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Chlorodicarbonyl(1-(I-propylamino)-2,3,4,5-tetraphenylcyclopentadienyl)ruthenium (II)

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Chlorodicarbonyl(1-(I-propylamino)-2,3,4,5-tetraphenylcyclopentadienyl)ruthenium (II) Basic information
Reaction
Product Name:Chlorodicarbonyl(1-(I-propylamino)-2,3,4,5-tetraphenylcyclopentadienyl)ruthenium (II)
Synonyms:CHLORODICARBONYL(1-(ISOPROPYLAMINO)-2,3&;chlorodicarbonyl[1-(i-propylamino)-2,3,4,5-tetraphenylcyclopentadienyl]ruthenium(ii)95+%;Chlorodicarbonyl[1-(i-propylamino)-2,3,4,5-tetraphenylcyclopentadienyl]ruthenium(II),min.95%;Chlorodicarbonyl(1-(isopropylamino)-2,3,4,5-tetraphenylcyclopentadienyl)ruthenium(II);Chlorodicarbonyl[1-(i-propylamino)-2,3,4,5-tetraphenylcyclopentadienyl]ruthenium(II), min. 95%;Chlorodicarbonyl[1-(i-propylamino)-2,3,4,5-tetraphenylcyclopentadienyl]
ruthenium (II), min. 95%;Chlorodicarbonyl(1-(isopropylaMino)-2,3,4,5-tetraphenylcyclo;BRMXQWNTLPPMGQ-UHFFFAOYSA-M
CAS:470688-18-7
MF:C34H28ClNO2Ru5*
MW:619.11
EINECS:
Product Categories:metallocene
Mol File:470688-18-7.mol
Chlorodicarbonyl(1-(I-propylamino)-2,3,4,5-tetraphenylcyclopentadienyl)ruthenium (II) Structure
Chlorodicarbonyl(1-(I-propylamino)-2,3,4,5-tetraphenylcyclopentadienyl)ruthenium (II) Chemical Properties
Melting point 197°C (dec.)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form crystal
color yellow
Sensitive air sensitive
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36/37
WGK Germany 3
MSDS Information
Chlorodicarbonyl(1-(I-propylamino)-2,3,4,5-tetraphenylcyclopentadienyl)ruthenium (II) Usage And Synthesis
ReactionMetal catalyst used in conjunction with enzymes for enantioselective transformations via dynamic kinetic resolution. Reactions of 470688-18-7
UsesCatalyst for asymmetric:
  • Synthesis of achaetolide
  • Transfer hydrogenation and racemization
  • Total synthesis of stagonolide-C

Reactant for synthesis of air-stable racemization catalysts

Racemization catalyst for dynamic kinetic resolution of secondary alcohols
reaction suitabilitycore: ruthenium
reagent type: catalyst
Chlorodicarbonyl(1-(I-propylamino)-2,3,4,5-tetraphenylcyclopentadienyl)ruthenium (II) Preparation Products And Raw materials
Tag:Chlorodicarbonyl(1-(I-propylamino)-2,3,4,5-tetraphenylcyclopentadienyl)ruthenium (II)(470688-18-7) Related Product Information
Chloro[1,3-bis(2,6-di-I-propylphenyl)imidazol-2-ylidene]copper(I) Chlorodicarbonyl(1,2,3,4,5-pentaphenylc& Isopropylamine Cinchonidine Chlorodicarbonyl(1-(I-propylamino)-2,3,4,5-tetraphenylcyclopentadienyl)ruthenium (II) Cyclopentyl-isopropyl-aminehydrochloride Cypenamine