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9-Anthraldehyde

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CAS:642-31-9
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9-Anthraldehyde Basic information
Product Name:9-Anthraldehyde
Synonyms:9-Formylanthracene;9-ANTHRACENECARBALDEHYDE;9-ANTHRALDEHYDE;AKOS B029849;AKOS BBS-00003154;ANTHRACENE-9-ALDEHYDE;ANTHRACENE-9-CARBOXALDEHYDE;9-Anthaldehyde
CAS:642-31-9
MF:C15H10O
MW:206.24
EINECS:211-383-0
Product Categories:Aromatic Aldehydes & Derivatives (substituted);Anthracenes
Mol File:642-31-9.mol
9-Anthraldehyde Structure
9-Anthraldehyde Chemical Properties
Melting point 103-105 °C (lit.)
Boiling point 305.09°C (rough estimate)
density 1.0701 (rough estimate)
refractive index 1.6324 (estimate)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Soluble in toluene.
form Crystalline Powder or Needles
color Yellow
Sensitive Air Sensitive
BRN 639167
Stability:Stable. Incompatible with strong bases, strong oxidizing agents.
InChI1S/C15H10O/c16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-10H
InChIKeyYMNKUHIVVMFOFO-UHFFFAOYSA-N
SMILES[H]C(=O)c1c2ccccc2cc3ccccc13
CAS DataBase Reference642-31-9(CAS DataBase Reference)
NIST Chemistry Reference9-Anthracenecarboxaldehyde(642-31-9)
EPA Substance Registry System9-Anthracenecarboxaldehyde (642-31-9)
Safety Information
Hazard Codes Xn
Risk Statements 36/37/38-20/21/22
Safety Statements 24/25-36
WGK Germany 3
TSCA TSCA listed
HS Code 29122900
Storage Class11 - Combustible Solids
MSDS Information
ProviderLanguage
9-Anthracenecarboxaldehyde English
ACROS English
SigmaAldrich English
ALFA English
9-Anthraldehyde Usage And Synthesis
Chemical Propertiesyellow powder
Uses9-Anthraldehyde is used to prepare asymmetrical tridentate Schiff base ligands, 2-(9-anthrylmethyl-ideneamino)-4-methyl-phenol and functionalized ligand like 2-(anthracen-9-ylidene)-4,5-bis(diphenylphosphino)-4-cyclopentene-1,3-dione through Knoevenangel condensation with the diphosphine ligand 4,5-bis(diphenylphosphino)-4-cyclopentene-1,3-dione. It is also used as an intermediate for dyes, pigment, active pharmaceutical ingredients and other organic compounds. Further, it is involved in the Diels Alder reaction with benzenediazonium-2-carboxylate.
Synthesis Reference(s)The Journal of Organic Chemistry, 53, p. 4587, 1988 DOI: 10.1021/jo00254a035
General DescriptionThe Diels-Alder reaction of 9-anthracenecarboxaldehyde with benzenediazonium-2-carboxylate was studied.
Purification Methods9-Anthraldehyde [642-31-9] M 206.2, m 104-105o. Crystallise the aldehyde from acetic acid or EtOH. [Masnori et al. J Am Chem Soc 108 1126 1986, Beilstein 7 IV 1738.]
Tag:9-Anthraldehyde(642-31-9) Related Product Information
Benzaldehyde Anthracene Formaldehyde 9-Anthracenecarboxylic acid Paraformaldehyde 9,10-ANTHRACENEDICARBOXALDEHYDE 1,2-ACEANTHRYLENEDIONE 9-TRIFLUOROACETYLANTHRACENE Formaldehyde catching agent 9-METHYL-10-ANTHRALDEHYDE 9-ACETYLANTHRACENE 4-(9-ANTHROYLOXY)PHENACYL BROMIDE 9-ANTHRALDEHYDE HYDRAZONE,9-ANTHRALDEHYDE HYDRAZONE 99% 9-ANTHRALDEHYDE OXIME,9-Anthraldehyde oxime, predominantly syn,9-ANTHRALDEHYDE OXIME, 99%, PREDOMINANTL Y SYN 9-Anthraldehyde Formaldehyde scavenging agent 16-(9-ANTHROYLOXY)PALMITIC ACID 9-ANTHROYLNITRILE Anthraldehyde