers ( 153)
Supplier Tel Email Country ProdList Advantage
New Energy Chemicals 0515-82159099 13770142076 info@njuchem.com China 251 65
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Beijing Donghualituo Techonlogy Development Co.,Ltd. 010-88425576 sales@dhltchem.com China 793 59
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Wuhan Chemwish Technology Co., Ltd 86-027-67849912 sales@chemwish.com China 35884 56
Capot Chemical Co., Ltd +86 (0) 571 85 58 67 18 China 18187 66
Beijing Ouhe Technology Co., Ltd 13552068683 13522913783 2355560935@qq.com China 11777 60
JinYan Chemicals(ShangHai) Co.,Ltd. 13817811078 sales@jingyan-chemical.com China 9963 60

View Latest Price from Ethoxyethyne manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Ethoxyethyne pictures 2020-01-08 Ethoxyethyne
927-80-0
$1.00 1IU 99.0% 100kg Career Henan Chemical Co
Ethoxyacetylene,ca50%w/winhexanes ETHYL ETHYNYL ETHER,50wt% SOLUITON IN HEXANES Ethoxyacetylene, 50% hexane solution ETHOXYACETYLENE(40% W/W SOLUTION IN HEXANES) ETHYL ETHYNYL ETHER: (50% BY WT. IN HEXANE) Ethynyl ethyl ether Ethyl ethynyl ether, 40 WT% solution in hexanes ETHYL ETHYNYL ETHER, 50% (W/W) In HEXANES ETHOXYACETHYLENE Ethyl ethynyl ether, 40 wt.% solution in hexanes, AcroSeal Ethyl ethynyl ether, 40 wt% solution in hexanes 5GR Ethoxyacetylene, ca w/w in Hexanes Ethyl ethynyl ether, Ethoxyethyne Ethoxyacetylene solution ~40 wt. % in hexanes Ethoxyacetylene solution, 50 wt. % in hexanes Ether, ethyl ethynyl ether,ethylethynyl ethoxy-ethyn Ethyne, ethoxy- ETHYL ETHYNYL ETHER ETHOXYETHYNE Ethoxyacethlene ETHYL ETHYNYL ETHER, CA. 50 WT. % SOLUTI ON IN HEXANES/ETHANOL (40:10) ETHYL ETHYNYL ETHER, 50 WT. % SOLUTION I N HEXANES ETHOXYACETYLENE SOLUTION, ~40% IN HEXANE Ethoxyacetylene, 50% w/w in hexane Ethoxyacetylene solution Ethyl ethynyl ether, 50% in hexanes ETHYL ETHYNYL ETHER, 50% (W/W), In HEXANESETHYL ETHYNYL ETHER, 50% (W/W), In HEXANESETHYL ETHYNYL ETHER, 50% (W/W), In HEXANESETHYL ETHYNYL ETHER, 50% (W/W), In HEXANES EthoxyacetyL Ethyne, ethoxy- (9CI) ethynoxyethane Ethyl ethynyl ether, 40 wt.% solution in hexanes, AcroSeal&trade Ethyl ethynyl ether - 40 wt. % in hexanes 1-Ethoxyacetylene ETHOXYACETYLENE 927-80-0 927-80-0977-80-0 C2H5OC8801CH CH3CH2OCCH HCCOC2H5 HCCOCH2CH3 Building Blocks Alkynes Organic Building Blocks Terminal Alkynes Organic Building Blocks Terminal