1,2-Bis((2R,5R)-2,5-dimethylphospholano&

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1,2-Bis((2R,5R)-2,5-dimethylphospholano& Basic information
Product Name:1,2-Bis((2R,5R)-2,5-dimethylphospholano&
Synonyms:1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene monooxide;R,R-Me-BozPhos, (2R,5R)-1-{2-[(2R,5R)-2,5-Dimethylphospholan-1-yl]phenyl}-2,5-dimethylphospholane 1-oxide;[1-(2R,5R)-2,5-dimethylphospholanyl]-[2-(2R,5R)-2,5-dimethylphospholanyl-1-oxide]benzene, min. 97%;(2R,5R)-1-(2-[(2R,5R)-2,5-DiMethylphospholan-1-yl]phenyl)-2,5-diMethylphospholane 1-oxide, 97+%;R,R-Me-BozPhos;1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene monooxide kanata purity;[1-(2R,5R)-2,5-DIMETHYLPHOSPHOLANYL]-[2-(2R,5R)-2,5-DIMETHYLPHOSPHOLANYL-1-OXIDE]BENZENE,MIN.97%;[1-(2R,5R)-2,5-dimethylphospholanyl]-[2-(2R,5R)-2,5-dimethylphospholanyl-1-oxide]benzene
CAS:638132-66-8
MF:C18H28OP2
MW:322.36
EINECS:
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Mol File:638132-66-8.mol
1,2-Bis((2R,5R)-2,5-dimethylphospholano& Structure
1,2-Bis((2R,5R)-2,5-dimethylphospholano& Chemical Properties
Melting point 116-122 °C
Boiling point 484.0±28.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form solid
color white
Optical Rotation[α]22/D -171°, c = 1 in chloroform
Sensitive Air Sensitive
InChI1S/C18H28OP2/c1-13-9-10-14(2)20(13)17-7-5-6-8-18(17)21(19)15(3)11-12-16(21)4/h5-8,13-16H,9-12H2,1-4H3/t13-,14-,15-,16-/m1/s1
InChIKeyORZVYNTUPREFTI-KLHDSHLOSA-N
SMILESC[C@@H]1CC[C@@H](C)P1(C2=CC=CC=C2P3[C@H](C)CC[C@H]3C)=O
Safety Information
WGK Germany 3
Storage Class11 - Combustible Solids
MSDS Information
1,2-Bis((2R,5R)-2,5-dimethylphospholano& Usage And Synthesis
UsesDuPhos and BPE Ligands: Highly Efficient Privileged Ligands
General Description1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene monooxide is a chiral ligand whose copper complexes are used extensively in many organic reactions such as addition to imines, nitroalkenes, and reduction of β,β-disubstituted vinyl sulfones.
1,2-Bis((2R,5R)-2,5-dimethylphospholano& Preparation Products And Raw materials
Tag:1,2-Bis((2R,5R)-2,5-dimethylphospholano&(638132-66-8) Related Product Information
(+)-1,2-Bis[(2S,5S)-2,5-dimethylphospholano]benzene (-)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene (+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene (+)-1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene [1-(2S,5S)-2,5-Dimethylphospholanyl]-[2-(2S,5S)-2,5-Dimethylphospholanyl-1-Oxide]Benzene