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2-Methoxypropene

2-Methoxypropene Structure
2-Methoxypropene structure
CAS No.
116-11-0
Chemical Name:
2-Methoxypropene
Synonyms
MOP;2-methoxyprop-1-ene;ISOPROPENYL METHYL ETHER;2-Methoxyproene;2-METHYOXYPROPENE;Ether, isopropenyl methyl;CH2=C(CH3)OCH3;CH3C(OCH3):CH2;2-Methoxyprope;2-METHOXYPROPENE
CBNumber:
CB9735606
Molecular Formula:
C4H8O
Molecular Weight:
72.11
MDL Number:
MFCD00014929
MOL File:
116-11-0.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 05:58:27
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2-Methoxypropene Properties

Melting point 25°C
Boiling point 34-36 °C (lit.)
Density 0.753 g/mL at 25 °C (lit.)
vapor pressure 27.96 psi ( 55 °C)
refractive index n20/D 1.382(lit.)
Flash point −21 °F
storage temp. 2-8°C
solubility Chloroform
form Liquid
color Clear colorless
PH 7 (H2O)
Water Solubility negligible
Sensitive Light Sensitive
BRN 1734635
InChI 1S/C4H8O/c1-4(2)5-3/h1H2,2-3H3
InChIKey YOWQWFMSQCOSBA-UHFFFAOYSA-N
SMILES COC(C)=C
LogP 1.7 at 21℃ and pH8.1-8.4
CAS DataBase Reference 116-11-0(CAS DataBase Reference)
FDA UNII 15WBG0JT6B
NIST Chemistry Reference 1-Propene, 2-methoxy-(116-11-0)
EPA Substance Registry System 1-Propene, 2-methoxy- (116-11-0)
UNSPSC Code 12352112
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
Signal word  Danger
Hazard statements  H224-H302
Precautionary statements  P210-P233-P240-P241-P301+P312-P403+P235
PPE Eyeshields, Faceshields, Gloves
Hazard Codes  F+,Xn,F
Risk Statements  12-19-22-11
Safety Statements  3-16-29-33-7/9-9-18
RIDADR  UN 1993 3/PG 1
WGK Germany  1
RTECS  UD0800000
F  8-10
Autoignition Temperature 374 °F
TSCA  TSCA listed
HazardClass  3
PackingGroup  I
HS Code  29091990
Storage Class 3 - Flammable liquids
Hazard Classifications Acute Tox. 4 Oral
Flam. Liq. 1
Hazardous Substances Data 116-11-0(Hazardous Substances Data)
Toxicity rabbit,LD50,skin,> 20mL/kg (20mL/kg),American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969.
REACH Registrations Active
Limited Quantities 0.5 L (0.1 gallon)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (300g or 300ml)
NFPA 704
4
2 0

2-Methoxypropene price More Price(44)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 174645 2-Methoxypropene 97% 116-11-0 50g $79.3 2026-04-30 Buy
Sigma-Aldrich 174645 2-Methoxypropene 97% 116-11-0 250g $163 2026-04-30 Buy
TCI Chemical I0303 2-Methoxypropene >95.0%(GC) 116-11-0 25mL $39 2026-04-30 Buy
TCI Chemical I0303 2-Methoxypropene >95.0%(GC) 116-11-0 100mL $103 2026-04-30 Buy
Usbiological 284887 2-Methoxypropene Asreported 116-11-0 100g $376 2026-06-03 Buy
Product number Packaging Price Buy
174645 50g $79.3 Buy
174645 250g $163 Buy
I0303 25mL $39 Buy
I0303 100mL $103 Buy
284887 100g $376 Buy

2-Methoxypropene Chemical Properties, Uses, Production

Chemical Properties

clear colorless liquid

Uses

2-Methoxypropene is used in the synthesis of Macrolactin A, a 24-member macrolide typically employed as an antibiotic. Also used in the synthesis of phenylalanine derivatives used as α4β1 and α4β7 receptor antagonists in the treatment of allergic asthma.

Preparation

2-Methoxypropene is prepared in high yield from Succinic Anhydride, 2,2-Dimethoxypropane, benzoic acid, and Pyridine.

Reactivity Profile

2-Methoxypropene is an electron-rich alkene used in the monoprotection of aliphatic, allylic, and propargylic alcohols, often followed by Claisen or other rearrangements; protection of peroxides, cyanohydrins, α-hydroxy ketones, and phenols; condensation with amines; protection of 1,2- and 1,3-diols, sometimes followed by Prins rearrangements; protection of 1,2-dithiols and α-hydroxy carbamates; participant in pericyclic reactions; formation of 2-methoxyallyl halides and substituted furans.

Toxics Screening Level

The initial threshold screening level (ITSL) for 2-Methoxy-1-propene is 6 μg/m3 based on an annual averaging time.

Precautions

flammable liquid; light-sensitive; should be refrigerated.

