Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II)

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Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) Suppliers list
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Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) Basic information
Uses
Product Name:Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II)
Synonyms:Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II);(S)-[(RuCl (T-BINAP))2(μ-Cl)3[NH2Me2];Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2μ-bis(di-p-tolylphosphino)-1,1μ-binaphthyl]diruthenate(II);Dimethylammoniumdichlorotri(μ-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II)[NH2Me2][{RuCl((S)-tolbinap)}2(μ- Cl)3];DiMethylaMMoniuM dichlorotri(Mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((S)-tolbinap)}2(μ-Cl)3];[NH2Me2][[RuCl((S)-tolbinap)]2(mu-Cl)3];Dimethylammonium dichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]dir;Dimethylammonium dichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((S)-tolbinap)}2(mu-Cl)3]
CAS:309735-86-2
MF:2C48H40P2.C2H7N.Cl.Cl3Ru2.ClH
MW:1783.08
EINECS:
Product Categories:Ru
Mol File:309735-86-2.mol
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) Structure
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) Chemical Properties
Melting point >100°C
storage temp. 2-8°C
Water Solubility Insoluble in water
form Powder
color brown
Sensitive air sensitive
InChIKeyQGBBTZBFEYSGDQ-UHFFFAOYSA-M
CAS DataBase Reference309735-86-2
Safety Information
Hazard Codes F
Risk Statements 11
RIDADR UN 1325 4.1/PG 3
WGK Germany 3
HS Code 2843.90.0000
Storage Class4.1B - Flammable solid hazardous materials
Hazard ClassificationsFlam. Sol. 2
MSDS Information
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) Usage And Synthesis
UsesCatalyst system for asymmetric hydrogenation.
UsesTakasago Ligands and Complexes for Asymmetric Reactions
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) Preparation Products And Raw materials
Tag:Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II)(309735-86-2) Related Product Information
(R)-(+)-TolBINAP 2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL CHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) Tris(triphenylphosphine)ruthenium(II) chloride