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(S)-4-Benzyl-2-oxazolidinone

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(S)-4-Benzyl-2-oxazolidinone Basic information
Product Name:(S)-4-Benzyl-2-oxazolidinone
Synonyms:(4S)-4-BENZYL-1,3-OXAZOLIDIN-2-ONE;4-S-BENZYL-OXAZOLIDIN-2-ONE;(S)-(-)-4-BENZYL-2-OXAZOLIDINONE;(S)-4-BENZYL-2-OXAZOLIDINONE;(S)-(-)-4-BENZYL-2-OXAZOLIDONE;(S)-4-Benzyl-2-oxazolodinone, 99% ee:>99%;2-OXAZOLIDINONE, 4-(PHENYLMETHYL)-, (4S)-;(S)-4-Benzyl-2-oxazolidinone, >99% ee
CAS:90719-32-7
MF:C10H11NO2
MW:177.2
EINECS:618-632-6
Product Categories:Asymmetric Synthesis;Chiral Auxiliaries;Oxazolidinone Derivatives;Oxazolidinone;Chiral Compounds;chiral;Aromatics Compounds;Asymmetric Synthesis;Chiral Building Blocks;Glycidyl Compounds, etc. (Chiral);Synthetic Organic Chemistry;Chiral chemicals;Peptide;Aromatics;Chiral Reagents;Heterocycles;aliskiren;90719-32-7
Mol File:90719-32-7.mol
(S)-4-Benzyl-2-oxazolidinone Structure
(S)-4-Benzyl-2-oxazolidinone Chemical Properties
Melting point 86-88 °C(lit.)
alpha -62 º (C=1, CHCl3)
Boiling point 309.12°C (rough estimate)
density 1.1607 (rough estimate)
refractive index -14.5 ° (C=5, MeOH)
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform (Slightly), Methanol (Slightly)
pka12.78±0.40(Predicted)
form Crystalline Powder
color White to very slightly yellow
Optical Rotation[α]20/D 63°, c = 1 in chloroform
Water Solubility Insoluble in water.
Sensitive Hygroscopic
BRN 3649667
InChI1S/C10H11NO2/c12-10-11-9(7-13-10)6-8-4-2-1-3-5-8/h1-5,9H,6-7H2,(H,11,12)/t9-/m0/s1
InChIKeyOJOFMLDBXPDXLQ-VIFPVBQESA-N
SMILESO=C1N[C@H](CO1)Cc2ccccc2
CAS DataBase Reference90719-32-7(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 24/25-36-26-37/39
WGK Germany 3
F 3-10
HS Code 29349990
Storage Class11 - Combustible Solids
Hazard ClassificationsAcute Tox. 4 Oral
STOT RE 2
MSDS Information
ProviderLanguage
(S)-4-Benzyl-2-oxazolidinone English
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(S)-4-Benzyl-2-oxazolidinone Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
Uses(S)-(-)-4-Benzyl-2-oxazolidinone is used in chiral auxiliary asymmetric alkylation. It has been used in the synthesis of (S)-equol. Preparation and functionalization of chiral, stabilized ylides. It was used for asymmetric synthesis of (3R)- and (3S)-piperazic acid.
UsesAs an oxazolidinone, (S)-4-Benzyl-2-Oxazolidinone can be used in chiral auxiliary asymetric synthesis.
DefinitionChEBI: (S)-4-BENZYL-2-OXAZOLIDINONE is a member of benzenes.
Tag:(S)-4-Benzyl-2-oxazolidinone(90719-32-7) Related Product Information
Benzyl acetate N,N-Dimethylbenzylamine Benzyltrimethylammonium chloride Benzoyl peroxide Benzyl benzoate Dimethylbenzylcarbinyl acetate Benzyl alcohol Benzyl chloride Oxadixyl Benzyltriethylammonium chloride Dibenzyltoluene (S)-(+)-4-Phenyl-2-oxazolidinone (R)-4-Benzyl-2-oxazolidinone (R)-(-)-4-Phenyl-2-oxazolidinone (S)-4-(4-Nitrobenzyl)-2-oxazolidinone (S)-4-(4-Hydrazinylbenzyl)-2-oxazolidinone Benzenepropanol, b,4-diamino-, (S)- 5-[[(4S)-2-Oxo-4-oxazolidinyl]Methyl]-1H-indole-3-acetic Acid