Chlorohydridotris(triphenylphosphine)ruthenium (II)

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Chlorohydridotris(triphenylphosphine)ruthenium (II) Basic information
Uses
Product Name:Chlorohydridotris(triphenylphosphine)ruthenium (II)
Synonyms:CHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE) RUTHENIUM(II) TOLUENE ADDUCT;chlorohydridotris(triphenylphosphine)-ruthenium(I;chlorohydrotris(triphenylphosphine)ruthenium;Chlorohydridotris(triphenylphosphine)ruthenium(Ⅱ);Chlorohydridotris(triphenylphosphine)ruthenium();Chlorohydridotris(triphenylphosphine)ruthenium(II)tolueneadduct,98%;Chlorohydridotris(triphenylphosphine)rutheniuM (II) toluene adduct,98% (PPh3)3HRuCl;Hydridotris(triphenylphosphine)ruthenium chloride
CAS:55102-19-7
MF:C54H45ClP3Ru
MW:923.38
EINECS:259-480-7
Product Categories:Ru;Catalysis and Inorganic Chemistry;Ru Catalysts;Ruthenium;metal phosphine complex
Mol File:55102-19-7.mol
Chlorohydridotris(triphenylphosphine)ruthenium (II) Structure
Chlorohydridotris(triphenylphosphine)ruthenium (II) Chemical Properties
Melting point decomposes at 130℃ [ALD94]
Fp 113 °C
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form crystal
color purple
Sensitive air sensitive
InChIInChI=1S/3C18H15P.ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1
InChIKeyGZKMGAXTHYGXEO-UHFFFAOYSA-M
SMILESP(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.Cl[Ru]
Safety Information
Hazard Codes Xn
Risk Statements 36/37/38-20/21/22
Safety Statements 26-36/37/39
MSDS Information
Chlorohydridotris(triphenylphosphine)ruthenium (II) Usage And Synthesis
UsesStarting material to produce high reactive ruthenium metathesis and hydrogenation catalysts.
Chemical Propertiessensitive to moisture; used as a highly active hydrogenation catalyst [ALD94]
Chlorohydridotris(triphenylphosphine)ruthenium (II) Preparation Products And Raw materials
Tag:Chlorohydridotris(triphenylphosphine)ruthenium (II)(55102-19-7) Related Product Information
Tris(triphenylphosphine)chlororhodium Dichloro(p-cymene)ruthenium(II) dimer Rhodium(II) acetate dimer Ruthenium(II) chloride mesitylene dimer Rhodium(III) 2,4-pentanedionate Bis(tricyclohexylphosphine)nickel(II) chloride, 99% Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium Tris(triphenylphosphine)ruthenium(II) chloride Carbonylchlorohydrotris(triphenylphosphine)ruthenium Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Chlorohydridotris(triphenylphosphine)ruthenium (II) Dichlorotris(triphenylphosphine)ruthenium(II) Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) Chloro[hydrotris(pyrazol-1-yl)borato]ruthenium(II)-dichloromethane/ethanol adduct Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2μ-bis[di-(3,5-xylyl)phosphino]-1,1μ-binaphthyl]diruthenate(II) Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-5,5μ-bis[di(3,5-xylyl)phosphino]-4,4μ-bi-1,3-benzodioxole]diruthenate(II)