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3-Thienylmethanol

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CAS:71637-34-8
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CAS:71637-34-8
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3-Thienylmethanol manufacturers

  • 3-Thienylmethanol
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  • 2025-11-18
  • CAS:71637-34-8
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  • Thiophen-3-ylmethanol
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3-Thienylmethanol Basic information
Product Name:3-Thienylmethanol
Synonyms:3-THIENYLMETHANOL;3-THIOPHENEMETHANOL;3-HYDROXYMETHYLTHIOPHENE;RARECHEM AL BD 0549;TIMTEC-BB SBB004309;THIOPHENE-3-METHANOL;3-Thiophene;3-THIOPHENEMETHANOL 98+%
CAS:71637-34-8
MF:C5H6OS
MW:114.17
EINECS:275-741-8
Product Categories:Building Blocks;Heterocyclic Building Blocks;Thiophens;Functional Materials;Reagents for Conducting Polymer Research;Thiophene Derivatives (for Conduting Polymer Research);Thiophen;Sulphur Derivatives;heterocyclic/Aliphatic series;Thiophene&Benzothiophene;Alkohols;Heterocyclic Compounds;Thiophenes
Mol File:71637-34-8.mol
3-Thienylmethanol Structure
3-Thienylmethanol Chemical Properties
Boiling point 86-88 °C/10 mmHg (lit.)
density 1.211 g/mL at 25 °C (lit.)
refractive index n20/D 1.564(lit.)
Fp 213 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
pka14.49±0.10(Predicted)
form clear liquid
color Colorless to Almost colorless
Water Solubility Slightly soluble in water.
BRN 106460
InChIInChI=1S/C5H6OS/c6-3-5-1-2-7-4-5/h1-2,4,6H,3H2
InChIKeyBOWIFWCBNWWZOG-UHFFFAOYSA-N
SMILESC1SC=CC=1CO
CAS DataBase Reference71637-34-8(CAS DataBase Reference)
NIST Chemistry Reference3-Thiophenemethanol(71637-34-8)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
HS Code 29349990
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
3-Thienylmethanol Usage And Synthesis
Chemical PropertiesColorless liquid
Uses3-Thiophenemethanol was used in the preparation of 3-substituted thiophene conducting copolymers which has potential applications in electrochromic displays. It was also used in the synthesis of 4-(thiophene-3-ylmethoxy)phthalonitrile.
DefinitionChEBI: 3-Thiophenemethanol is a heteroarene.
General DescriptionComparision of electrochemical polymerization properties of 3-thiophenemethanol and 3-methylthiophene has been reported.
Synthesis
3-BROMO-4-FORMYLTHIOPHENE

18791-78-1

3-Thienylmethanol

71637-34-8

The general procedure for the synthesis of 3-thiophene methanol from 3-bromothiophene-4-carboxaldehyde was as follows: 3-bromothiophene-4-carboxaldehyde (930 mg, 5.0 mmol), sodium acetate (820 mg, 10.0 mmol), methanol (30 mL), and palladium chloride (45 mg) were mixed in a balloon-covered glass vial filled with hydrogen. The reaction mixture was stirred at 35 °C for 4 h before being filtered and washed with methanol. Subsequently, the solvent was removed by reduced pressure distillation and the residue was dissolved in water, neutralized with solid sodium bicarbonate and extracted with ethyl acetate. The organic phase was dried with anhydrous sodium sulfate and filtered. Finally, the solvent was removed by reduced pressure distillation and the residue was purified by column chromatography to give 3-thiophene methanol (428 mg, 78% yield).

References[1] Tetrahedron Letters, 2012, vol. 53, # 29, p. 3798 - 3801
Tag:3-Thienylmethanol(71637-34-8) Related Product Information
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