| Company Name: |
Shanghai Tube Pharmaceutical Co., Ltd. Gold
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| Tel: |
021-54338626 18017892860 |
| Email: |
sales@tubepharm.com |
| Products Intro: |
Product Name:Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II) CAS:677736-23-1 Purity:98% Package:10g,25g,50g,100g,500g,1kg,10kg
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CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC& manufacturers
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| | CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC& Basic information |
| Product Name: | CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC& | | Synonyms: | CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC&;Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II);Dicarbonylchloro[(1,2,3,4,5-η)-1,2,3,4,5-pentaphenyl-2,4-cyclopentadien-1-yl]-Ruthenium;CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC& ISO 9001:2015 REACH;2,3,4,5-Tetraphenylcyclopenta-1,4-dien-1-yl)benzene carbon monoxide Chlororuthenium(1+ | | CAS: | 677736-23-1 | | MF: | C35H25.2CO.ClRu | | MW: | 638.125 | | EINECS: | | | Product Categories: | | | Mol File: | 677736-23-1.mol |  |
| | CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC& Chemical Properties |
| Melting point | 152-167 °C | | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | form | solid | | Appearance | Light yellow to yellow Solid | | InChIKey | NGSBLRJKXUHTOC-UHFFFAOYSA-M | | SMILES | [C]1([C](C2C=CC=CC=2)[C]([C](C2C=CC=CC=2)[C]1C1C=CC=CC=1)C1C=CC=CC=1)C1C=CC=CC=1.[O+]#[C-].[O+]#[C-].[Ru]Cl |^1:0,1,8,9,16| |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26 | | WGK Germany | 3 | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
| | CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC& Usage And Synthesis |
| Uses | Reactant for:
- Synthesis of cyclopentadienyl ruthenium dicarbonyl catalyst
- Ligand exchange
- Formation of cyclopentadienyl ruthenium alkoxycarbonylcomplexes with coordinated C:C bonds
Catalyst for:
- (S)-Selective dynamic kinetic resolution of secondary alcohols
- Stereoselective synthesis of neonicorinoide pesticide derivatives
- Divergent asymmetric synthesis of 3,5-disubstituted piperidines
| | reaction suitability | core: ruthenium reagent type: catalyst |
| | CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC& Preparation Products And Raw materials |
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