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| | CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Basic information | | Reactions |
| Product Name: | CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) | | Synonyms: | (1,5-cyclooctadiene) (pentamethylcyclopentadiene) rubidium chloride;Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II),98%;Ruthenium,chloro[(1,2,5,6-h)-1,5-cyclooctadiene][(1,2,3,4,5-h)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]-;1,5-Cyclooctadiene, ruthenium complex;Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium;Chloro(1，5-cyclooctadiene)(pentamethylcyclopent...;Chloro(pentaMethylcyclopentadienyl)(cyclooctadiene)rutheniuM;CHLORO(PENTAMETHYLCYCLOPENTADIENYL)(CYC& | | CAS: | 92390-26-6 | | MF: | C18H27ClRu5* | | MW: | 379.93 | | EINECS: | | | Product Categories: | Ru;organometallic complex | | Mol File: | 92390-26-6.mol |  |
| | CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Chemical Properties |
| Melting point | 143-147℃ | | storage temp. | -20°C | | color | brown microxtls | | Stability: | store cold | | InChI | InChI=1S/C10H15.C8H12.ClH.Ru/c1-6-7(2)9(4)10(5)8(6)3;1-2-4-6-8-7-5-3-1;;/h1-5H3;1-2,7-8H,3-6H2;1H;/q;;;+1/p-1/b;2-1-,8-7-;; | | InChIKey | JBVMVFXUVNUNNG-ONEVTFJLSA-M | | SMILES | [C]1(C)[C](C)[C]([C](C)[C]1C)C.C1CCC=CCCC=1.[Ru]Cl |c:13,17,^1:0,2,4,5,7| |
| Hazard Codes | F | | Risk Statements | 20/21/22-14/15 | | Safety Statements | 22-36/37/39-43 | | RIDADR | UN 3395 | | WGK Germany | 3 | | TSCA | No | | HazardClass | 4.3 | | Storage Class | 4.3 - Hazardous materials which set free flammable gases upon contact with water | | Hazard Classifications | Water-react 2 |
| | CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Usage And Synthesis |
| Reactions |
- Catalyst for regio and stereo-specific ring opening via N-O bond cleavage.
- Catalyst for transformation of 1,6-enynes and diazoalkanes into alkenylbicyclo[3.1.0]hexane derivatives.
- Catalyst for ring closing enyne metathesis.
- Catalyst for [2 + 2 + 2] cocyclization of diene-yne, and cyclodimerization of allenynes.
- Catalyst for hydrovinylation of ynamides with ethylene.
- Catalyst for C–H insertion reactions of carbenes.
| | Uses | Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) is a homogeneous catalyst for the formation of carbon-carbon and carbon-heteroatom bonds.
It can be used:
- To catalyze cyclotrimerization of alkynylboronates, propargyl alcohols, and terminal alkynes to form arylboronate, which in turn undergoes palladium(II)-catalyzed carbonylation to form highly substituted phthalides.
- To catalyze C-C coupling of norbornenes and norbornadiene with alkynesto form [2 + 2] cycloadducts.
- In combination with 2-diphenylphosphinoethylamine-potassium tertiary butoxide to form a ternary catalyst system that can catalyze fast racemization of chiral non-racemic sec-alcohols.
- To synthesize new organoruthenium complexes with phosphorus-based ligands such as bis(phosphino)amines.
- To catalyze the addition of organic disulfides to alkenes leading to vic-dithioethers.
| | reaction suitability | core: ruthenium
reagent type: catalyst |
| | CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Preparation Products And Raw materials |
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