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2-Aminobenzimidazole

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CAS:934-32-7
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  • 2025-06-27
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2-Aminobenzimidazole Basic information
Product Name:2-Aminobenzimidazole
Synonyms:2-Aminobenzimidazole;2-Benzimidazolamine;2-AMINOBENZIMIDAZOLE PESTANAL, 250 MG;2-AMINOBENZIMIDAZOLE, 250MG, NEAT;2-Aminobenzimidazole, 99+%;1H-Benzimidazol-2-amine(9CI);2-Aminobenzimidazole, 98+%;1H-Benzimidazol-2-amin;1H-Benzimidazole-2(3H)-imine
CAS:934-32-7
MF:C7H7N3
MW:133.15
EINECS:213-280-6
Product Categories:Imidazol&Benzimidazole;BENZIMIDAZOLE
Mol File:934-32-7.mol
2-Aminobenzimidazole Structure
2-Aminobenzimidazole Chemical Properties
Melting point 226-230 °C (lit.)
Boiling point 235.67°C (rough estimate)
density 1.1873 (rough estimate)
refractive index 1.5341 (estimate)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility <1g/l slightly soluble
pka11.41±0.10(Predicted)
form Crystalline Powder, Crystals or Flakes
color Yellow to beige or light brown
Water Solubility Soluble in water (Slightly).
BRN 116525
Major Applicationagriculture
environmental
InChI1S/C7H7N3/c8-7-9-5-3-1-2-4-6(5)10-7/h1-4H,(H3,8,9,10)
InChIKeyJWYUFVNJZUSCSM-UHFFFAOYSA-N
SMILESNc1nc2ccccc2[nH]1
CAS DataBase Reference934-32-7(CAS DataBase Reference)
NIST Chemistry Reference2-Aminobenzimidazole(934-32-7)
EPA Substance Registry System2-Aminobenzimidazole (934-32-7)
Safety Information
Hazard Codes Xn
Risk Statements 22-36/37/38-43
Safety Statements 26-36/37/39-22
WGK Germany 3
RTECS DD5775000
TSCA TSCA listed
HS Code 29339990
Storage Class11 - Combustible Solids
Hazard ClassificationsAcute Tox. 4 Oral
MSDS Information
ProviderLanguage
2-Benzimidazolamine English
SigmaAldrich English
ACROS English
ALFA English
2-Aminobenzimidazole Usage And Synthesis
Chemical PropertiesLight yellow to cream or beige powder or flakes. N,N'-o-Phenyleneguanidine [934-32-7], 2-aminobenzimidazole, C7H7N3, Mr 133.15, mp 231 – 232 ℃(decomp.), obtained by cyclization of o-phenylenediamine with cyanogen chloride or cyanamide, is the nucleus for a number of compounds of economic interest.
Uses2-Aminobenzimidazole was used in the hydrolysis of a choline carbonate. It was also used in the synthesis of imidazo[1,2-a]benzimidazoles.
PreparationSynthesis of 2-aminobenzimidazole: Cyanogen bromide (3.5 g., 0.034 mole) was added in small portions, with shaking, to a suspension of o-phenylenediamine (4.2 g. , 0.34 mole) in water (40 ml), the exothermic reaction mixture was cooled to room temperature and it was stirred for 36hrs. The solution was filtered after standing overnight. Sodium hydroxide (1.4 g., 0.034 mole) in 30 ml of water was then added and the solution was evaporated. The solid thus obtained was filtered and recrystalized from water. Yield 85%, m.p. 228 - 230°C
DefinitionChEBI: 2-aminobenzimidazole is a member of the class of benzimidazoles that is benzimidazole in which the hydrogen at position 2 is replaced by an amino group. It has a role as a marine xenobiotic metabolite.
General DescriptionPlates (in water); white powder.
Air & Water ReactionsInsoluble in water.
Reactivity Profile2-Aminobenzimidazole neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides.
Health HazardACUTE/CHRONIC HAZARDS: When heated to decomposition 2-Aminobenzimidazole emits toxic fumes of nitrogen oxides.
Fire HazardFlash point data for 2-Aminobenzimidazole are not available; however, 2-Aminobenzimidazole is probably combustible.
Safety ProfilePoison by intravenous and intraperitoneal routes. Moderately toxic by ingestion. An experimental teratogen. Mutation data reported. When heated to decomposition it emits toxic NO,. See also AROUTIC AMINES.
Tag:2-Aminobenzimidazole(934-32-7) Related Product Information
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