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| | TITANIUM(III) CHLORIDE TETRAHYDROFURAN COMPLEX Basic information |
| | TITANIUM(III) CHLORIDE TETRAHYDROFURAN COMPLEX Chemical Properties |
| Melting point | 250 °C | | storage temp. | Refrigerator (+4°C) + Flammables area | | form | Powder or Crystals | | color | Blue to blue-green | | Sensitive | air sensitive, moisture sensitive | | Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents | | InChI | 1S/3C4H8O.3ClH.Ti/c3*1-2-4-5-3-1;;;;/h3*1-4H2;3*1H;/q;;;;;;+3/p-3 | | InChIKey | MIDYWIPTCYRMQF-UHFFFAOYSA-K | | SMILES | Cl[Ti](Cl)Cl.C1CCOC1.C2CCOC2.C3CCOC3 |
| Hazard Codes | C-F,C,F | | Risk Statements | 34-29-19-14-11 | | Safety Statements | 8-45-36/37/39-26-16-27 | | RIDADR | 2925 | | WGK Germany | WGK 3 | | HS Code | 29310099 | | Storage Class | 4.1B - Flammable solid hazardous materials | | Hazard Classifications | Flam. Sol. 1
Skin Corr. 1B |
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ACROS
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| | TITANIUM(III) CHLORIDE TETRAHYDROFURAN COMPLEX Usage And Synthesis |
| Chemical Properties | Blue crystalline powder | | reaction suitability | reagent type: catalyst
core: titanium | | Synthesis | Titanium(III) chloride tetrahydrofuran complex was prepared as follows: to a 2L round-bottomed flask (fitted with a thermometer, mechanical stirrer and reflux condenser) was added granulated titanium (~100 mesh, 99.9 purity, 8.3 g), titanium tetrachloride (98.6 g) and toluene (800 g). THF (432 g) was added under ice cooling while maintaining the tank temperature at 10-20 C. The reaction mixture was heated to reflux (90-100 C) for 6 hours. The reaction mixture was then cooled to room temperature and filtered. The solid tetrahydrofuran titanium chloride product was washed with deoxyhexane (200 mL) and dried under vacuum, yield = 240 g; 94%, based on the total charge of titanium (TiCl4 and particulate titanium). |
| | TITANIUM(III) CHLORIDE TETRAHYDROFURAN COMPLEX Preparation Products And Raw materials |
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