Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)

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Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) Suppliers list
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Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) manufacturers
Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) Basic information
Product Name:Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)
Synonyms:Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II);RuCl2[(R)-DM-BINAP][(R,R)-DPEN];RuCl2[(R)-xylbinap][(R,R)-dpen];Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R,R)-dpen];-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II),RuCl2[(;RUCL2[(R)-DM-BINAP][(R,R)-DPEN] 1G;DICHLORO{(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL}[(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II),RUCL2[(;Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}
CAS:220114-38-5
MF:C66H64Cl2N2P2Ru
MW:1119.17
EINECS:
Product Categories:Ru
Mol File:220114-38-5.mol
Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) Structure
Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) Chemical Properties
storage temp. 2-8°C
form Powder
color yellow
Sensitive air sensitive
InChIKeyWCMIEHITLHVXIN-UHFFFAOYSA-N
SMILESCl[Ru]Cl.N[C@@H]([C@H](N)c1ccccc1)c2ccccc2.Cc3cc(C)cc(c3)P(c4cc(C)cc(C)c4)c5ccc6ccccc6c5-c7c(ccc8ccccc78)P(c9cc(C)cc(C)c9)c%10cc(C)cc(C)c%10
Safety Information
WGK Germany 3
HS Code 2843.90.0000
Storage Class11 - Combustible Solids
MSDS Information
Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) Usage And Synthesis
UsesRuCl2[(R)-DM-BINAP][(R,R)-DPEN] can catalyze the enantioselective asymmetric reduction of benzils to form the corresponding chiral 1,2-diols.
General DescriptionThe product is a bis-naphthalene containing phosphine ligand, in conjugation with a ruthenium complex.
Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) Preparation Products And Raw materials
Tag:Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)(220114-38-5) Related Product Information
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium (II) Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium (II) (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 1,2-Diphenylethylenediamine (1R,2R)-(+)-1,2-Diphenylethylenediamine (R)-DM-BINAP (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)