PROHEXADIONE

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Products Intro: Product Name:Prohexadione
CAS:88805-35-0
Purity:98% Package:1g,10g,25g,100g,500g,1kg
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CAS:88805-35-0
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Products Intro: Product Name:Prohexadione
CAS:88805-35-0
Purity:98% Package:1g;10g;25g;500g;1kg
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CAS:88805-35-0
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Products Intro: Product Name:Prohexadione
CAS:88805-35-0
Purity:95% Package:1mg;5mg;10mg
PROHEXADIONE Basic information
Product Name:PROHEXADIONE
Synonyms:PROHEXADIONE;PROHEXADIONE STANDARD;Prohexadione Solution, 1000ppm;Cyclohexanecarboxylic acid, 3,5-dioxo-4-(1-oxopropyl)-
CAS:88805-35-0
MF:C10H12O5
MW:212.2
EINECS:
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Mol File:88805-35-0.mol
PROHEXADIONE Structure
PROHEXADIONE Chemical Properties
Melting point 98-99°
Boiling point 454.9±45.0 °C(Predicted)
density 1.330±0.06 g/cm3(Predicted)
storage temp. Store at -20°C
solubility Chloroform: soluble
pka2.66±0.25(Predicted)
form A solid
LogP-1.098 (est)
Safety Information
MSDS Information
PROHEXADIONE Usage And Synthesis
UsesProhexadione (BX-112 free acid) is a plant growth regulator. Prohexadione inhibits gibberellin biosynthesis of plants[1][2].
DefinitionChEBI: Prohexadione is a 4-oxo monocarboxylic acid that is cyclohexanecarboxylic acid which is substituted by oxo groups at positions 3 and 5, and by a propanoyl group at position 4. A plant growth regulator, it is used (commonly as the corresponding calcium salt, known as prohexadione-calcium) as an anti-lodging agent in small-grain cereals. It has a role as an agrochemical, a plant growth regulator and a gibberellin biosynthesis inhibitor. It is a 4-oxo monocarboxylic acid and a beta-triketone. It is a conjugate acid of a prohexadione(2-).
Enzyme inhibitorThis plant growth regulator (FWfree-acid = 178.19 g/mol), also named 3- hydroxy-5-oxo-4-propionylcyclohex-3-ene-1-carboxylic acid, inhibits the biosynthesis of growth active gibberellins (GAs), thereby reducing longitudinal shoot growth. Prohexadione resembles 2-oxoglutaric acid, the co-substrate the dioxygenases that catalyze hydroxylation steps in late stages of GA biosynthesis. Its primary target of is 3b hydroxylation, thereby reducing levels of GA1 (the highly active form) and bringing about theaccumulation of its immediate precursor (inactive). Targets: flavanone 3-dioxygenase flavonol synthase; and gibberellin biosynthesis.
References[1] Paulson GS, et al. Effect of a plant growth regulator prohexadione-calcium on insect pests of apple and pear. J Econ Entomol. 2005 Apr;98(2):423-31. DOI:10.1093/jee/98.2.423
[2] Vavilala DT, et al. Prohexadione, a plant growth regulator, inhibits histone lysine demethylases and modulates epigenetics. Toxicol Rep. 2014 Nov 4;1:1152-1161.
[3] Feng N, et al. Prohexadione-calcium alleviates saline-alkali stress in soybean seedlings by improving the photosynthesis and up-regulating antioxidant defense. Ecotoxicol Environ Saf. 2021 Sep 1;220:112369. DOI:10.1016/j.ecoenv.2021.112369
[4] McGrath MJ, et al. Evidence that prohexadione-calcium induces structural resistance to fire blight infection. Phytopathology. 2009 May;99(5):591-6. DOI:10.1094/PHYTO-99-5-0591
PROHEXADIONE Preparation Products And Raw materials
Tag:PROHEXADIONE(88805-35-0) Related Product Information
PROHEXADIONE-CALCIUM SOLUTION 100UG/ML IN ACETONITRILE 1ML PROHEXADIONE-CALCIUM PROHEXADIONE-CALCIUM SOLUTION 100UG/ML IN TOLUENE 1ML 3-OXO-1-CYCLOHEXANECARBOXYLIC ACID 96 3,5-Dioxocyclohexanecarboxylic acid prohexadione-calcium 4,6-DIOXOHEPTANOIC ACID 2-ACETYL-1,3-CYCLOHEXANEDIONE PROHEXADIONE 2-ACETYLCYCLOHEXANONE