4-Nitro-1-naphthylamine

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4-Nitro-1-naphthylamine Basic information
Product Name:4-Nitro-1-naphthylamine
Synonyms:08890_FLUKA;4-Nitronaphthalen-1-amine, 4-Nitro-1-naphthylamine;4-Nitronaphthalen-1-amine;4-12-00-03114 (Beilstein Handbook Reference);A70003_ALDRICH;AI3-62662;BRN 2211897;EINECS 212-277-7
CAS:776-34-1
MF:C10H8N2O2
MW:188.18
EINECS:212-277-7
Product Categories:Fused Ring Systems;Amines
Mol File:776-34-1.mol
4-Nitro-1-naphthylamine Structure
4-Nitro-1-naphthylamine Chemical Properties
Melting point 190-193 °C(lit.)
Boiling point 419.0±25.0 °C(Predicted)
density 1.366±0.06 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
pka1.31±0.10(Predicted)
form powder to crystal
color Light yellow to Brown
BRN 2211897
InChI1S/C10H8N2O2/c11-9-5-6-10(12(13)14)8-4-2-1-3-7(8)9/h1-6H,11H2
InChIKeyBVPJPRYNQHAOPQ-UHFFFAOYSA-N
SMILESNc1ccc([N+]([O-])=O)c2ccccc12
CAS DataBase Reference776-34-1(CAS DataBase Reference)
NIST Chemistry Reference1-Naphthalenamine, 4-nitro-(776-34-1)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
RTECS QM4370000
HS Code 29214500
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
4-Nitro-1-naphthylamine Usage And Synthesis
Chemical PropertiesOrange-yellow needle-shaped crystals. Melting point: 196°C. Soluble in ethanol and acetic acid, slightly soluble in hot water.
Purification MethodsIt crystallises from EtOH, ethyl acetate or aqueous NH3 as light yellow crystals. The acetyl derivative also forms yellow crystals, m 192.5-193.5o, from Me2CO. [Beilstein 12 H 1259, 12 I 530, 12 II 704, 12 III 2971, 12 IV 3114.]
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