(3-Ethoxycarbonyl-2-oxopropyl)triphenylphosphonium chloride

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(3-Ethoxycarbonyl-2-oxopropyl)triphenylphosphonium chloride Basic information
Product Name:(3-Ethoxycarbonyl-2-oxopropyl)triphenylphosphonium chloride
Synonyms:(3-(ethoxycarbonyl)-2-oxopropyl)triphenyl-phospho;(3-Ethoxycarbonyl-2-oxoproply)triphenylphosphonium chloride;(4-Ethoxy-2,4-dioxo-butyl)-triphenyl-phosphonium chloride;(4-ethoxy-2,4-dioxobutyl)-triphenylphosphanium,chloride;(3-Ethoxycarbonyl-2-oxopropyl)triphenylphosphonium chloride
CAS:106302-03-8
MF:C24H24ClO3P
MW:426.87
EINECS:
Product Categories:C-C Bond Formation;Olefination;Wittig Reagents
Mol File:106302-03-8.mol
(3-Ethoxycarbonyl-2-oxopropyl)triphenylphosphonium chloride Structure
(3-Ethoxycarbonyl-2-oxopropyl)triphenylphosphonium chloride Chemical Properties
Melting point 160 °C (dec.)(lit.)
InChI1S/C24H24O3P.ClH/c1-2-27-24(26)18-20(25)19-28(21-12-6-3-7-13-21,22-14-8-4-9-15-22)23-16-10-5-11-17-23;/h3-17H,2,18-19H2,1H3;1H/q+1;/p-1
InChIKeyBRRCLIKFZISBBV-UHFFFAOYSA-M
SMILES[Cl-].CCOC(=O)CC(=O)C[P+](c1ccccc1)(c2ccccc2)c3ccccc3
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
(3-Ethoxycarbonyl-2-oxopropyl)triphenylphosphonium chloride Usage And Synthesis
UsesReactant for:
  • Preparation of cyclic amidine-based inhibitors of -secretase (BACE-1)
  • Wittig reactions
  • Dehydrochlorination and alkylation reactions
reaction suitabilityreaction type: C-C Bond Formation
(3-Ethoxycarbonyl-2-oxopropyl)triphenylphosphonium chloride Preparation Products And Raw materials
Raw materialsEthyl 3-oxo-4-(triphenylphosphoranylidene)butyrate-->Ethyl 4-chloroacetoacetate-->Triphenylphosphine
Tag:(3-Ethoxycarbonyl-2-oxopropyl)triphenylphosphonium chloride(106302-03-8) Related Product Information
(3-ETHOXYCARBONYL-2-OXOPROPYL)TRIPHENYLPHOSPHONIUM CHLORIDE Triphenyl(propyl)phosphonium bromide (FORMYLMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE Butyltriphenylphosphonium chloride (CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE