| Company Name: |
Alchemie Shanghai Co.,Ltd. |
| Tel: |
+86-15921545397 |
| Email: |
cindy_hu@alchemie-shanghai.com |
| Products Intro: |
Product Name:3,4- DICHLORO ANILINE;3,4-Dichlorobenzenamine;3,4-Dichloraniline;Benzenamine, 3,4-dichloro-;1-Amino-3,4-dichlorobenzene;Aniline, 3,4-dichloro-;m,p-dichloroaniline;3,4-Dichlorophenylamine;3,4-dichlorobenzeneamine;3,4-Dichloro-phenylamine;34DCA
CAS:95-76-1
Purity:100% Package:50KG/Bag
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| | 3,4-Dichloroaniline Basic information |
| Product Name: | 3,4-Dichloroaniline | | Synonyms: | 3,4-DICHLOROPHENYLAMINE;3,4-dichlorobenzenamine;3,4-DICHLOROANILINE;3,4-Dichloranilin;3,4-Dichloraniline;3,4-Dichloroanaline;3,4-dichloro-anilin;3,4-dichloro-benzenamin | | CAS: | 95-76-1 | | MF: | C6H5Cl2N | | MW: | 162.02 | | EINECS: | 202-448-4 | | Product Categories: | amine | alkyl chloride;Aromatics;Miscellaneous Reagents;Anilines, Aromatic Amines and Nitro Compounds;Organics;Building Blocks;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks;Intermediates of Dyes and Pigments;C2 to C6;Nitrogen Compounds;DIA - DICMethod Specific;2000/60/EC;Alpha sort;Amines;AromaticsPesticides&Metabolites;Chemical Class;D;DAlphabetic;European Community: ISO and DIN;C6 | | Mol File: | 95-76-1.mol |  |
| | 3,4-Dichloroaniline Chemical Properties |
| Melting point | 69-71 °C(lit.) | | Boiling point | 272 °C(lit.) | | density | 1,34 g/cm3 | | vapor pressure | 97.5Pa at 78℃ | | refractive index | 1.6140 (estimate) | | Fp | 166 °C | | storage temp. | 0-6°C | | solubility | 0.73g/l | | pka | 2.90±0.10(Predicted) | | form | Crystalline Mass and/or Chunks | | color | Beige to brown | | PH | 7.1 (0.8g/l, H2O) | | Water Solubility | 0.06 g/100 mL | | Merck | 14,3054 | | BRN | 636837 | | Henry's Law Constant | 6.8×10-1 mol/(m3Pa) at 25℃, Duchowicz et al. (2020) | | Stability: | Stable, but darkens in storage. Combustible. Incompatible with strong oxidizing agents, acids, acid chlorides, acid anhydrides. | | InChI | 1S/C6H5Cl2N/c7-5-2-1-4(9)3-6(5)8/h1-3H,9H2 | | InChIKey | SDYWXFYBZPNOFX-UHFFFAOYSA-N | | SMILES | Nc1ccc(Cl)c(Cl)c1 | | LogP | 2.68 at 20℃ | | CAS DataBase Reference | 95-76-1(CAS DataBase Reference) | | NIST Chemistry Reference | Benzenamine, 3,4-dichloro-(95-76-1) | | EPA Substance Registry System | 3,4-Dichloroaniline (95-76-1) |
| Hazard Codes | T,N | | Risk Statements | 23/24/25-41-43-50/53-51/53-33 | | Safety Statements | 26-36/37/39-45-60-61-36/37-28 | | RIDADR | UN 1590 (DICHLOROANILINES, LIQUID) | | WGK Germany | 3 | | RTECS | BX2625000 | | F | 8 | | TSCA | TSCA listed | | HazardClass | 6.1 | | PackingGroup | II | | HS Code | 29214210 | | Storage Class | 6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials | | Hazard Classifications | Acute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 3 Oral
Aquatic Acute 1
Aquatic Chronic 1
Eye Dam. 1
Skin Sens. 1 | | Hazardous Substances Data | 95-76-1(Hazardous Substances Data) |
| | 3,4-Dichloroaniline Usage And Synthesis |
| Description | 3,4-Dichloroaniline, 1-amino-
3,4- dichlorobenzene, is a gray
to dark-brown crystalline solid at room temperature. It is
used as an intermediate for pesticides and dyes
and is produced by catalytic hydrogenation of
3,4-dichloronitrobenzene with noble metal catalysts
under pressure. Various types of additives
prevent dehalogenation during production and
reactors must be fabricated with special steel
alloys to inhibit corrosion . | | Chemical Properties | brown solid
 | | Uses | 3,4-Dichloroaniline is used in the preparation of the herbicide propanil (P760840). | | Uses | 3,4-Dichloroaniline may be employed as derivatization reagent for the HPLC analysis of perfluorooctanoic acid (PFOA). | | Uses | 3,4-Dichloroaniline is used as an intermediate for pesticides and dyes. | | Preparation | 3,4-Dichloroaniline is produced by catalytic hydrogenation of 3,4-dichloronitrobenzene with noble metal catalysts under pressure. Various types of additives prevent dehalogenation during production and reactors must be fabricated with special steel alloys to inhibit corrosion. | | Definition | ChEBI: A dichloroaniline having the two chloro-substituents at the 3- and 4-positions. | | General Description | Light tan to dark gray crystals or brown solid. Melting point 71-72°C. | | Air & Water Reactions | Sensitive to prolonged exposure to heat, light and air. Darkens in storage. Insoluble in water. | | Reactivity Profile | 3,4-Dichloroaniline is incompatible with oxidizing agetns, acids, acid chlorides and acid anhydrides. 3,4-Dichloroaniline can decompose at low pH. Hydrochloric acid accelerates decomposition. Reacts at temperatures above 356°F in the presence of ferric chloride . | | Fire Hazard | 3,4-Dichloroaniline is combustible. | | Metabolic pathway | The basidiomycete Filoboletus sp. TA9054
metabolizes 3,4-dichloroaniline and forms several
condensation products on solid media and in liquid
culture, and no oligomers are produced. Six
metabolites are identified as 3,3'-4,4'-
tetrachloroazobenzene, 4-(3,4-dichloroanilino)-3,3',4' -
trichloroazobenzene, 4-[(3,4-dichloroanilino)-4-(3,4-
dichloroanilino)]-3,3'4'-trichloroazobenzene, 2-(3,4-
dichloroanilino)-N-(3,4-dichlorophenyl)-4-
(chlorophenylene), 6-(3,4-dichloroanilino)-N-(3,4-
dichlorophenyl)-4-(chlorophenylene), and 3,5-bis(3,4-
dichloroanilino)-1,4-chlorobenzoquinone. | | Purification Methods | Crystallise the aniline from MeOH. [Beilstein 12 IV 1257.] |
| | 3,4-Dichloroaniline Preparation Products And Raw materials |
| Raw materials | Chlorine-->Hydrogen-->Ferric chloride-->1,2-Dichlorobenzene-->4-Chloronitrobenzene-->3,4-Dichloronitrobenzene | | Preparation Products | 3,4-DICHLORO-N-METHYLANILINE-->Propanil-->Diuron-->1-(3,4-Dichlorophenyl)piperazine-->Isocyanic acid 3,4-dichlorophenyl ester-->2-AMINO-5,6-DICHLOROBENZOIC ACID-->SWEP-->5-[(3,4-dichlorophenyl)azo]-1,2-dihydro-6-hydroxy-1,4-dimethyl-2-oxonicotinonitrile-->CHLORANOCRYL-->1-(3,4-DICHLOROPHENYL)-3-METHYL UREA-->3-(3,4-DICHLOROPHENYL)PROPIONIC ACID-->6-AMINO-2H-1,4-BENZOXAZIN-3(4H)-ONE-->1-(3,4-DICHLOROPHENYL)-2-THIOUREA-->3,3',4,4'-TETRACHLOROAZOBENZENE-->5,6-Dichloro-2-benzothiazolamine-->5-[(3,4-dichlorophenyl)azo]-1,2-dihydro-6-hydroxy-1,4-dimethyl-2-oxonicotinonitrile-->C.I. Disperse Yellow 58 |
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