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2-Methylpropylzinc bromide

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2-Methylpropylzinc bromide Basic information
Product Name:2-Methylpropylzinc bromide
Synonyms:ISOBUTYLZINC BROMIDE, 0.5M SOLUTION IN T ETRAHYDROFURAN;isobutylzinc bromide solution;Isobutylzinc bromide solution 0.5 in THF;Isobutylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles;Isobutylzinc broMide solution 0.5 M in THF;Isobutylzinc broMide, 0.5 M solution in THF, SpcSeal;Isobutylzinc(II) bromide;Zinc, bromo(2-methylpropyl)-
CAS:126403-67-6
MF:C4H9BrZn
MW:202.4
EINECS:
Product Categories:Chemical Synthesis;Organometallic Reagents;Organozinc Halides;Rieke and Organozinc Reagents;Alkyl;Organozinc Halides;Reike and Organozinc Reagents
Mol File:126403-67-6.mol
2-Methylpropylzinc bromide Structure
2-Methylpropylzinc bromide Chemical Properties
density 0.943 g/mL at 25 °C
Fp 1 °F
storage temp. 2-8°C
Water Solubility Reacts with water.
Sensitive Air Sensitive
InChI1S/C4H9.BrH.Zn/c1-4(2)3;;/h4H,1H2,2-3H3;1H;/q;;+1/p-1
InChIKeyWYBHVVXVUCUWSE-UHFFFAOYSA-M
SMILESCC(C)C[Zn]Br
Safety Information
Hazard Codes F,Xn
Risk Statements 14-19-22-36/37/38-40-36/37-14/15-11
Safety Statements 16-23-26-36-43-36/37
RIDADR UN 3399 4.3/PG 2
WGK Germany 1
HazardClass 4.3
HS Code 29319090
Storage Class4.3 - Hazardous materials which set free flammable gases upon contact with water
Hazard ClassificationsAcute Tox. 4 Oral
Carc. 2
Eye Irrit. 2
Flam. Liq. 2
Skin Irrit. 2
STOT SE 3
Water-react 2
MSDS Information
ProviderLanguage
SigmaAldrich English
2-Methylpropylzinc bromide Usage And Synthesis
UsesIsobutylzinc bromide is an organozinc compound, which can be used as a reagent in the palladium-catalyzed Negishi cross-coupling reaction to construct a carbon-carbon bond by reacting with aryl or heteroaryl halides . It is also used to prepare regioselective unsaturated ketones by reacting with tert-butyl isocyanide via an allylic carbonylative coupling reaction in the presence of a nickel catalyst.
2-Methylpropylzinc bromide Preparation Products And Raw materials
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