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| | (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate Basic information | | Reactions |
| Product Name: | (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate | | Synonyms: | (-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (R,R)-Me-DUPHOS-Rh;(-)-1,2-Bis[(2R,5R)-2,5-diMethylphospholano]benzene(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate, 97%;(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(l)tetrafluoroborate;Bisdimethylphospholanobenzenecyclooctadienerho;1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO&;(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(I)tetrafluoroborate,98+%(R,R)-Me-DUPHOS-Rh;(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate;(-)-1,2-Bis((2R,5R)-2,5-diMethylphospholano)benzene(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate (R,R)-Me-DUPHOS-Rh | | CAS: | 210057-23-1 | | MF: | C26H40BF4P2Rh4* | | MW: | 604.25 | | EINECS: | | | Product Categories: | Chiral Catalysts, Ligands, and Reagents;DuPhos/BPE;Privileged Ligands and Complexes;organometallic complex | | Mol File: | 210057-23-1.mol | ![(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate Structure](CAS/GIF/210057-23-1.gif) |
| | (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate Chemical Properties |
| storage temp. | 2-8°C, protect from light, stored under nitrogen | | form | crystal | | color | red-orange | | Water Solubility | insoluble | | Sensitive | air sensitive | | InChIKey | FKGVQOXVEDXEEW-MYDVBLLJSA-N | | SMILES | [F-].FB(F)F.C1CC=CCCC=C1.C[C@@H]2CC[C@@H](C)[PH]23c4ccccc4[PH]5([C@H](C)CC[C@H]5C)[Rh+]3(C)C | | CAS DataBase Reference | 210057-23-1(CAS DataBase Reference) |
| Risk Statements | 36/37/38 | | Safety Statements | 24/25 | | WGK Germany | 3 | | HS Code | 29310099 | | Storage Class | 11 - Combustible Solids |
| Provider | Language |
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ACROS
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| | (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate Usage And Synthesis |
| Reactions |
- The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.
- Forms superior catalysts for asymmetric reductive aminations.
- Catalyst used for the asymmetric hydrogenation of enol phosphonates.
- A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines.
- Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO.
- Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization.
- Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.
- Palladium catalyzed asymmetric phosphination.
| | Chemical Properties | red or red-brown crystalline powder | | Uses | DuPhos and BPE Ligands: Highly Efficient Privileged Ligands |
| | (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate Preparation Products And Raw materials |
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