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1,4-Diacetylbenzene

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CAS:1009-61-6
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CAS:1009-61-6
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CAS:1009-61-6
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Products Intro: Product Name:1,4-Diacetylbenzene
CAS:1009-61-6
Purity:99% Package:1KG,5KG,10KG

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  • 2026-07-02
  • CAS:1009-61-6
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  • Purity: 99%min
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1,4-Diacetylbenzene Basic information
Product Name:1,4-Diacetylbenzene
Synonyms:1-(4-Acetyl-phenyl)-ethanone;1,1’-(1,4-phenylene)bis-ethanon;Benzene, p-diacetyl-;P-ACETYL ACETOPHENONE;P-DIACETYLBENZENE;TIMTEC-BB SBB008588;1,4-DIACETYLBENZENE;4'-ACETYLACETOPHENONE
CAS:1009-61-6
MF:C10H10O2
MW:162.19
EINECS:213-769-4
Product Categories:C10;Carbonyl Compounds;Ketones;Aromatic Ketones (substituted)
Mol File:1009-61-6.mol
1,4-Diacetylbenzene Structure
1,4-Diacetylbenzene Chemical Properties
Melting point 111-113 °C (lit.)
Boiling point 120 °C / 1mmHg
density 1.0613 (rough estimate)
refractive index 1.5120 (estimate)
storage temp. Sealed in dry,Room Temperature
form powder to crystaline
color White to Almost white
Water Solubility 6.309mg/L(25 ºC)
BRN 1907515
InChIInChI=1S/C10H10O2/c1-7(11)9-3-5-10(6-4-9)8(2)12/h3-6H,1-2H3
InChIKeySKBBQSLSGRSQAJ-UHFFFAOYSA-N
SMILESC1(C(=O)C)=CC=C(C(=O)C)C=C1
CAS DataBase Reference1009-61-6(CAS DataBase Reference)
NIST Chemistry ReferenceEthanone, 1,1'-(1,4-phenylene)bis-(1009-61-6)
EPA Substance Registry SystemEthanone, 1,1'-(1,4-phenylene)bis- (1009-61-6)
Safety Information
Risk Statements 36/37/38
Safety Statements 22-24/25
WGK Germany 3
TSCA TSCA listed
HS Code 29143990
Storage Class11 - Combustible Solids
MSDS Information
ProviderLanguage
SigmaAldrich English
1,4-Diacetylbenzene Usage And Synthesis
Chemical PropertiesALMOST WHITE TO LIGHT BROWN CRYSTALLINE POWDER
Uses1,1''-(1,4-phenylene)bis-Ethanone can undergo oxidative C-C Bond Cleavage to synthesize an aryl carboxylic acid with an iodine catalyst . 1,1''-(1,4-phenylene)bis-Ethanone is also capable of Suzuki-Miyaura coupling.
Synthesis Reference(s)The Journal of Organic Chemistry, 26, p. 4308, 1961 DOI: 10.1021/jo01069a031
Synthetic Communications, 26, p. 3175, 1996 DOI: 10.1080/00397919608004626
Purification MethodsCrystallise it from EtOH (m 114o) or *benzene and dry it in a vacuum over CaCl2. Also purify it by dissolving it in acetone, treating with Norit, evaporating and recrystallising from MeOH. The dioxime has m 248-259o. [Wagner et al. J Am Chem Soc 108 7727 1986]. [Beilstein 7 H 686, 7 II 624, 7 III 3504, 7 IV 2156.]
Tag:1,4-Diacetylbenzene(1009-61-6) Related Product Information
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