2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&

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2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& manufacturers
2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& Basic information
Product Name:2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&
Synonyms:2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&;2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D) OXAZOLIN-2-YL)PYRIDINE;(3aR,8aS)-in-pybox, (3aR,3μaR,8aS,8μaS)-2,2μ-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole;2,6-Bis((3aR,8aS)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine;8H-Indeno[1,2-d]oxazole,2,2'-(2,6-pyridinediyl)bis[3a,8a-dihydro-, (3aR,3'aR,8aS,8'aS)-;(3aR,3'aR,8aS,8'aS)-2,2'-(2,6-pyridinediyl)bis[3a,8a-dihydro-8H-Indeno[1,2-d]oxazole;2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine >=94%;2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine, >=98%
CAS:357209-32-6
MF:C25H19N3O2
MW:393.44
EINECS:
Product Categories:BOX series;Chiral Nitrogen
Mol File:357209-32-6.mol
2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& Structure
2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& Chemical Properties
Melting point 284 °C (dec.)
Boiling point 633.0±55.0 °C(Predicted)
density 1.50±0.1 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form solid
pka4.35±0.20(Predicted)
AppearanceWhite to off-white Solid
Optical Rotation[α]20/D +386°, c = 1 in methylene chloride(lit.)
InChI1S/C25H19N3O2/c1-3-8-16-14(6-1)12-20-22(16)27-24(29-20)18-10-5-11-19(26-18)25-28-23-17-9-4-2-7-15(17)13-21(23)30-25/h1-11,20-23H,12-13H2/t20-,21-,22+,23+/m0/s1
InChIKeyBZSJUFJXCHHRHW-MYDTUXCISA-N
SMILESC1[C@@H]2OC(=N[C@@H]2c3ccccc13)c4cccc(n4)C5=N[C@H]6[C@H](Cc7ccccc67)O5
Safety Information
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 29349990
Storage Class11 - Combustible Solids
Hazard ClassificationsAquatic Chronic 4
MSDS Information
2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& Usage And Synthesis
Chemical PropertiesWhite powder
UsesCatalytic ligand used for:
  • [3+2] cycloaddition of N-tosyl aziridines with electron-rich alkenes via selective carbon-carbon bond cleavage
  • Enantioselective Mukaiyama-aldol reactions
  • Enantioselective carbonyl-ene reactions
  • Cu(I)-catalyzed asymmetric alkynylation of imino esters with terminal alkynes
  • Asymmetric three-component coupling reactions catalyzed by a Cu/pybox complex
  • Enantioselective Diels-Alder reaction
  • Ni-catalyzed cross-coupling reactions
2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& Preparation Products And Raw materials
Tag:2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&(357209-32-6) Related Product Information
2,6-bis[(4R,5R)-4,5-dihydro-1-[(4-methylphenyl)sulfonyl]-4,5-diphenyl-1H-imidazol-2-yl]-Pyridine (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE 2-[(4R)-4,5-dihydro-4-(phenylMethyl)-2-oxazolyl]- Pyridine 2,6-bis[(4S,5S)-4,5-dihydro-4,5-diphenyl-1H-imidazol-2-yl]-Pyridine (S)-5-CF3-pyrox-tBu 2-[(4R)-4-(1,1-diMethylethyl)-4,5-dihydro-2-oxazolyl]-5-(trifluoroMethyl)-Pyridine (+)-2 2'-ISOPROPYLIDENEBIS((4R)-4-BENZYL (S,S)-2,2-BIS(4-PHENYL-2-OXAZOLIN-2-YL)PROPANE (4S 4'S)-(-)-2 2'-(3-PENTYLIDENE)BIS(4-& (4R,4'R)-2,2'-(Cyclopentane-1,1-diyl)-bis(4-phenyl-4,5-dihydrooxazole)