(S,S)-2,2-Bis(4-phenyl-2-oxazolin-2-yl)propane

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(S,S)-2,2-Bis(4-phenyl-2-oxazolin-2-yl)propane manufacturers
(S,S)-2,2-Bis(4-phenyl-2-oxazolin-2-yl)propane Basic information
Product Name:(S,S)-2,2-Bis(4-phenyl-2-oxazolin-2-yl)propane
Synonyms:(S,S)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE);(S)-(-)-2,2'-ISOPROPYLIDENEBIS(4-PHENYL-2-OXAZOLINE);(-)-2,2-Bis[(4S)-4-phenyl-2-oxazolin-2-yl]propane,98%;(-)-2,2'-isopropylidenebis[(4s)-4-phenyl-2-oxazoline];2,2'-isopropylidenebis(4-phenyl-2-oxazoline);(S,S)-2,2-Bis(4-phenyl-2-oxazolin-2-yl)propane, (S,S)-2,2μ-Isopropylidenebis(4-phenyl-2-oxazoline);(S,S)-2,2′-Isopropylidene-bis(4-phenyl-2-oxazoline),(S,S)-2,2-Bis(4-phenyl-2-oxazolin-2-yl)propane;()-2,2′-Isopropylidenebis[(4S)-4-phenyl-2-oxazoline],(S,S)-2,2′-Isopropylidenebis(4-phenyl-2-oxazoline), (S,S)-2,2-Bis(4-phenyl-2-oxazolin-2-yl)propane
CAS:131457-46-0
MF:C21H22N2O2
MW:334.41
EINECS:
Product Categories:BOX series;Chiral Nitrogen;organic building block;Asymmetric Synthesis;Synthetic Organic Chemistry;organic amine
Mol File:131457-46-0.mol
(S,S)-2,2-Bis(4-phenyl-2-oxazolin-2-yl)propane Structure
(S,S)-2,2-Bis(4-phenyl-2-oxazolin-2-yl)propane Chemical Properties
Melting point 37-41 °C(lit.)
Boiling point 193 °C0.03 mm Hg(lit.)
alpha -150 º (C=1% IN ETOH)
density 1 g/mL at 25 °C(lit.)
refractive index -155 ° (C=1, EtOH)
Fp >230 °F
storage temp. -20°C
form liquid
pka4.85±0.70(Predicted)
AppearanceOff-white to light yellow <37°C Solid,>41°C Liquid
Optical Rotation[α]20/D 160°, c = 1 in ethanol
BRN 4266906
InChIInChI=1S/C21H22N2O2/c1-21(2,19-22-17(13-24-19)15-9-5-3-6-10-15)20-23-18(14-25-20)16-11-7-4-8-12-16/h3-12,17-18H,13-14H2,1-2H3/t17-,18-/m1/s1
InChIKeyJTNVCJCSECAMLD-QZTJIDSGSA-N
SMILESC(C1=N[C@@H](C2=CC=CC=C2)CO1)(C1=N[C@@H](C2=CC=CC=C2)CO1)(C)C
Safety Information
Risk Statements 36/37/38
Safety Statements 22-24/25
WGK Germany 3
F 10
HS Code 29349990
Storage Class10 - Combustible liquids
MSDS Information
ProviderLanguage
SigmaAldrich English
(S,S)-2,2-Bis(4-phenyl-2-oxazolin-2-yl)propane Usage And Synthesis
Chemical PropertiesClear light yellow viscous liquid
UsesC2 symmetric ligand for enantioselective catalysis. Easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.
(S,S)-2,2-Bis(4-phenyl-2-oxazolin-2-yl)propane Preparation Products And Raw materials
Tag:(S,S)-2,2-Bis(4-phenyl-2-oxazolin-2-yl)propane(131457-46-0) Related Product Information
(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane (-)-2,6-Bis[2-[3aS-(2(3'aR*,8'aS*),3a,8a)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]]pyridine 2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine (4R,4'R)-2,2'-(Cyclopentane-1,1-diyl)-bis(4-phenyl-4,5-dihydrooxazole) (S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine (4S 4's)-(-)-2 2'-(3-pentylidene)bis(4-& (+)-2 2'-Isopropylidenebis((4R)-4-benzyl 2,6-Bis((3aR,8aS)-8H-indeno(1,2-d)oxazo& (S,S)-2,2-Bis(4-phenyl-2-oxazolin-2-yl)propane Oxazoline 2-Ethyl-2-oxazoline (R,R)-2,2'-(Dimethylmethylene)bis(4-phenyl-2-oxazoline) (S,S)-2,2'-Methylenebis(4-phenyl-2-oxazoline) (S)-(+)-1-Amino-1-phenyl-2-methoxyethane 2-(1-(Hydroxymethyl)ethyl)-oxazoline& 2-Isopropyl-2-oxazoline 2-[1-Methyl-1-(4-phenyl-4,5-dihydro-1,3-oxazol-2-yl)ethyl]-4-phenyl-4,5-dihydro-1,3-oxazole