ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Phosphine ligand >(alphaR,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-2,2'-bis(dicyclohexylphosphino)ferrocene

(alphaR,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-2,2'-bis(dicyclohexylphosphino)ferrocene

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(alphaR,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-2,2'-bis(dicyclohexylphosphino)ferrocene manufacturers
(alphaR,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-2,2'-bis(dicyclohexylphosphino)ferrocene Basic information
Reaction
Product Name:(alphaR,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-2,2'-bis(dicyclohexylphosphino)ferrocene
Synonyms:MANDYPHOS SL-M002-1;(R,R)-1,1'-BIS[(R)-ALPHA-(DIMETHYLA;(R,R)-1,1'-BIS[(R)-ALPHA-(DIMETHYLAMINO)PHENYLMETHYL]-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE;(R,R)-1,1#-Bis[-(dimethylamino)benzyl]-(S,S)-2,2#-bis(dicyc;(S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino)ferrocene,min.97%;(r,r)-1,1'-bis[(r)-α-(dimethylamino)phenylmethyl]-2,2'-bis(dicyclohexylphosphino)ferrocene (acc to cas);(αr,αr)-1,1'-bis[α-(dimethylamino)benzyl]-(s,s)-2,2'-bis(dicyclohexylphosphino)ferrocene;(SP,SμP)-1,1μ-Bis(dicyclohexylphosphino)-2,2μ-bis[(R)-α-(dimethylamino)benzyl]ferrocene
CAS:494227-35-9
MF:C52H72FeN2P2
MW:844.95
EINECS:
Product Categories:Chiral Phosphine;Ferrocene Series;Mandyphos Series
Mol File:494227-35-9.mol
(alphaR,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-2,2'-bis(dicyclohexylphosphino)ferrocene Structure
(alphaR,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-2,2'-bis(dicyclohexylphosphino)ferrocene Chemical Properties
alpha +54.6° (c 1.0, CHCl3)
form solid
color orange-red
Stability:store cold
InChIKeyOMHGSRQJSWIMDO-PMIUFOJNSA-N
SMILES[Fe].CN(C)[C@@H]([C]1[CH][CH][CH][C]1P(C2CCCCC2)C3CCCCC3)c4ccccc4.CN(C)[C@@H]([C]5[CH][CH][CH][C]5P(C6CCCCC6)C7CCCCC7)c8ccccc8
CAS DataBase Reference494227-35-9
Safety Information
WGK Germany 3
HS Code 29319090
Storage Class13 - Non Combustible Solids
MSDS Information
(alphaR,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-2,2'-bis(dicyclohexylphosphino)ferrocene Usage And Synthesis
ReactionLigand for a copper-catalyzed domino conjugated reduction/aldol reaction of methyl acrylate with various alkyl aryl ketones. Reactions of 494227-35-9_1 Ligand for gold catalyzed Phenol synthesis from furyldialkyne Reactions of 494227-35-9_2
Ligand for asymmetric palladium-catalyzed cross-coupling of aryl triflates with [(η6-benzylamine)Cr(CO)3] Reactions of 494227-35-9_3
Chemical PropertiesOrange powder
General Descriptionsold in collaboration with Solvias AG
(alphaR,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-2,2'-bis(dicyclohexylphosphino)ferrocene Preparation Products And Raw materials
Tag:(alphaR,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-2,2'-bis(dicyclohexylphosphino)ferrocene(494227-35-9) Related Product Information
(alphaR,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-,2'-bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]ferrocene (alphaR,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-2,2'-bis(diphenylphosphino)ferrocene (alphaR,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene (alphaR,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-2,2'-bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocene (S,S)-1,2-Ethanediyl-bis-[(2-methoxyphenyl)-phenylphosphine]]-(1,5-cyclooctadiene)-rhodium(I)]-tetrafluoroborate 1,1'-Bis(dicyclohexylphosphino)ferrocene (+/-)-N,N-Dimethyl-1-ferrocenylethylamine (R)-(+)-N,N-Dimethyl-1-ferrocenylethylamine 1,1'-Dimethylferrocene (alphaR,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-2,2'-bis(dicyclohexylphosphino)ferrocene 1,1'-Diethylferrocene Ferrocene 1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE N,N-Dimethylaminomethylferrocene