(R)-(+)-TolBINAP
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(R)-(+)-TolBINAP 속성
- 녹는점
- 255-257 °C
- 알파
- +156° (c 0.5, C6H6)
- 끓는 점
- 754.4±60.0 °C(Predicted)
- 저장 조건
- Inert atmosphere,Room Temperature
- 물리적 상태
- 가루
- 색상
- 흰색에서 크림색으로
- ??? (Optical Rotation)
- [α]20/D +162°, c = 0.5 in benzene
- 수용성
- 물에 불용성.
- 최대 파장(λmax)
- 223nm(EtOH)(lit.)
- InChIKey
- IOPQYDKQISFMJI-UHFFFAOYSA-N
- SMILES
- P(C1C=CC(C)=CC=1)(C1C=CC(C)=CC=1)C1C=CC2=CC=CC=C2C=1C1C2=CC=CC=C2C=CC=1P(C1C=CC(C)=CC=1)C1C=CC(C)=CC=1
- CAS 데이터베이스
- 99646-28-3(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
(R)-(+)-TolBINAP C화학적 특성, 용도, 생산
화학적 성질
White to cream powder용도
(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl is used as chiral catalyst ligand. (R)-T-BINAP complexes derived from rhodium precursors are used for the asymmetric hydroformylation of vinyl acetate. It is a catalysts used for reductive amination of ketones, Pt dications for cation trapping, Rh(I)-catalyst for hydrogenation of acetamidoacrylic acid derivatives.일반 설명
BINAP is based on a bis naphthalene backbone with different phosphine derivatives. 2,2′-bis(di-p-tolylphosphino)-1,1′-binaphthyl (p-Tol-BINAP)·AgF complex catalyzed asymmetric Mukaiyama-type aldol reaction is reported.(R)-(+)-TolBINAP 준비 용품 및 원자재
원자재
염화니켈 헥사히드레이트
에틸알코올
N,N-다이메틸폼아마이드
(R)-1,1'-비-2-나프톨
트리클로로실란
나트륨
트리플루오로메탄술폰산무수물
4-브로모톨루엔
테트라하이드로푸란
초산에틸
1,2-디클로로에탄
디에틸포스파이트
트리페닐포스핀
피리딘
트리에틸렌디아민
마그네슘
준비 용품
(R)-(+)-TolBINAP 공급 업체
글로벌( 156)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| XINXIANG RUNYU MATERIAL CO., LTD. | +86-13592593621; +8613592593621 |
sales@runvmat.com | China | 434 | 58 |
| Hebei Zhuanglai Chemical Trading Co Ltd | +86-16264648883 |
niki@zlchemi.com | China | 7245 | 58 |
| Shenzhen Nexcon Pharmatechs Ltd. | +86-0755-89396905 +86-18025329037 |
admin@nexconn.com | China | 3119 | 58 |
| ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | +86-13017695106 +86-13676922317 |
jiuyitime@fdachem.com | China | 9029 | 58 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 |
info@dakenam.com | China | 13090 | 58 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 |
ivan@atkchemical.com | China | 33024 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 |
sales@coreychem.com | China | 29852 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28172 | 58 |
| Accela ChemBio Inc. | +1-858-6993322 |
info@accelachem.com | United States | 21193 | 58 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 |
info@antaichem.com | CHINA | 9636 | 58 |
(R)-(+)-TolBINAP 관련 검색:
디클로로 [(S) - (+) - 2,2'- 비스 (디 페닐 포스 피노) -1,1'- 바이 나프 틸] 루테늄 (II) (S)-(-)-2,2'-비스[디(3,5-자일릴)포스피노]-1,1'-비나프틸 디클로로 [(R) - (+) - 2,2'- 비스 (디 페닐 포스 피노) -1,1'- 바이 나프 틸] 루테늄 (II) (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)루테늄클로라이드 R-(+)-1,2-BIS(디페닐포스피노)프로판 클로로[(S)-(-)-2,2'-비스(디-p-톨릴포스피노)-1,1'-비나프틸](p-시멘)루테늄(II)클로라이드 디아세토[(S)-(-)-2,2'-비스(디-p-톨릴포스피노)-1,1'-비나프틸]루테늄(II) 디메틸암모늄디클로로트리(뮤-클로로)비스[(R)-(+)-2,2'-비스(디-p-톨릴포스피노)-1,1'-비나프틸]디루테네이트(II) 클로로[(R)-(+)-2,2'-비스(디-p-톨릴포스피노)-1,1'-비나프틸](p-시멘)루테늄(II)클로라이드 디아세토[(R)-(+)-2,2'-비스(디-p-톨릴포스피노)-1,1'-비나프틸]루테늄(II) 디메틸암모늄디클로로트리(뮤클로로)비스[(S)-(-)-2,2'-비스(디-p-톨릴포스피노)-1,1'-비나프틸]디루테네이트(II)
(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
(R)-DM-BINAP
Bis(diphenylphosphino)methane
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
rac-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl ,2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
1,1'-BINAPHTHYL