2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate

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Products Intro: Product Name:CIP; 2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate
CAS:101385-69-7
Purity:98% HPLC Package:50g;100g;500g;1kg;10kg;25kg
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CAS:101385-69-7
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Products Intro: Product Name:2-Chloro-1,3-Dimethylimidazolidinium Hexafluorophosphate
CAS:101385-69-7
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Products Intro: Product Name:2-Chloro-1,3-dimethyl-4,5-dihydro-1H-imidazol-3-ium hexafluorophosphate(V)
CAS:101385-69-7
Purity:97+% Package:1g;10g;100g;;1kg Remarks:Z-09530

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2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate Basic information
Product Name:2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate
Synonyms:2-CHLORO-1,3-DIMETHYL-2-IMIDAZOLINIUM HEXAFLUOROPHOSPHATE;2-CHLORO-1,3-DIMETHYLIMIDAZOLIDINIUM HEXAFLUOROPHOSPHATE;2-CHLORO-1,3-DIMETHYLIMIDAZOLINIUM HEXAFLUOROPHOSPHATE;2-CHLORO-1,3-DIMETHYLIMIDAZOLINIUM PF6;2-Chlor-1,3-dimethyl-imidazolidinium-hexafluorophosphat;2-CHLORO-1,3-DIMETHYLIMIDAZOLINIUM HEXAFLUOROPHOSPHATE 98+%;2-Chloro-1,3-dimethy;CIP 2-Chloro-1,3-diMethyliMidazolidiniuM hexafluorophosphate
CAS:101385-69-7
MF:C5H10ClN2.F6P
MW:278.56
EINECS:628-484-4
Product Categories:Biochemistry;Condensation & Active Esterification;Coupling Reactions (Peptide Synthesis);Peptide Synthesis;Synthetic Organic Chemistry
Mol File:101385-69-7.mol
2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate Structure
2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate Chemical Properties
Melting point 231-233 °C (lit.)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility acetonitrile: 0.1 g/mL, clear
form powder to crystal
color White to Almost white
Sensitive Moisture & Light Sensitive
BRN 5369058
Major Applicationpeptide synthesis
InChIInChI=1S/C5H10ClN2.F6P/c1-7-3-4-8(2)5(7)6;1-7(2,3,4,5)6/h3-4H2,1-2H3;/q+1;-1
InChIKeyCNAKHAGVVMOXFE-UHFFFAOYSA-N
SMILES[P-](F)(F)(F)(F)(F)F.C1(Cl)=[N+](C)CCN1C
CAS DataBase Reference101385-69-7(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
F 8-10-21
HS Code 29332900
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate Usage And Synthesis
Chemical PropertiesWhite crystalline powder
UsesReactant for synthesis of:
Diazo-transfer reagents

Reagent for synthesis of:
Cannabinoid CB1 receptor agonists
Selective small-molecule melanocortin-4 receptor agonists
Imidazoles as selective cannabinoid CB2 receptor antagonists
Cyclic alpha-peptoids
Cyclic melanotropin peptide analogues selective for the human melanocortin-4 receptor
General Description2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate is a reagent used for the coupling and esterification of sterically hindered amino acids.[1]
reaction suitabilityreaction type: Coupling Reactions
Solubility in organics2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate is soluble in DMF; partially soluble in H2O, MeOH, EtOAc, CH2Cl2, and CHCl3.
storage2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate (CIP) can be stored refrigerated for at least 5 years without loss of reactivity. CIP is an irritant and should be used in a fumehood, when possible.
References1. (a) Humphery, J. M.; Chamberlin, R., Chem. Rev. 1997, 97, 2243. (b) Albericio, F.; Carpino, L. A., Methods Enzymol. 1997, 289, 104
2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate Preparation Products And Raw materials
Tag:2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate(101385-69-7) Related Product Information
Potassium hexafluorophosphate Chlorodimethylphenylsilane Lithium hexafluorophosphate tert-Butyldimethylsilyl chloride 2-Chloro-1,3-dimethylimidazolidinium chloride 2-Fluoro-1,3-dimethylimidazolidinium hexafluorophosphate 2-Chloro-1,3-dimethylimidazolidinium tetrafluoroborate Tetramethylguanidine tert-Butyl carbamate Hexafluorophosphoric acid Difluorochloromethane Hexafluorophosphate Chloro-N,N,N′,N′-tetramethylformamidinium hexafluorophosphate 2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate