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| | 1-Naphthylmagnesium bromide Basic information |
| Product Name: | 1-Naphthylmagnesium bromide | | Synonyms: | 1-NAPTHYLMAGNESIUM BROMIDE, 0.25M SOLUTION IN TETRAHYDROFURAN;1-naphthylmagnesium bromide solution;1-NAPHTHYLMAGNESIUM BROMIDE, 0.25M SOLUTION IN THF;(1-Naphthyl)bromomagnesium;1-Naphthylbromomagnesium;Bromo(1-naphthalenyl)magnesium;Bromo(1-naphthyl)magnesium;1-Naphthylmagnesium bromide, 0.5M in MeTHF | | CAS: | 703-55-9 | | MF: | C10H7BrMg | | MW: | 231.37 | | EINECS: | | | Product Categories: | Aryl;Grignard Reagents;Organometallic Reagents | | Mol File: | 703-55-9.mol |  |
| | 1-Naphthylmagnesium bromide Chemical Properties |
| Boiling point | 65 °C | | density | 0.908 g/mL at 25 °C | | Fp | -17 °C | | storage temp. | water-free area | | Sensitive | Air & Moisture Sensitive | | InChI | 1S/C10H7.BrH.Mg/c1-2-6-10-8-4-3-7-9(10)5-1;;/h1-7H;1H;/q;;+1/p-1 | | InChIKey | PZIIGUMPOSVMSD-UHFFFAOYSA-M | | SMILES | Br[Mg]c1cccc2ccccc12 | | EPA Substance Registry System | Magnesium, bromo-1-naphthalenyl- (703-55-9) |
| Hazard Codes | F,C,Xn | | Risk Statements | 11-14-19-22-34-40-36/37/38 | | Safety Statements | 16-26-33-36/37/39-45-36/37 | | RIDADR | UN 2924 3/PG 2 | | WGK Germany | 1 | | TSCA | TSCA listed | | HazardClass | 3 | | HS Code | 29319090 | | Storage Class | 3 - Flammable liquids | | Hazard Classifications | Acute Tox. 4 Oral
Carc. 2
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3 |
| | 1-Naphthylmagnesium bromide Usage And Synthesis |
| Chemical Properties | Light yellow to yellow slurry or solution | | Uses | 1-Naphthylmagnesium bromide can be used:
- To prepare unsymmetrical chiral diene ligands, which are applicable in asymmetric transformation reactions.
- As a starting material in the synthesis of methyl (2Z,4E)-2-methylsulfanyl-5-(1-naphthyl)-4-nitro-2,4-pentadienoate, a naphthylnitrobutadiene based anti-proliferative compound.
| | reaction suitability | reaction type: Grignard Reaction |
| | 1-Naphthylmagnesium bromide Preparation Products And Raw materials |
| Raw materials | 1(2H)-Naphthalenone, 6-[2-(dimethylamino)ethoxy]-3,4-dihydro--->1-Bromonaphthalene | | Preparation Products | 1-(4-Bromophenyl)-naphthlene-->(4R,5R)-(-)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanol-->1-(2-Chloroethyl)naphthalene-->5-bromonaphthalene-1-carboxylic acid-->3-Quinolineethanol, 6-bromo-2-methoxy-α-1-naphthalenyl-β-phenyl-, (βR)- |
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