| Company Name: |
MDA Chemicals Ltd.
|
| Tel: |
+44(0)1524 771881 |
| Email: |
sheila@mda-chem.co.uk |
| Products Intro: |
Cas:102-09-0
ProductName:Diphenyl carbonate
|
- Allyl Phenyl Carbonate
-
- $1.00 / 1KG
-
2025-12-12
- CAS:16308-68-2
- Min. Order: 1KG
- Purity: 99%
- Supply Ability: 10000KG
|
| | Phenyl Carbonate Basic information |
| | Phenyl Carbonate Chemical Properties |
| Melting point | 79-82 °C (lit.) | | Boiling point | 301-302 °C (lit.) | | density | 1,3 g/cm3 | | vapor pressure | 0.014Pa at 20℃ | | refractive index | 1.5090 (estimate) | | Fp | 168 °C | | storage temp. | Sealed in dry,Room Temperature | | solubility | Chloroform (Slightly), Methanol (Slightly) | | form | Flakes or Crystalline Powder | | color | White | | Water Solubility | Insoluble | | Merck | 14,7278 | | BRN | 1074863 | | Stability: | Stable. Incompatible with strong oxidizing agents. Flammable. | | InChI | 1S/C13H10O3/c14-13(15-11-7-3-1-4-8-11)16-12-9-5-2-6-10-12/h1-10H | | InChIKey | ROORDVPLFPIABK-UHFFFAOYSA-N | | SMILES | O=C(Oc1ccccc1)Oc2ccccc2 | | LogP | 3.21 at 25℃ | | CAS DataBase Reference | 102-09-0(CAS DataBase Reference) | | NIST Chemistry Reference | Diphenyl carbonate(102-09-0) | | EPA Substance Registry System | Carbonic acid, diphenyl ester (102-09-0) |
| Hazard Codes | Xn | | Risk Statements | 22-20 | | Safety Statements | 22-24/25 | | RIDADR | 3077 | | WGK Germany | 1 | | RTECS | FG0500000 | | TSCA | TSCA listed | | HazardClass | 9 | | PackingGroup | III | | HS Code | 29209010 | | Storage Class | 13 - Non Combustible Solids | | Hazard Classifications | Acute Tox. 4 Oral
Aquatic Acute 1
Aquatic Chronic 2 | | Hazardous Substances Data | 102-09-0(Hazardous Substances Data) | | Toxicity | rat,LD50,oral,1500mg/kg (1500mg/kg),BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD,National Technical Information Service. Vol. OTS0540144, |
| | Phenyl Carbonate Usage And Synthesis |
| Chemical Properties | white solid | | Uses | In the molten state as solvent for nitrocellulose. | | Uses | Estrogenic activity of Diphenyl Carbonate by yeast 2-hybrid assay was studied. | | Preparation | Diphenyl carbonate is prepared by passing phosgene into a solution of
phenol in aqueous sodium hydroxide in the presence of an inert solvent such
as methylene chloride:
The organic phase, which contains the diphenyl carbonate, is separated; the
solvent is stripped off and the diphenyl carbonate is purified by distillation.
The reaction is accelerated by tertiary amines and is analogous to the
interfacial polycondensation of 2,2-bis(4'hydroxyphenyl)propane and phosgene
described. Diphenyl carbonate is a white crystalline
solid, m.p. 78C. | | Definition | ChEBI: A carbonate ester that is the diphenyl ester of carbonic acid. | | Flammability and Explosibility | Non flammable | | Safety Profile | Questionable
carcinogen with experimental neoplastigenic
and tumorigenic data. When heated to
decomposition it emits acrid smoke and
irritating fumes |
| | Phenyl Carbonate Preparation Products And Raw materials |
| Raw materials | Sodium hydroxide-->Hydrogen-->Phenol-->PHOSGENE-->CARBON MONOXIDE-->calcium diphenoxide-->Vinylene carbonate-->Tetraphenylphosphonium chloride-->METHYL PHENYL CARBONATE-->phenyl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylate-->3-tert-Butylphenol-->Hexamethylene Diisocyanate | | Preparation Products | Polycarbonate-->1,5-Diphenylcarbazide-->Diphenyl N-cyanocarbonimidate-->2,4-bis[1-(4-hydroxyphenyl)isopropyl]phenol-->4-Amino-2,4-dihydro-5-(1-methylethyl)-3H-1,2,4-triazol-3-one-->Bisphenol TMC-->1H-BenziMidazole-7-carboxylic acid, 1-[[2'-(2,5-dihydro-5-oxo-1,2,4-oxadiazol-3-yl)[1,1'-biphenyl]-4-yl]Methyl] -2-ethoxy-, Methyl ester |
|