2-Methoxypropene synthesis

77-76-9
116-11-0
Synthesis of 2-Methoxypropene from 2,2-Dimethoxypropane

2-Methoxypropene Preparation Products And Raw materials

Raw materials

Ethanone, 1-(3-methoxy-2,3-dimethyl-2-oxetanyl)- (9CI) Butanoic acid, 2,2,3,3,4,4,4-heptafluoro-, 1,1-dimethylethyl ester Butaneperoxoic acid, 2,2,3,3,4,4,4-heptafluoro-, 1,1-dimethylethyl ester 2,3-Butanedione 1,2-Diphenylethane
Dimethyl carbonate Allene Pyridine 2,2-Dimethoxypropane Methyl bromide
Methyltriphenylphosphonium bromide

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Preparation Products

Teprenone Impurity 20 Warfarin 1,3-Dioxan-5-ol, 2,2-dimethyl- 1,2:5,6-Bis-O-(1-methylethylidene)-D-mannitol 5-Ketohexanenitrile
4-(Chloromethyl)-2,2-dimethyl-1,3-dioxolane

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2-Methoxypropene Suppliers

Global Suppliers ( 328)
Supplier Tel Email Country ProdList Advantage
Wuhan xinyangruihe Chemical Technology Co., Ltd. 027-18120580375 18120580375 669797270@qq.com China 5375 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Beijing HwrkChemical Technology Co., Ltd 89508211 18501085097 sales.bj@hwrkchemical.com China 9407 55
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Wuhan Chemwish Technology Co., Ltd 86-027-67849912 sales@chemwish.com China 35884 56
Beijing Ouhe Technology Co., Ltd 13552068683 13522913783 2355560935@qq.com China 11777 60
JinYan Chemicals(ShangHai) Co.,Ltd. 13817811078 sales@jingyan-chemical.com China 9963 60
Supplier Advantage
Wuhan xinyangruihe Chemical Technology Co., Ltd. 58
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
Alfa Aesar 84
TCI (Shanghai) Development Co., Ltd. 81
Beijing HwrkChemical Technology Co., Ltd 55
Energy Chemical 61
Wuhan Chemwish Technology Co., Ltd 56
Beijing Ouhe Technology Co., Ltd 60
JinYan Chemicals(ShangHai) Co.,Ltd. 60

View Latest Price from 2-Methoxypropene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Methoxypropene pictures 2026-05-28 2-Methoxypropene
116-11-0
 $10.70 10kg 99% 10000kg Hebei Chuanghai Biotechnology Co,.LTD
2-Methoxypropene pictures 2026-03-20 2-Methoxypropene
116-11-0
 $10.00 1KG 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
2-Methoxypropene pictures 2025-04-04 2-Methoxypropene
116-11-0
 1KG 98% 1ton Henan Aochuang Chemical Co.,Ltd.

2-Methoxypropene Spectrum

2-Methoxypropene(116-11-0)MS2-Methoxypropene(116-11-0)1HNMR2-Methoxypropene(116-11-0)13CNMR2-Methoxypropene(116-11-0)IR12-Methoxypropene(116-11-0)IR22-Methoxypropene(116-11-0)Raman

116-11-0 (2-Methoxypropene) Related Search:

Tribenuron methyl Kresoxim-methyl Methyl acetate 4-Methoxybenzylchloride Isobutylene
(Trifluoromethoxy)benzene p-Anisaldehyde Anisole Methyl salicylate Pirimiphos-methyl
p-Anisidine 4'-Methoxyacetophenone Thiophanate-methyl 4-Methoxybenzoic acid Metsulfuron methyl
3-(Methoxymethoxy)benzaldehyde Propylene Methyl

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Methyl isopropenyl ether 2-METHOXYPROPENE 2-METHOXY-1-PROPENE MOP 1-Propene,2-methoxy- 2-methoxy-1-propen 2-methoxy-prop-1-ene 2-methoxy-propen CH2=C(CH3)OCH3 ether,isopropenylmethyl 2-METHOXYPROPENE, STAB. 2-Methoxypropene, stabilized, 98% 2-METHOXYPROPENE , STABILIZED WITH CA 0.5% POTASSIUM CARBONATE 2-METHOXYPROPENE, 99.5+% 2-METHOXYPROPENE:ISOPROPENYL METHYL ETHER 99% 2-Methoxypropene, 98%, stab. with ca 0.5% potassium carbonate 2-Methoxypropene, 99%, stab. with ca 0.5% potassium carbonate Methyl 1-methylvinyl ether Methyl 1-propene-2-yl ether Methyl α-methylvinyl ether 2-Methoxypropene,97%,stabilized CH3C(OCH3):CH2 2-Methoxypropene, stabilized, 97% 250ML 2-Methoxypropene, 95%, stab. with ca 0.5% potassiuM carbonate 2-Methoxypropene, 95%, stabilized Isopropenyl methyl ethe 2-Methoxypropene, 98%, stabilized 2-Methoxypropene, Stabilized with PotassiuM Carbonate 2-Methoxy-1-propene for synthesis 2-Methoxypropene, stabilized with &ap:0.5% potassium carbonate 2-Methoxypropene> TIANFUCHEM--High purity 116-11-0 2-Methoxypropene 2-METHOXYPROPENE (STABILIZED) Extra Pure Aminocaproic acid impurity 4 (methyl oleyl phthalate) 2-Methoxyprope 2-methoxyprop-1-ene 2-METHYOXYPROPENE 2-Methoxyproene Ether, isopropenyl methyl ISOPROPENYL METHYL ETHER 116-11-0 Alphabetic META - METH Others Protection and Derivatization Protecting and Derivatizing Reagents Synthetic Reagents Analytical Standards Analytical Chromatography Product Catalog Protection & Derivatization Reagents (for Synthesis) Propanes/propenes Protection & Derivatization Reagents (for Synthesis) Synthetic Organic Chemistry